0000000000805637

AUTHOR

E.v. Vaschenko

showing 2 related works from this author

Studies on the proton acceptor ability of phosphoryl compounds

1996

Abstract Dipole moments and molar Kerr constants of complexes of phenols with phosphoryl compounds were studied to establish the structure of complexes and parameters characterizing the proton acceptor ability of these compounds. The structures of these complexes and parameters ( μ H , Δ ( mk ) S , log K and δ 0 ) were established. It has been suggested that a new parameter Δ ( mK ) S — structural additive difference of the molar Kerr constant — makes it possible to determine changes of polarity and polarizability of the systems during complex formation.

Kerr constantStereochemistryPolarity (physics)Organic ChemistryComplex formationAnalytical ChemistryInorganic ChemistryDipolechemistry.chemical_compoundCrystallographychemistryPolarizabilityPhenolsProton acceptorSpectroscopyJournal of Molecular Structure
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Studies on proton acceptor ability of SOx-containing compounds

1995

Abstract IR spectra, dipole moments and molar Kerr constants of complexes of phenols with compounds containing SO x groups were studied to establish the structure of the complexes and the parameters characterizing the proton acceptor capability of these compounds. ( μ H , Δ ( mK ), log K and δ 0 ). It has been suggested that the new parameter Δ ( mK ) — the structural additive difference of the molar Kerr constant — makes it possible to determine changes of polarity and polarizability of the systems during complex formation.

Kerr constantPolarity (physics)Organic ChemistryComplex formationAnalytical chemistryInfrared spectroscopyAnalytical ChemistryInorganic Chemistrychemistry.chemical_compoundDipolechemistryPolarizabilityPhysical chemistryPhenolsProton acceptorSpectroscopyJournal of Molecular Structure
researchProduct