0000000000297679
AUTHOR
K. Morita
Complex chemistry with complex compounds
In recent years gas-phase chemical studies assisted by physical pre-separation allowed for the investigation of fragile single molecular species by gas-phase chromatography. The latest success with the heaviest group 6 transactinide seaborgium is highlighted. The formation of a very volatile hexacarbonyl compound Sg(CO)6 was observed similarly to its lighter homologues molybdenum and tungsten. The interactions of these gaseous carbonyl complex compounds with quartz surfaces were investigated by thermochromatography. Second-generation experiments are under way to investigate the intramolecular bond between the central metal atom of the complexes and the ligands addressing the influence of re…
Focusing ions by viscous drag and weak electric fields in an ion guide
Abstract A new special ion guide has one or more grids at low electric potential in the space between nozzle and skimmer. Viscous drag caused by helium flow is used together with weak electric fields for focusing ions through the skimmer. A typical yield through the skimmer is 75% of that through the nozzle. The focusing device is called a “squeezer”. Most properties of the “squeezer ion guide” are similar to those of an ordinary ion guide. Because the kinetic energies are only of the order of 10 eV, however, problems caused by ion scattering are greatly reduced as compared to ordinary ion guides.
Collinear fast atomic-beam laser spectroscopy at riken garis/igisol
We have constructed a fast atomic-beam collinear laser spectroscopy system connected to the on-line isotope separator facility GARIS/IGISOL at RIKEN. This system is potentially powerful in studying refractory elements. To test the system, an off-line collinear experiment was made on stable Hf isotopes produced by means of laser ablation technique. For production of radioactive Hf isotopes, the use of the inverse kinematics of a fusion reaction,9Be(166Er,xn)175-xHf, was investigated. The radioactive isotope169Hf was successfully extracted from GARIS/IGISOL and accelerated up to 30 keV.