0000000000860579

AUTHOR

Frans D. Tichelaar

showing 2 related works from this author

Downsizing of robust Fe-triazole@SiO2 spin-crossover nanoparticles with ultrathin shells

2019

A chemical protocol to design robust hybrid [Fe(Htrz)2(trz)](BF4)@SiO2 nanoparticles (NPs) with sizes as small as 28 nm and ultrathin silica shells below 3 nm has been developed. These NPs present a characteristic abrupt spin transition with a subsequent decrease in the width of the thermal hysteresis upon reducing the NP size.

Thermal hysteresisMaterials science010405 organic chemistrySpin transitionTriazoleNanoparticleQuímica010402 general chemistry01 natural sciences0104 chemical sciencesInorganic Chemistrychemistry.chemical_compoundchemistryChemical physicsSpin crossoverCompostos de coordinació
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Size-Dependent Spin Switching in Robust Fe-triazole@SiO2 Spin-Crossover Nanoparticles with Ultrathin Shell

2019

<p>A familly of chemically robust hybrid [Fe(Htrz)2(trz)](BF4)@SiO2nanoparticles (NPs) presenting different sizes (from ca. 90 to 28 nm) and an ultrathin silica shell (< 3 nm) have been prepared. All NPs present a characteristic abrupt spin transition with a subsequent decrease in the width of the thermal hysteresis upon reducing the NP size.<br></p>

chemistry.chemical_compoundThermal hysteresisMaterials scienceCondensed matter physicschemistrySpin crossoverSize dependentSpin transitionTriazoleShell (structure)NanoparticleSpin-½
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