0000000000515018

AUTHOR

Boštjan Zalar

showing 3 related works from this author

The orientational glass studied by nuclear magnetic resonance

1997

Single crystals of the orientational glass have been studied using iodine NMR for temperatures 1.8 K < T < 300 K. Two-dimensional spectroscopy has shown that the quadrupole-perturbed central transitions are predominantly inhomogeneously broadened. The orientational glass transition is already accompanied by a considerable increase of that broadening in the regime of fast motion. Evidence for a random-field smearing of the random-bond-induced freezing process is obtained. Measurements of the spin - lattice relaxation time reveal the existence of a broad distribution of orientational correlation times at low temperatures.

Nuclear magnetic resonanceCondensed matter physicsChemistryLattice (order)General Materials ScienceFast motionCondensed Matter PhysicsSpectroscopyOrientational glassJournal of Physics: Condensed Matter
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Surface-induced order and diffusion in 5CB liquid crystal confined to porous glass.

2001

Liquid crystals confined into small cavities are known to have a weak orientational order even above the nematic-isotropic transition temperature. The surface-induced order and molecular dynamics in this temperature range are studied with the aid of deuteron NMR spectra, spin relaxation times T(1) and T(2,) proton dipolar-correlation effect, and direct measurements of the effective diffusion coefficient for the liquid crystal 5CB confined to controlled-pore glasses. Our results show that an arrangement of molecules parallel to the wall is induced by local molecular interactions between the liquid crystal and solid, resulting in a weak and temperature independent surface order parameter, S(0…

Molecular diffusionMagnetic Resonance SpectroscopyProtonChemistryPolymersTransition temperatureDiffusionBiomedical EngineeringBiophysicsAnalytical chemistryTemperaturePorous glassAtmospheric temperature rangeDiffusionMolecular dynamicsLiquid crystalChemical physicsRadiology Nuclear Medicine and imagingGlassRheologyPorosityMagnetic resonance imaging
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Chemical disorder and Pb207 hyperfine fields in the magnetoelectric multiferroic Pb(Fe1/2Sb1/2)O3 and its solid solution with Pb(Fe1/2Nb1/2)O3

2018

We report on the results of magnetic susceptibility, electron paramagnetic resonance, and $^{207}\mathrm{Pb}$ nuclear magnetic resonance (NMR) studies of the magnetoelectric multiferroic $\mathrm{Pb}(\mathrm{F}{\mathrm{e}}_{1/2}\mathrm{S}{\mathrm{b}}_{1/2}){\mathrm{O}}_{3}$ (PFS) ceramic, as well as its solid solution with $\mathrm{Pb}(\mathrm{F}{\mathrm{e}}_{1/2}\mathrm{N}{\mathrm{b}}_{1/2}){\mathrm{O}}_{3}$ (PFN) of different degrees of the 1:1 ordering of magnetic $\mathrm{F}{\mathrm{e}}^{3+}$ and nonmagnetic $\mathrm{S}{\mathrm{b}}^{5+}$ ions. The ordering has been studied by x-ray diffraction (XRD) and NMR methods. In particular, two spectral lines, originating from the ordered and dis…

Fermi contact interactionMaterials scienceSpin glassPhysics and Astronomy (miscellaneous)Lattice (group)Order (ring theory)02 engineering and technology021001 nanoscience & nanotechnology01 natural sciencesMagnetic susceptibilityCrystallography0103 physical sciencesAntiferromagnetismGeneral Materials Science010306 general physics0210 nano-technologyHyperfine structureSolid solutionPhysical Review Materials
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