showing 9 related works from this author
New chronology for Ksâr ‘Akil (Lebanon) supports Levantine route of modern human dispersal into Europe
2015
Modern human dispersal into Europe is thought to have occurred with the start of the Upper Paleolithic around 50,000-40,000 y ago. The Levantine corridor hypothesis suggests that modern humans from Africa spread into Europe via the Levant. Ksâr 'Akil (Lebanon), with its deeply stratified Initial (IUP) and Early (EUP) Upper Paleolithic sequence containing modern human remains, has played an important part in the debate. The latest chronology for the site, based on AMS radiocarbon dates of shell ornaments, suggests that the appearance of the Levantine IUP is later than the start of the first Upper Paleolithic in Europe, thus questioning the Levantine corridor hypothesis. Here we report a seri…
The shell matrix of the european thorny oyster, Spondylus gaederopus: microstructural and molecular characterization.
2020
17 pages; International audience; Molluscs, the largest marine phylum, display extraordinary shell diversity and sophisticated biomineral architectures. However, mineral-associated biomolecules involved in biomineralization are still poorly characterised.We report the first comprehensive structural and biomolecular study of Spondylus gaederopus, a pectinoid bivalve with a peculiar shell texture. Used since prehistoric times, this is the best-known shell of Europe’s cultural heritage. We find that Spondylus microstructure is very poor in mineral-bound organics, which are mostly intercrystalline and concentrated at the interface between structural layers.Using high-resolution liquid chromatog…
Reply to Douka et al: Critical evaluation of the Ksâr 'Akil chronologies
2015
Our paper (1) proposes a new chronology for Ksâr 'Akil based on 16 accelerator mass spectrometry (AMS) determinations on shells. To minimize the possibility of dating diagenetically compromised samples, we conducted amino acid racemization analyses on the intracrystalline proteins, oxygen isotope analysis, and geochemical characterization of all dated shells. Our calibrated radiocarbon ages fit well with existing Levantine chronologies, but are up to 4,000 y older than Douka et al.’s (2). Our paper explores several possibilities for this difference, whereas Douka et al. (3) provide alternative explanations. They accept our radiocarbon ages as correct but question our sample selection and Ba…
Shell palaeoproteomics: first application of peptide mass fingerprinting for the rapid identification of mollusc shells in archaeology.
2020
10 pages; International audience; Molluscs were one of the most widely-used natural resources in the past, and their shells are abundant among archaeological findings. However, our knowledge of the variety of shells that were circulating in prehistoric times (and thus their socio-economic and cultural value) is scarce due to the difficulty of achieving taxonomic determination of fragmented and/or worked remains. This study aims to obtain molecular barcodes based on peptide mass fingerprints (PMFs) of intracrystalline proteins, in order to obtain shell identification. Palaeoproteomic applications on shells are challenging, due to low concentration of molluscan proteins and an incomplete unde…
The degradation of intracrystalline mollusc shell proteins: a proteomics study of Spondylus gaederopus.
2021
Mollusc shells represent excellent systems for the preservation and retrieval of genuine biomolecules from archaeological or palaeontological samples. As a consequence, the post-mortem breakdown of intracrystalline mollusc shell proteins has been extensively investigated, particularly with regard to its potential use as a "molecular clock" for geochronological applications. But despite seventy years of ancient protein research, the fundamental aspects of diagenesis-induced changes to protein structures and sequences remain elusive. In this study we investigate the degradation of intracrystalline proteins by performing artificial degradation experiments on the shell of the thorny oyster, Spo…
'Palaeoshellomics' reveals the use of freshwater mother-of-pearl in prehistory
2019
The extensive use of mollusc shell as a versatile raw material is testament to its importance in prehistoric times. The consistent choice of certain species for different purposes, including the making of ornaments, is a direct representation of how humans viewed and exploited their environment. The necessary taxonomic information, however, is often impossible to obtain from objects that are small, heavily worked or degraded. Here we propose a novel biogeochemical approach to track the biological origin of prehistoric mollusc shell. We conducted an in-depth study of archaeological ornaments using microstructural, geochemical and biomolecular analyses, including ‘palaeoshellomics’, the first…
Late Pleistocene-Holocene coastal adaptation in central Mediterranean: Snapshots from Grotta d’Oriente (NW Sicily)
2018
Marine faunal remains from Grotta d’Oriente (Favignana Island, NW Sicily) offer invaluable snapshots of human-coastal environment interaction in the central Mediterranean from the Late Pleistocene to the Middle Holocene. The long-term shellfish and fish records reflect human exploitation of coastal environments undergoing considerable reorganizations during the postglacial sea level rise and the progressive isolation of Favignana from mainland Sicily. We detected an intensification of marine resource exploitation between ∼9.6 ka and ∼7.8 ka BP, which corresponds with the isolation of Favignana Island and, later on, with the introduction of early agro-pastoral economy in this region. We sugg…
Author response: 'Palaeoshellomics’ reveals the use of freshwater mother-of-pearl in prehistory
2019
Integrated novel applications for dietary reconstructions in Prehistory
2013
A broad range of biogeochemical techniques encompassing a wide array of disciplines is successfully being used to address key questions in archaeological research, including chronology, migration, trade, palaeopathology and palaeoenvironmental reconstructions. The aim of the session was to focus particularly on the developments in palaeodietary studies, which inform about population dynamics and socio-cultural characteristics of different communities over space and time. Biogeochemical techniques in particular have shown a remarkable adeptness at acquiring data from a variety of archaeological substrates, such as ceramics, lithics, textiles, sediments, plant remains, and human and animal ti…