6533b828fe1ef96bd1288c90

RESEARCH PRODUCT

New time-differential Mössbauer emission measurements on the high-spin→low-spin relaxation in [57Co/Co(phen)3](ClO4)2

P. GütlichC. HennenM. AlflenHartmut Spiering

subject

Nuclear and High Energy Physicseducation.field_of_studySpectrometerChemistryRelaxation (NMR)PopulationAnalytical chemistryCondensed Matter PhysicsAtomic and Molecular Physics and OpticsMetastabilityMössbauer spectroscopyEmission spectrumPhysical and Theoretical ChemistrySpectroscopySpin (physics)education

description

Using our new spectrometer for time-differential Mossbauer emission spectroscopy we reinvestigated the high-spin→low-spin relaxation following the57Co(EC)57Fe process in [57Co/Co(phen)3](ClO4)2 (phen=1,10-phenanthroline). In contrast to former investigations we found a temperature dependent initial population less than 1 for the metastable high-spin states. The results and the data evaluation method are presented.

yearjournalcountryeditionlanguage
1990-07-01Hyperfine Interactions
https://doi.org/10.1007/bf02405470