6533b7dafe1ef96bd126f3ec

RESEARCH PRODUCT

The influence of the cation on the conformation of the anion μ-hydridobis[pentacarbonylchromium(0)]: crystal and molecular structure of [(phenH)2Cl][Cr2(CO)10(μ-H)] and [K(phen)2][Cr2(CO)10(μ-H)]

M. D. GrilloneFranco BenetolloGabriella BombieriA. Del Pra

subject

DiffractionChemistryOrganic ChemistryCrystal structurePotassium CationBiochemistryIonInorganic ChemistryCrystalCrystallographyMaterials ChemistryMoleculePhysical and Theoretical ChemistrySingle crystal

description

Abstract The crystal and molecular structures of [(phenH)2Cl][Cr2(CO)10(μ-H)] (1) and [K(phen)2][Cr2(CO)10(μ-H)] (2) have been determined by single crystal X-ray diffraction. The availability of the potassium cation for the carbonyl oxygens coordination influences the conformation of the anion in 2 as demonstrated by the comparison with the non-coordinating [(phenH)2Cl] cation in 1 and with literature data.

yearjournalcountryeditionlanguage
1999-03-01Journal of Organometallic Chemistry
https://doi.org/10.1016/s0022-328x(98)00993-0