0000000000479341
AUTHOR
Johann Troles
Microstructured Optical Fibers from As2S3 Glass for Fiber Optics Sources in the MIR range
International audience
Selenium Nanoparticles Synthesized via a Facile Hydrothermal Method
Crystalline selenium nanostructures were synthesized from the reaction of a GeSe3 glass with water at 85°C for 144 hours. The hydrolysis of the Ge-Se bonds releases Se fragments in the solution where they form a colloidal suspension of amorphous nanospheres. The later evolve toward a more stable hexagonal phase (trigonal) leading to the anisotropic growth of one-dimensional monocrystalline structures. Filaments, bars and tubes of monocrystalline trigonal selenium were obtained with diameters ranging from 10 nm to 1 µm and aspect ratio up to 180. This simple process in aqueous solution opens new perspectives for the synthesis of 1D nanoparticles of trigonal selenium at large scale.
Chalcogenide Microstructured Fibers for Infrared Systems, Elaboration, Modelization, and Characterization
special issue " Fiber Optic Research in France " (Part III of III); International audience; Chalcogenide fibers present numerous possible applications in the IR field. For many applications, single mode fibers must be obtained. An original way is the realization of microstructured optical fibers (MOFs) with solid core. These fibers present a broad range of optical properties thanks to the high number of freedom degrees of their geometrical structure. In this context, we have developed MOFs for near and mid IR transmission with different geometries and properties such as multimode or endless single-mode operation, small or large mode area fibers. We have also investigated numerically the mai…
Elaboration by casting method of low losses chalcogenide microstructured fibers for near and mid infrared applications
oral session C " Preparation and Property ", oral [TuA-16]; International audience
Aqueous Corrosion of the GeSe4 Chalcogenide Glass: Surface Properties and Corrosion Mechanism
International audience; The aqueous corrosion behavior of the GeSe4 glass composition has been studied over time under various conditions (temperature and pH). The evolution of the surface topography by atomic force microscopy and properties such as surface hardness and reduced modulus, as well as the optical transmission in the 1-16 μm window, have been measured as a function of time spent in the corrosive solution. It was found that even if the glass reacts at room temperature, its optical transparency was barely affected. Nevertheless, the durability of GeSe4 was found to be drastically affected by an increase of both temperature and pH. Furthermore, pure selenium nanoparticles were form…
Fiber-based optical functions for high-bit-rate transmissions
oral
Low losses highly non linear As2S3 suspended core microstructured optical fibers
International audience
Nonlinear effects above 2 µm in chalcogenide suspended core microstructured optical fibers: modeling and experiments
International audience
Recent developments in chalcogenide PCF
International audience
Caractérisation d'une fibre optique ultra non-linéaire en verre de chalcogénure
session orale 3 « Effets nonlinéaires » [Ma1.4], http://optiquelille2009.univ-lille1.fr/; National audience; Nous présentons les résultats expérimentaux concernant la caractérisation d'une fibre optique microstructurée en verre de chalcogénure de composition AsSe. Ces mesures concernent l'atténuation, la dispersion, l'aire effective et le coefficient non-linéaire du troisième ordre. Cette fibre présente un fort potentiel pour des applications non-linéaires avec un coefficient non-linéaire Kerr de 15 400 W-1m-1.
Small-core chalcogenide microstructured fibers for the infrared.
International audience; We report several small-core chalcogenide microstructured fibers fabricated by the "Stack & Draw" technique from Ge(15)Sb(20)S(65) glass with regular profiles. Mode field diameters and losses have been measured at 1.55 microm. For one of the presented fibers, the pitch is 2.5 microm, three times smaller than that already obtained in our previous work, and the corresponding mode field diameter is now as small as 3.5 microm. This fiber, obtained using a two step "Stack & Draw" technique, is single-mode at 1.55 microm from a practical point of view. We also report the first measurement of the attenuation between 1 and 3.5 microm of a chalcogenide microstructured fiber. …
Recent advances in the development of chalcogenide photonic crystal fibers.
International audience
Simulation of mid-IR amplification in Er3+-doped chalcogenide microstructured optical fiber
International audience; This paper deals with the design of an erbium doped microstructured optical fiber (MOF) amplifier operating in the mid-infrared (mid-IR) wavelength range, more precisely around 4.5 µm wavelength. A homemade numerical code which solves the rate equations and the power propagation equations has been ad hoc developed to theoretically investigate the feasibility of mid-IR MOF amplifier. On the basis of the measured energy level transition parameters of a Er3+-doped Ga5Ge20Sb10S65 chalcogenide glass, the amplifier feasibility is demonstrated exhibiting high gain and low noise figure.
Nonlinear effects above 2 µm in chalcogenide suspended core microstructured optical fibers: Modeling and experiments
We present our latest results on the linear and nonlinear modeling, and on the fabrication of chalcogenide suspended core microstructured optical fibers for mid-infrared generation. We focus on an AsSe glass composition. We have used a thulium-doped fiber laser to pump our fibers around 2 µm. In order to enhance further the nonlinearities and to manage the chromatic dispersion for supercontinuum application, we have tapered some of our microstructured optical fibers.
Infrared monitoring of underground CO2 storage using chalcogenide glass fibers
International audience; An optical-fiber-based system suitable for monitoring the presence of carbon dioxide, so-called "greenhouse gas", is investigated. Since each pollutant gas shows a characteristic optical absorption spectrum in the mid-infrared (mid-IR), it is possible to detect selectively and quantitatively the presence of gases in a given environment by analysing mid-IR spectra. The main infrared signature of carbon dioxide gas is a double absorption peak located at 4.2 μm. Chalcogenide optical fibers, which can transmit light in the 1-6 μm range, are well-adapted for CO2 analysis. In this wavelength range, they show attenuation losses that compare favourably with other types of fi…
Strong infrared spectral broadening in low-loss As-S chalcogenide suspended core microstructured optical fibers
Made available in DSpace on 2013-08-28T14:10:10Z (GMT). No. of bitstreams: 1 WOS000275454100017.pdf: 273411 bytes, checksum: da2aeaea61ab57013d39ecf2456466e3 (MD5) Made available in DSpace on 2013-09-30T19:22:36Z (GMT). No. of bitstreams: 2 WOS000275454100017.pdf: 273411 bytes, checksum: da2aeaea61ab57013d39ecf2456466e3 (MD5) WOS000275454100017.pdf.txt: 34647 bytes, checksum: b4efba760b21442eba43e7096f213b3e (MD5) Previous issue date: 2010-03-01 Submitted by Vitor Silverio Rodrigues (vitorsrodrigues@reitoria.unesp.br) on 2014-05-20T15:33:52Z No. of bitstreams: 2 WOS000275454100017.pdf: 273411 bytes, checksum: da2aeaea61ab57013d39ecf2456466e3 (MD5) WOS000275454100017.pdf.txt: 34647 bytes, ch…
Chalcogenide glass hollow core photonic crystal fibers
International audience; We report the first hollow core photonic crystal fibers (HC PCF) in chalcogenide glass. To design the required HC PCF profiles for such high index glass, we use both band diagram analysis to define the required photonic bandgap and numerical simulations of finite size HC PCFs to compute the guiding losses. The material losses have also been taken into account to compute the overall losses of the HC PCF profiles. These fibers were fabricated by the stack and draw technique from Te20As30Se50 (TAS) glass. The fibers we drew in this work are composed of six rings of holes and regular microstructures. Two profiles are presented, one is known as a kagome lattice and the ot…
Low loss microstructured chalcogenide fibers for large non linear effects at 1995 nm
International audience; Microstructured optical fibers (MOFs) are traditionally prepared using the stack and draw technique. In order to avoid the interfaces problems observed in chalcogenide glasses, we have developed a new casting method to prepare the chalcogenide preform. This method allows to reach optical losses around 0.4 dB/m at 1.55 µm and less than 0.05 dB/m in the mid IR. Various As(38)Se(62) chalcogenide microstructured fibers have been prepared in order to combine large non linear index of these glasses with the mode control offered by MOF structures. Small core fibers have been drawn to enhance the non linearities. In one of these, three Stokes order have been generated by Ram…
Elaboration and characterizations of solid core and holow core microstructured chalcogenide fibers
Symposium 25 " Glasses for Optoelectronic and Optical Applications ", Session " Glass Fibers " [PACRIM8-S25-039-2009]; International audience
Photonic crystal fibers from chalcogenide glasses for the mid infrared
International audience
Casting process for manufacturing a low loss chalcogenide photonic crystal fiber
International audience
Fourth-order cascaded Raman shift in AsSe chalcogenide suspended-core fiber pumped at 2 μm
International audience; Cascaded Raman wavelength shifting up to the fourth order ranging from 2092 to 2450nm is demonstrated using a nanosecond pump at 1995nm in a low-loss As38Se62 suspended-core microstructured fiber. These four Stokes shifts are obtained with a low peak power of 11W, and only 3W are required to obtain three shifts. The Raman gain coefficient for the fiber is estimated to (1.6 +-0.5)x 10e−11 m/W at 1995nm. The positions and the amplitudes of the Raman peaks are well reproduced by the numerical simulations of the nonlinear propagation.
Experimental investigation of Brillouin and Raman scattering in a 2SG sulfide glass microstructured chalcogenide fiber.
International audience; In this work, we investigate the Brillouin and Raman scattering properties of a Ge15Sb20S65 chalcogenide glass microstructured single mode fiber around 1.55 microm. Through a fair comparison between a 2-m long chalcogenide fiber and a 7.9-km long classical single mode silica fiber, we have found a Brillouin and Raman gain coefficients 100 and 180 larger than fused silica, respectively.
Recent advances in chalcogenide holey fibres
oral
Chalcogenide Photonic Crystal Fibers for Near and Middle Infrared Applications
Chalcogenide glasses are based on sulphur, selenium, tellurium and the addition of other elements such as arsenic, germanium, antimony, gallium, etc. Chalcogenide fibers present numerous applications in the IR field, such as telecommunication at 1.55 mum, spectroscopy and military systems in the two atmospherics windows (3-5 mum and 8-12 mum). One of the interests of chalcogenide glasses is to associate high non linear properties with their Infrared transmission from 0.51 mum to 12-18 mum depending on the composition. Indeed, chalcogenide glasses present high third order optical properties, 100 - 1000 times as high as the non linearity of silica glass at 1.55 mum. For many applications, sin…
Feasibility of Er3+-doped, Ga5Ge20Sb10S65 chalcogenide microstructured optical fiber amplifiers
International audience; The feasibility of a microstructured optical fiber (MOF) amplifier, made of a novel Er3+-doped chalcogenide glass, has been demonstrated via accurate simulations performed by employing an oppositely implemented computer code. The optical and geometrical parameters measured on the first MOF sample together with other physical constants from literature have been taken into account in the simulations. The calculated optical gain of the optimized MOF amplifier, 2.79 m long, is close to 23 dB at the signal wavelength of 1.538 μm, by using a pump power of 200 mW and a signal power of 0.1 μW.
Er3+-doped GeGaSbS glasses for mid-IR fibre laser application: Synthesis and rare earth spectroscopy
International audience; With an infrared transparency extended to 10 µm, low multiphonon relaxation rates and suitable rare earth solubility, sulphide glasses in the Ge-Ga-Sb-S system allow radiative emission from rare earth ions in the mid-IR range. The Er3+ ion, widely studied in glass fibres for optical amplification at 1.5 µm, presents an interesting transition for mid-IR applications around 4.5 µm (4I9/2→ 4I11/2). Thus, the aim of this work is to evaluate the Er3+-doped Ge20Ga5Sb10S65 glass as a potential fibre laser source operating in the 3-5 µm mid-IR spectral region. For that purpose, absorption and emission spectra were recorded from visible to mid-IR and the radiative lifetimes o…
Te-As-Se glass microstructured optical fiber for the middle infrared
International audience; We present the first fabrication, to the best of our knowledge, of chalcogenide microstructured optical fibers in Te-As-Se glass, their optical characterization, and numerical simulations in the middle infrared. In a first fiber, numerical simulations exhibit a single-mode behavior at 3.39 and 9.3 μm, in good agreement with experimental near-field captures at 9.3 μm. The second fiber is not monomode between 3.39 and 9.3 μm, but the fundamental losses are 9 dB/m at 3:39 μm and 6 dB/m at 9.3 μm. The experimental mode field diameters are compared to the theoretical ones with a good accordance.
Chalcogenide microstructured optical fibers : from linear to nonlinear properties
International audience; In this talk, we review the linear properties of chalcogenide microstructured optical fibers (MOFs) of several types. We mainly focus our talk on mid-infrared applications of such fibers. We start with the general properties of solid core MOFs made of these high index glasses and compare them with the ones of silica. Then, we give some details concerning a solid core MOF made of TAS glass. Next, we describe the first guiding suspended chalcogenide MOF and explain how it was designed for supercontinuum generation in the mid-infrared. Both linear and nonlinear properties of As2S3 suspended core MOFs are also numerically studied. In the next part, We describe the design…
Suspended core tellurite glass optical fibers for infrared supercontinuum generation
International audience; We report the fabrication and characterization of tellurite TeO(2)-ZnO-Na(2)O (TZN) microstructured suspended core optical fibers (MOFs). These fibers are designed for infrared supercontinuum generation with zero dispersion wavelength (ZDW) at 1.451 mu m. The measured losses at this wavelength are approximately 6 dB/m for a MOF with a 2.2 mu m diameter core. The effective area of a particular fiber is 3.5 mu m(2) and the nonlinear coefficient is calculated to be 437 W(-1)km(-1). By pumping a 20 cm long fiber at 1.56 mu m with a sub-nj femtosecond laser source, we generate a supercontinuum (SC) spanning over 800 nm in the 1-2 mu m wavelength range.
Microstructured chalcogenide optical fibers from As2S3 glass: towards new IR broadband sources
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