0000000000666982
AUTHOR
Andrew N. French
Thermal Infrared Emissivity Dependence on Soil Moisture in Field Conditions
An accurate estimate of land surface temperature, which is a key parameter in surface energy balance models, requires knowledge of surface emissivity. Emissivity dependence on soil water content has been already reported and modeled under controlled conditions at the laboratory. This paper completes and extends that previous work by providing emissivity measurements under field conditions without elimination of impurities, local heterogeneities, or soil cracks appearing in the drying process. The multispectral radiometer CE312-2, with five narrow bands and a broad band in the 8-13-μm range, was used, and surface emissivity values were determined through a temperature-emissivity separation a…
Catalytic Enantioselective α-Oxysulfonylation of Ketones Mediated by Iodoarenes
The alpha-oxysulfonylation of ketones catalysed by enantioenriched iodoarenes using mCPBA as stoichiometric oxidant is reported to give useful synthetic intermediates in good yield and modest enantioselectivity. We believe this to be the first report of an enantioselective organocatalytic reaction involving hypervalent iodine reagents which should open up a new field for enantioselective organocatalysis of oxidation reactions.