6533b822fe1ef96bd127d4dd

RESEARCH PRODUCT

The orientational glass studied by nuclear magnetic resonance

Robert BlincRoland BöhmerGerald HinzeBoštjan Zalar

subject

Nuclear magnetic resonanceCondensed matter physicsChemistryLattice (order)General Materials ScienceFast motionCondensed Matter PhysicsSpectroscopyOrientational glass

description

Single crystals of the orientational glass have been studied using iodine NMR for temperatures 1.8 K < T < 300 K. Two-dimensional spectroscopy has shown that the quadrupole-perturbed central transitions are predominantly inhomogeneously broadened. The orientational glass transition is already accompanied by a considerable increase of that broadening in the regime of fast motion. Evidence for a random-field smearing of the random-bond-induced freezing process is obtained. Measurements of the spin - lattice relaxation time reveal the existence of a broad distribution of orientational correlation times at low temperatures.

https://doi.org/10.1088/0953-8984/9/1/013