Magnetic Resonance Studies of the Heterogeneous Rotational and Translational dynamics in Disordered Materials

2008

Deuteron NMR investigations of glass and phase transitions in(KI)1−x(ND4I)xmixed crystals

1998

Powdered potassium ammonium iodide mixed crystals with ammonium concentrations of 20% and 70% have been studied using deuteron NMR techniques. For the less doped sample the deuteron line starts to broaden and the spin-lattice relaxation time ${T}_{1}$ becomes nonexponential below about 20 K. These observations indicate the breakdown of ergodicity and the onset of orientational glass freezing. At the lowest temperatures ${T}_{1}$ reaches a plateau value. For the 70% sample a relatively abrupt onset of two-phase behavior at $Tl35\mathrm{K}$ is inferred from measurements of the spin-spin and spin-lattice relaxation times. These observations are taken to indicate an order-disorder transition to…

Correlation of primary and secondary relaxations in a supercooled liquid

2006

The widespread assumption that primary and secondary relaxations in glass-forming materials are independent processes is scrutinized using spin-lattice relaxation weighted stimulated-echo spectroscopy. This nuclear magnetic resonance (NMR) technique is simultaneously sensitive to the dynamics on well-separated time scales. For the deeply supercooled liquid sorbitol, which exhibits a strong secondary relaxation, the primary relaxation (that is observable using NMR) can be modified by suppressing the contributions of those subensembles which are characterized by relatively slow secondary relaxations. This is clear evidence for a correlation between primary and secondary relaxation times. In t…

Phase transition kinetics and reorientational dynamics of the plastic crystal meta-carborane studied by deuteron NMR

2002

Meta-carborane shows an orientationally disordered, orthorhombic phase which transforms into an ordered monoclinic phase near 170 K and into a quasi-isotropic cubic phase near 280 K. From deuteron magnetization measurements both transitions are found to exhibit a thermal hysteresis and slow transformation kinetics. Furthermore, solid-echo NMR spectra and spin-lattice relaxation times are reported. These results indicate that in the orthorhombic phase the meta-carborane molecules perform a strongly anisotropic motion which is characterized by a temperature dependent amplitude.

Microscopic origin of the nonexponential dynamics in a glassy crystal

2003

The origin of the slow relaxation and of the dynamic heterogeneity is studied for an orientation-ally disordered crystal, orthocarborane, composed of quasi-icosahedrally shaped molecules. Multidimensional deuteron magnetic resonance reveals that large jump angles dominate their complex, anisotropic reorientational motion. It involves a sequence of small-angle tilts about locally preferred axes as well as symmetry adapted threefold jumps. The intrinsic dynamics of this glassy crystal is nonexponential and can be fully accounted for in terms of the tilt and jump motion.