0000000000636941
AUTHOR
D. J. Pegg
Selective detection of 13C by laser photodetachment mass spectrometry
Abstract In this paper, we demonstrate how laser photodetachment mass spectrometry (LPMS) can be used to selectively detect 13C− ions in the presence of 12C− ions in a low energy ion beam. An isotopically enriched beam of carbon ions consisting of equal amounts of 13C− and 12C− ions was extracted from an ion source. The ions interacted with a laser beam in a collinear geometry over a distance of 70 cm. Residual atoms produced in the photodetachment process were detected in a neutral particle detector placed downstream of the collinear interaction region. By making use of the Doppler effect we were able to selectively photodetach 13C− ions. The number of detected 13C atoms was 13 times large…
The electron affinity of phosphorus
We have measured the energies of all three fine structure components in the 3PJ ground state of the negative ion of phosphorus using laser photodetachment threshold spectroscopy. The experiment yielded an electron affinity of 746.68(6) meV. The ΔJ = 2–0, 2–1 and 1–0 fine structure splittings were determined to be 32.73(7) meV, 22.48(7) meV and 10.25(3) meV, respectively. In the experiment, a mass selected beam of P− ions was merged with the output from a pulsed infrared optical parametric oscillator. The residual atoms produced in the photodetachment process were detected and used as a monitor of the photon-energy dependence of the relative cross section. The Wigner law was fitted to each o…
Laser photodetachment mass spectrometry
We demonstrate that the technique of laser photodetachment spectroscopy on atomic negative ions can be used as a sensitivity enhancement tool in mass spectrometry, useful for suppressing both isotopic as well as molecular isobaric interferences. In the experiment a beam of negative ions and a laser beam are merged in a collinear geometry and the wavelength of the laser is tuned across the photodetachment threshold region. Due to the large differential Doppler shifts associated with the fast moving ions of different masses, it is possible to selectively detach ions of certain isotopes while leaving others unaffected. By choosing co-propagating laser and ion beams, the heavier isotopes of an …
A graphene-based neutral particle detector
A neutral particle detector is presented, in which the traditionally used target material, indium tin oxide (ITO), is replaced by graphene. The graphene-based detector enables collinear photodetachment measurements at a significantly shorter wavelength of light down to 230 nm compared to ITO-based detectors, which are limited at 335 nm. Moreover, the background signal from the photoelectric effect is drastically reduced when using graphene. The graphene based detector, reaching 1.7 eV further into the UV energy range, allows increased possibilities for photodetachment studies of negatively charged atoms, molecules, and clusters.A neutral particle detector is presented, in which the traditio…
Experimental investigation of electron impact onSi2−
A merged beams technique has been used to investigate collisions between electrons and $\text{Si}_{2}{}^{\ensuremath{-}}$ ions over a relative kinetic energy range of 0--210 eV. Absolute cross sections for pure electron detachment, detachment plus dissociation, and dissociation involving atomic and ionic products were measured. The dominant process over the energy range studied is pure electron detachment. A search for a resonance associated with a ${\text{Si}}_{2}$ dianion was made but none was observed.