0000000000338699

AUTHOR

Francesco Di Giacomo

0000-0002-2489-5385

showing 2 related works from this author

Large area perovskite light-emitting diodes by gas-assisted crystallization:

2019

Halide perovskites have been gaining considerable attention recently for use in light-emitting applications, due to their bandgap tunability, color purity and low cost fabrication methods. However, current fabrication techniques limit the processing to small-area devices. Here, we show that a facile N 2 gas-quenching technique can be used to make methylammonium lead bromide-based perovskite light-emitting diodes (PeLEDs) with a peak luminance of 6600 cd m −2 and a current efficiency of 7.0 cd A −1 . We use this strategy to upscale PeLEDs to large-area substrates (230 cm 2 ) by developing a protocol for slot-die coating combined with gas-quenching. The resulting large area devices (9 device…

Materials scienceFabricationBand gapSlot-die coatings02 engineering and technologySubstrate (electronics)Large area devicesengineering.material010402 general chemistry01 natural sciencesLuminancelaw.inventionCoatinglawQuenchingMaterials ChemistryMaterialsDiodePerovskite (structure)Industrial Innovationbusiness.industryGeneral Chemistry021001 nanoscience & nanotechnologyPerovskite light emitting diodes0104 chemical sciencesLuminanceManufacturing techniquesHalide perovskitesengineeringOptoelectronics0210 nano-technologybusinessLight-emitting diode
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Efficient Perovskite Light-Emitting Diodes: Effect of Composition, Morphology, and Transport Layers

2018

Organic-inorganic metal halide perovskites are emerging as novel materials for light-emitting applications due to their high color purity, band gap tunability, straightforward synthesis, and inexpensive precursors. In this work, we improve the performance of three-dimensional perovskite light-emitting diodes (PeLEDs) by tuning the emissive layer composition and thickness and by using small-molecule transport layers. Additionally, we correlate PeLED efficiencies to the perovskite structure and morphology. The results show that the PeLEDs containing perovskites with an excess of methylammonium bromide (MABr) to lead bromide (PbBr2) in a 2:1 ratio and a layer thickness of 80 nm have the highes…

Materials scienceBand gapHOL - HolstHalide02 engineering and technologyPerovskite010402 general chemistry01 natural scienceslaw.inventionTransport layerslawLight-emitting diodeSurface roughnessGeneral Materials SciencePerovskite (structure)TS - Technical Sciencesbusiness.industryStoichiometric perovskite021001 nanoscience & nanotechnology0104 chemical sciencesNano TechnologyOptoelectronicsQuantum efficiencyCrystallite0210 nano-technologybusinessLayer (electronics)High efficiencyLight-emitting diodeACS Applied Materials & Interfaces
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