6533b834fe1ef96bd129d4da

RESEARCH PRODUCT

Studies on the proton acceptor ability of phosphoryl compounds

V. V. PrezhdoE.v. VaschenkoOleg V. Prezhdo

subject

Kerr constantStereochemistryPolarity (physics)Organic ChemistryComplex formationAnalytical ChemistryInorganic ChemistryDipolechemistry.chemical_compoundCrystallographychemistryPolarizabilityPhenolsProton acceptorSpectroscopy

description

Abstract Dipole moments and molar Kerr constants of complexes of phenols with phosphoryl compounds were studied to establish the structure of complexes and parameters characterizing the proton acceptor ability of these compounds. The structures of these complexes and parameters ( μ H , Δ ( mk ) S , log K and δ 0 ) were established. It has been suggested that a new parameter Δ ( mK ) S — structural additive difference of the molar Kerr constant — makes it possible to determine changes of polarity and polarizability of the systems during complex formation.

yearjournalcountryeditionlanguage
1996-11-01Journal of Molecular Structure
https://doi.org/10.1016/s0022-2860(96)09402-1