0000000000948799

AUTHOR

Jean Marie Bernard

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Lanthanide bis(trifluoromethylsulfonyl)amides vs. trifluoromethylsulfonates as catalysts for Friedel–Crafts acylations

2002

Abstract The use of catalytic amounts: 1 mol% or less of perfluoroalkyl lanthanide salts as homogeneous catalysts for Friedel–Crafts acylations in non-hazardous solvents is thereafter investigated. Lanthanide bis(trifluoromethylsulfonyl)amides are better catalysts than the triflate analogues towards the acetylation of activated aromatic rings.

LanthanideProcess Chemistry and TechnologyEtherHomogeneous catalysisAnisoleCatalysisCatalysischemistry.chemical_compoundchemistryLanthanide trifluoromethanesulfonatesOrganic chemistryPhysical and Theoretical ChemistryFriedel–Crafts reactionTrifluoromethanesulfonateJournal of Molecular Catalysis A: Chemical
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