Author: A. Del Pra

0000000000364646

AUTHOR

A. Del Pra

The influence of the cation on the conformation of the anion μ-hydridobis[pentacarbonylchromium(0)]: crystal and molecular structure of [(phenH)2Cl][Cr2(CO)10(μ-H)] and [K(phen)2][Cr2(CO)10(μ-H)]

Abstract The crystal and molecular structures of [(phenH)2Cl][Cr2(CO)10(μ-H)] (1) and [K(phen)2][Cr2(CO)10(μ-H)] (2) have been determined by single crystal X-ray diffraction. The availability of the potassium cation for the carbonyl oxygens coordination influences the conformation of the anion in 2 as demonstrated by the comparison with the non-coordinating [(phenH)2Cl] cation in 1 and with literature data.

research product

CCDC 152558: Experimental Crystal Structure Determination

Related Article: F.Benetollo, G.Bombieri, A.Del Pra, G.Alonzo, N.Bertazzi|2001|Inorg.Chim.Acta|319|49|doi:10.1016/S0020-1693(01)00436-4

research product

CCDC 152559: Experimental Crystal Structure Determination

Related Article: F.Benetollo, G.Bombieri, A.Del Pra, G.Alonzo, N.Bertazzi|2001|Inorg.Chim.Acta|319|49|doi:10.1016/S0020-1693(01)00436-4

research product

CCDC 152557: Experimental Crystal Structure Determination

Related Article: F.Benetollo, G.Bombieri, A.Del Pra, G.Alonzo, N.Bertazzi|2001|Inorg.Chim.Acta|319|49|doi:10.1016/S0020-1693(01)00436-4

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