Cytotoxicity and NMR Studies of Platinum Complexes with Cyclooctadiene Ligands
The synthesis of a series of platinum complexes containing cyclooctadiene ligands with the general structure PtMeL(R-cod) (where L = Cl, I, nC3F7, iC3F7, nC8F17, Me, aryl, alkynyl and R = H, Me, Et, iPr, nBu, iBu, nHex, Ph) is presented. All complexes are remarkably stable and were obtained in excellent yields. Their structure in both solution and the solid state were explored by crystal structures and multinuclear (1H, 13C, 19F, 195Pt) NMR spectroscopy. Cytotoxicity experiments with selected complexes in HeLa cells revealed higher toxicity in comparison to that of cisplatin for most of the structures.
Training Schrödinger’s cat: quantum optimal control
It is control that turns scientific knowledge into useful technology: in physics and engineering itprovides a systematic way for driving a dynamical system from a given initial state into a desired targetstate with minimized expenditure of energy and resources. As one of the cornerstones for enabling quantumtechnologies, optimal quantum control keeps evolving and expanding into areas as diverse as quantumenhancedsensing, manipulation of single spins, photons, or atoms, optical spectroscopy, photochemistry,magnetic resonance (spectroscopy as well as medical imaging), quantum information processing and quantumsimulation. In this communication, state-of-the-art quantum control techniques are r…
Synthesis of Azido-Glycans for Chemical Glycomodification of Proteins
CCDC 993792: Experimental Crystal Structure Determination
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CCDC 993789: Experimental Crystal Structure Determination
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CCDC 1565153: Experimental Crystal Structure Determination
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CCDC 1565150: Experimental Crystal Structure Determination
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CCDC 1565151: Experimental Crystal Structure Determination
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CCDC 993790: Experimental Crystal Structure Determination
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CCDC 1565154: Experimental Crystal Structure Determination
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CCDC 993788: Experimental Crystal Structure Determination
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CCDC 993791: Experimental Crystal Structure Determination
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