6533b837fe1ef96bd12a3315
RESEARCH PRODUCT
Downsizing of robust Fe-triazole@SiO2 spin-crossover nanoparticles with ultrathin shells
Eugenio CoronadoHenny W. ZandbergenMónica Giménez-marquésFrans D. TichelaarL. Lima-moyaRamón Torres-cavanillassubject
Thermal hysteresisMaterials science010405 organic chemistrySpin transitionTriazoleNanoparticleQuímica010402 general chemistry01 natural sciences0104 chemical sciencesInorganic Chemistrychemistry.chemical_compoundchemistryChemical physicsSpin crossoverCompostos de coordinaciódescription
A chemical protocol to design robust hybrid [Fe(Htrz)2(trz)](BF4)@SiO2 nanoparticles (NPs) with sizes as small as 28 nm and ultrathin silica shells below 3 nm has been developed. These NPs present a characteristic abrupt spin transition with a subsequent decrease in the width of the thermal hysteresis upon reducing the NP size.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2019-01-01 |