0000000000819103

AUTHOR

Valerio Benfante

showing 10 related works from this author

Small angle scattering study of poly(methylmethacrylate)-blockpoly(ethylene oxide) block co-polymer in aqueous solution

2005

A combined Small Angle X ray (SAXS) and Neutron (SANS) Scattering study of aqueous solutions of a symmetric block copolymer consisting of poly(methyl methacrylate) (PMMA) and poly(ethylene oxide) (PEO) moieties is presented. The polymer forms slightly polydisperse spherical micelles in a wide range of concentration (0.03 – 6.7 w/V) and temperature (20°C ≤ T ≤ 65°C). A good description of the SANS data is obtained using a polydisperse core-shell model with a structure factor for a modified hard sphere potential. By increasing the concentration at constant T we observed a decrease of the aggregation number and an increase of solvation of PEO groups in the shell, opposite to what happens by in…

chemistry.chemical_classificationAggregation numberMaterials scienceAqueous solutionEthylene oxideSmall-angle X-ray scatteringtechnology industry and agricultureAnalytical chemistryConcentration effectPolymerMicellechemistry.chemical_compoundchemistryPolymer chemistryMethyl methacrylate
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Composition and corrosion phases of Etruscan Bronzes from Villanovan Age

2008

A neutron diffraction (ND) and neutron tomography (NT) study of laminated ancient bronzes was performed at the ISIS (Rutherford Appleton Laboratory, UK) neutron source and at the BENSC reactor (Hahn-Meitner Institut, Germany). The samples are part of an 8th century BC Etruscan collection discovered in the necropolises of Osteria-Poggio Mengarelli and Cavalupo in the Vulci area (Viterbo, Italy). The study allowed us to derive-in a totally non-destructive manner-information related to the main composition of the objects, possible presence of alterations and their nature, crusts and inclusions, as well as structure of the bulk. The presence of some components is linked to a variety of question…

working methodAncient bronzes; Chemical environment; Corrosion; Neutron diffraction; Neutron tomography; Structure of the bulk; Working methodsancient bronzebusiness.industryApplied MathematicsMetallurgyNeutron diffractionNeutron tomographySettore FIS/01 - Fisica SperimentaleChemical environmentSettore FIS/07 - Fisica Applicata(Beni Culturali Ambientali Biol.e Medicin)Neutron diffractionCorrosionAncient bronzesCorrosionNeutron tomographyOpticsNeutron sourceWorking methodsneutron diffraction neutron tomography ancient bronzes corrosion chemical environment working methods structure of the bulkStructure of the bulkbusinessInstrumentationEngineering (miscellaneous)Geology
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Ceramics, Marbles and Stones in the Light of Neutrons: Characterization by Various Neutron Methods

2016

In this chapter we give a brief overview of neutron based analytical investigations applied to study archaeological ceramics, and different types of stones. Since the vast majority of archaeological objects are made of ceramics and various stones—all are of geological origin—, one of the key objectives of these studies to determine the origin of raw material. This research is called provenance research, and a wide range of neutron based methods are applicable in it. Following a very basic, user-oriented description of the methods, we introduce examples from our everyday practice. The examples are about provenance of prehistoric stone tools, about the sources of 4th–3rd c. B.C. millennium li…

PrehistoryArchaeological ceramicsProvenanceMaterials scienceMineralogyNeutronPotteryCeramics Marbles Stones NeutronsArchaeologySettore CHIM/02 - Chimica FisicaCharacterization (materials science)
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Niccolo: a free software for chemistry laboratories management

2017

Niccolo is a multiusers chemicals database, furthermore, it helps you in the laboratory safety and waste management.

Settore CHIM/03 - Chimica Generale E Inorganicachemistry software lisp inventorySettore CHIM/02 - Chimica Fisica
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Small angle scattering study of poly(methylmethacrylate)-block-poly(ethylene oxide) block co-polymer in aqueous solution

2005

A combined Small Angle X ray (SAXS) and Neutron (SANS) Scattering study of aqueous solutions of a symmetric block copolymer consisting of poly(methyl methacrylate) (PMMA) and poly(ethylene oxide) (PEO) moieties is presented. The polymer forms slightly polydisperse spherical micelles in a wide range of concentration (0.03 – 6.7 w/V) and temperature (20°C ≤ T ≤ 65°C). A good description of the SANS data is obtained using a polydisperse core-shell model with a structure factor for a modified hard sphere potential. By increasing the concentration at constant T we observed a decrease of the aggregation number and an increase of solvation of PEO groups in the shell, opposite to what happens by in…

Small Angle Scattering Di-Block Copolymer Micelles Structuretechnology industry and agriculture
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Fingerprinting white marbles of archaeometric interest by means of combined SANS and USANS

2007

We have performed a series of USANS and SANS measurements on a selected group of marble samples characterized by similar chemical composition but wide range of known metamorphic conditions. With these samples we start the building up of a data base in an attempt to correlate metamorphism and mesoscopic structure of white marbles. Experimental data have been analysed in terms of a hierarchical model. The present data highlight the importance of the structure at meso scale in identifying the provenance of the marble samples. A remarkable simple relation between the model parameters and the metamorphic degree has been found. This curve might represent a master curve to allow fingerprinting of …

fractals | Neutron scattering | small-angle scattering
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Combined USANS/SANS Measurements in Archaeometry

2004

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Application of Neutron Techniques in Archaeometry

2005

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Archaeometric Applications of X-Ray and Neutron Techniques

2009

Cultural Heritage is part of our everyday life and its conservation is extremely important not only from the cultural point of view, but also from a practical one. This is particularly true for Italy, a country which lists the highest number of World Heritage sites. Italian heritage, largely embodied in buildings and works of art, has a wider range of interests. For example information buried in sunk ships is very important when trying to gain information on commercial routes, exchange of technology and similar. In the case of stones authentication of works of art in museums is also of great concern, particularly as a number of rather expensive fakes have been acquired by museums from dubio…

Cultural HeritageX-rayNeutron TechniquesArchaeometry
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Investigating large scale structures by combining small angle and ultra small angle neutron scattering

2005

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