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RESEARCH PRODUCT
Lanthanide bis(trifluoromethylsulfonyl)amides vs. trifluoromethylsulfonates as catalysts for Friedel–Crafts acylations
Jean Roger DesmursAlain DormondFanny DurisJean Marie BernardDenise Barbier-baudrysubject
LanthanideProcess Chemistry and TechnologyEtherHomogeneous catalysisAnisoleCatalysisCatalysischemistry.chemical_compoundchemistryLanthanide trifluoromethanesulfonatesOrganic chemistryPhysical and Theoretical ChemistryFriedel–Crafts reactionTrifluoromethanesulfonatedescription
Abstract The use of catalytic amounts: 1 mol% or less of perfluoroalkyl lanthanide salts as homogeneous catalysts for Friedel–Crafts acylations in non-hazardous solvents is thereafter investigated. Lanthanide bis(trifluoromethylsulfonyl)amides are better catalysts than the triflate analogues towards the acetylation of activated aromatic rings.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2002-09-01 | Journal of Molecular Catalysis A: Chemical |