Time-differential Mössbauer emission spectroscopy: Development of a new spectrometer and first results

1989

A spectrometer for time-differential Mossbauer spectroscopy was developed with a high count rate capability, a good time resolution, and a flexible data handling. Chemical and physical aftereffects following the57Co decay were studied within the cobalt doped systems Turnbulls blue and ZnS.

Advances in Mössbauer Emission Spectroscopy

1990

After effects following nuclear transformation have been extensively studied in a large variety of matrices by Mossbauer Emission Spectroscopy (MES). The branching ratios of transient atomic charge states and energetically unstable states of the environment, excitations of electronic ligand field states and populations out of equilibrium within the electronic ground state manifold have been studied. Recent developments and also new insights and understandings of different aspects of the aftereffects of radioactive decay of57Co in semiconductors and molecular crystals are reviewed. A detailed picture of the decay process within the electronic states of the nucleogenic Fe3+ species could be o…

New time-differential Mössbauer emission measurements on the high-spin→low-spin relaxation in [57Co/Co(phen)3](ClO4)2

1990

Using our new spectrometer for time-differential Mossbauer emission spectroscopy we reinvestigated the high-spin→low-spin relaxation following the57Co(EC)57Fe process in [57Co/Co(phen)3](ClO4)2 (phen=1,10-phenanthroline). In contrast to former investigations we found a temperature dependent initial population less than 1 for the metastable high-spin states. The results and the data evaluation method are presented.

Mössbauer Emission Spectroscopy of Mixed-Valency after Nuclear Decay in Iron Complexes

1991

The population of anomalous spin states and aliovalent charge states of iron induced by the 57 Co(EC)57 Fe nuclear decay in polycristalline transition metal compounds was studied by means of Coincidence Mossbauer Emission Spectroscopy (CMES), that is Time-Differential Mossbauer Emission Spectroscopy (TDMES) as well as γ/Xray-Coincidence Mossbauer Emission Spectroscopy (γ/X-CMES). By use of time-integral Mossbauer emission spectroscopy (TIMES) we have observed anomalous high spin (S = 2) states of 57 Fe(II) in the system [57Co/Co(phen)3(ClO 4)2 with increasing intensities on lowering the temperature. With TDMES we followed quantitatively the high spin-low spin relaxation kinetics in this com…

Poster contributions

1989