Morphometric analysis of the shells of the Genus Bolivina from the Gulf of Gela (Sicilian Channel, Italy): a valid classification instrument?

Mapping the centers performing endocrine neck surgery in Italy

Background. Quality of care and provider’s experience seem to be strictly connected in any field of surgery. Aim of this study is to identify a method to classify the centers on the basis of the number of thyroidectomies and parathyroidectomies performed. Methods. We listed 666 centers performing endocrine neck surgery in 2015, from the database of the Italian Health Ministry. We performed a descriptive statistic analysis with a dedicated software. We identified the outliers, according to a previous literature review, in those centers performing >1000 and < 10 thyroidectomies, >100 and < 3 parathyroidectomies and we excluded them to our analysis. The remaining centers were group…

Wind forcing and fate of <i>Sardinella aurita</i> eggs and larvae in the Sicily Channel (Mediterranean Sea)

Abstract. Multidisciplinary studies are recently seeking to define diagnostic tools for fishery sustainability by coupling ichthyoplanktonic datasets, physical and bio-geochemical oceanographic measurements, and ocean modelling. The main goal of these efforts is the understanding of those processes that control fate and dispersion of fish larvae and eggs and thus tune the inter-annual variability of biomass of fish species. We here analyzed eggs and larvae distribution and biological features of Sardinella aurita in the northeast sector of the Sicily Channel (Mediterranean Sea) collected during the 2010 and 2011 summer cruises. We make use of satellite sea surface temperature, wind, and chl…

Distribution of REEs in box-core sediments offshore an industrial area in SE Sicily, Ionian Sea: Evidence of anomalous sedimentary inputs

The distribution of rare earth elements and yttrium (REEs+Y) has been investigated in box-core sediments recovered from four stations in the Sicilian coastal zone seawards of Augusta, one of the most industrialized and contaminated areas in the Mediterranean region. Shale-like REE patterns and low Y/Ho ratios (close to the chondritic ratio) suggest a dominant terrigenous (geogenic) source for REE. Slight enrichment of LREE over the HREE is interpreted as due to preferential adsorptive transfer of LREE from seawater to sediment particles. Samples from offshore cores exhibit slightly positive Gd and negative Ce anomalies. It is here hypothesized that main drivers of anthropogenic Gd flux towa…

Large deep-seated slump structure off Ischia volcanic island, Eastern Tyrrhenian sea (Italy)

Ischia island is located over the Campania sector of Eastern Tyrrhenian margin and represents the sub-aerial section of a larger, E-W trending volcanic ridge including others submerged or buried volcanic edifices. The island itself result from the coalescence of a multitude of small to medium scale eruptions leading to the emplacement of domes, lava flow and pyroclastic deposits and ignimbrites (VEZZOLI et al., 1988) ranging from alkali basalts to trachytes. The oldest basement dates back to 150 ky and crops out along the perimeter of the island especially to the south. Latest eruption occurred in 1302 A.D. and together with strong hydrothermal activity, ground uplift and seismic shaking in…

A new method to valued efficiency of enzyme blend for pancreas tissue digestion.

One of the best successful example of cell therapy is represented by islet transplantation since the '90. However islet isolation methods are not completely standardized yet. More than half of isolation procedures failed to isolate adequate islets for transplantation, due to variable pancreas condition, and to unpredictable enzymatic blend efficiency. Enzymes used for pancreas digestion are purified from Clostridium histolyticum; these enzymes has a broad substrate specificity and potent collagenolytic activity compared to vertebrate collagenases. However, a major obstacle in human islet isolation successful is due to the variability in composition and concentration of the collagenases used…

A Gaussian model for evaluating the release of CH4 by the landfill of Palermo

Many landfills for urban solid waste have been developed in sites very close to urbanised areas thus exposing the population to various dangerous pollutants. The landfill of "Bellolampo", located a few kilometres from the city ofPalermo is one of these. It was officially created in the eighties and only some years later it was decided convert it into a controlled landfill, soon becoming a catch basin of refuse for a large hinterland constituted by approximately 50 small towns. In recent years the city of Palermo has been equipped with a network of weather and air-quality stations for monitoring the main components that afe responsible for atmospheric pollution; it consists of 10 fixed stati…

First data on hydrobiological characterization of western Libyan sea area (August 2006)

Mercury in fishes from Augusta Bay (southern Italy): risk assessment and health implication

Our study reports on the total mercury (HgT) concentrations measured in the muscles and livers of several benthic, demersal and pelagic fish species caught inside and outside of Augusta Bay (southern Italy), a semi-enclosed marine area, highly contaminated by the uncontrolled (since the 1950s to 1978s) discharge of the largest European petrochemical plant. Mercury levels in fish tissues are discussed with regard to specific habitat, size and/or age of the specimens and HgT distribution in the bottom sediments. Results suggest a still active Hg release mechanism from the polluted sediments to the marine environment. Also, the high HgT concentrations measured in fishes caught in the external …

Dynamics at the Strait of Sicily and Mediterranean Sapropels

Comparative study on enzymatic activity and molecules stability of some commercial proteolytic enzymes used in pancreatic islet isolation.

In pancreatic islets purification, for cell therapy applications, the major enzymes used are obtained from Clostridium hystoliticum; class I and class II collagenases (COLL G and COLL H). They are used in a defined tissue dissociation enzyme (TDE) mixtures together neutral protease (Dispase) or thermolysin (Thermostable Neutral Protease). The TDE mixtures were in part responsible for the success of the Edmonton protocol; however, just to now, people working in islets purification found discrepancy in an application to another one. This variability in application see in the enzymatic blend composition the higher accused, such as the contamination from endotoxines due to extractive production…

Mercury levels in sediments of central Mediterranean Sea: a 150+ year record from box-cores recovered in the Strait of Sicily.

To evaluate the degree of anthropogenic mercury pollution, Hg contents have been measured for box-core sediments sampled along three nearshore-offshore transects in the Strait of Sicily and well constrained for their mineralogy, bulk geochemistry and TOC%. Hg values are generally low (from 15 to 70 microg kg(-1)); however, depth profiles clearly display upcore rising concentrations (up to 202 microg kg(-1) near the SE Sicily coast) that are attributed to anthropogenic load. Based on (210)Pb chronology, these trends are more dramatic across the last 20-30 years. Geogenic influence is thought to explain some anomalies related to volcanic emission and geothermal activity. Combined effects due …

Calcareous nannofossil surface sediment assemblages from the SicilyChannel (central Mediterranean Sea): palaeoceanographic implications.

Quantitative analysis of 67 calcareous nannofossil assemblages from surface sediments recovered in a wide area across the Sicily Channel has been carried out in order to improve the interpretation of palaeontological data based on this planktonic group in a key area for Mediterranean palaeoceanographic studies. The investigation focused on three case studies that demonstrate the high potentiality of such a combined approach, taking into account the recent distribution of taxa or groups of taxa on the sea floor and the palaeontological record. The distribution of reworked specimens over the northern Sicily Channel sea floor validates the role of southern Sicily as a source region for reworke…

Linking ecological and physical features in the Strait of Sicily preliminary results of air - sea interaction.

Stima dei flussi di calore latente e sensibile in differenti aree del Mediterraneo Centrale, attraverso strumentazione acustica e tradizionale.

Distribution and air-sea exchange of mercury (Hg) in polluted marine environments

Mercury (Hg) is emitted in the atmosphere by anthropogenic and natural sources, these last accounting for one third of the total emissions. Since the pre-industrial age, the atmospheric deposition of mercury have increased notably, while ocean emissions have doubled owing to the re-emission of anthropogenic mercury. Exchange between the atmosphere and ocean plays an important role in cycling and transport of mercury. We present the preliminary results from a study on the distribution and evasion flux of mercury at the atmosphere/sea interface in the Augusta basin (SE Sicily, southern Italy), a semi-enclosed marine area affected by a high degree of contamination (heavy metals and PHA) due to…

TRACE ELEMENT BEHAVIOUR IN SEAWATER DURING PYROCLASTIC ETNA'S ACTIVITY IN 2001. CONCURRENT EFFECTS OF NUTRIENTS AND FORMATION OF ALTERATION MINERALS

From July 13 2001 began the most intense Etna's eruptive activity in the last 300 years. While this phenomenon occurred the oceanographic cruise ANSIC 01 was carrying out. Therefore the unique opportunity is arisen to investigate the chemical effects on marine system of delivery of large amount of pyroclastic particles (about 1 g m-2) into seawater. Comparing collected trace element data with those analysed during the oceanographic cruise JUVENILE 99, carried out two years before, large enrichments in V, Cr, Mn, Fe, Co, Cu and Pb contents have been recognised and attributed to leaching of freshly-erupted volcanic ash. Further comparison between to-day and previous collected trace element da…

Study of benthic foraminifera in the Continental Shelf of the Gulf of Gela (Sicilian Channel) and their possible use as bioindicators

Role of prophylactic central neck dissection in cN0-papillary thyroid carcinoma: Results from a high-prevalence area

BACKGROUND: Prophylactic, compartment-oriented central neck dissection (CND) for cN0 papillary thyroid carcinoma (PTC) is not widely practiced. We examined our results with this surgical approach. METHODS: A cohort of 158 patients operated on for the classical variant of PTC at a follow-up of 1-22 years (mean: 6.6) were enrolled. The patients with a preoperative diagnosis of cN0 PTC (group A, 59 patients) underwent total thyroidectomy (TT) + CND. In the patients with incidental postoperative diagnosis of malignancy (group B, 99 patients) a TT alone was performed. RESULTS: Ninety-six T1, 36 T2, 26 T3/T4 PTC patients were enrolled. The overall biochemical/scintigraphic recurrence rate (15 pat…

The sea–air exchange of mercury (Hg) in the marine boundary layer of the Augusta basin (southern Italy): Concentrations and evasion flux

Abstract The first attempt to systematically investigate the atmospheric mercury (Hg) in the MBL of the Augusta basin (SE Sicily, Italy) has been undertaken. In the past the basin was the receptor for Hg from an intense industrial activity which contaminated the bottom sediments of the Bay, making this area a potential source of pollution for the surrounding Mediterranean. Three oceanographic cruises have been thus performed in the basin during the winter and summer 2011/2012, where we estimated averaged Hg atm concentrations of about 1.5 ± 0.4 (range 0.9–3.1) and 2.1 ± 0.98 (range 1.1–3.1) ng m −3 for the two seasons, respectively. These data are somewhat higher than the background Hg atm …

The nucleic acid binding protein PcCNBP is transcriptionally regulated during the immune response in red swamp crayfish Procambarus clarkii

Cellular nucleic acid binding proteins (CNBPs) represent a highly conserved protein family among vertebrates; they harbour seven tandem zinc finger repeats CCHC type and have been described as transcriptional and translational regulators. To date, there is little characterization of CNBP in invertebrates since its structure and function have been analysed solely in Drosophila melanogaster. However, no CNBP has been investigated in other arthropod systems. In an effort to isolate immune-related genes in Procambarus clarkii, a partial mRNA coding a zinc finger containing protein was found to be up-regulated during the response to white spot syndrome virus (WSSV) infection. The red swamp crayf…

Distribution of rare earth elements in marine sediments from the Strait of Sicily (western Mediterranean Sea): Evidence of phosphogypsum waste contamination

Concentrations of rare earth elements (REE), Y, Th and Sc were recently determined in marine sediments collected using a box corer along two onshore–offshore transects located in the Strait of Sicily (Mediterranean Sea). The REE + Y were enriched in offshore fine-grained sediments where clay minerals are abundant, whereas the REE + Y contents were lower in onshore coarse-grained sediments with high carbonate fractions. Considering this distribution trend, the onshore sediments in front of the southwestern Sicilian coast represent an anomaly with high REE + Y concentrations (mean value 163.4 lg g 1) associated to high Th concentrations (mean value 7.9 lg g 1). Plot of shale-normalized REE + …

A novel method to simulate the 3D chlorophyll distribution in marine oligotrophic waters

Abstract A 3D advection-diffusion-reaction model is proposed to investigate the abundance of phytoplankton in a difficult-to-access ecosystem such as the Gulf of Sirte (southern Mediterranean Sea) characterized by oligotrophic waters. The model exploits experimentally measured environmental variables to reproduce the dynamics of four populations that dominate phytoplankton community in the studied area: Synechococcus, Prochlorococcus HL, Prochlorococcus LL and picoeukaryotes. The theoretical results obtained for phytoplankton abundances are converted into chl-a and Dvchl-a concentrations, and the simulated vertical chlorophyll profiles are compared to the corresponding experimentally acquir…

Authigenic phases and biomass contents drive Zr, Hf and REE distributions in anoxic lake sediments.

Abstract. REE, Zr and Hf distributions in seafloor sediments collected from the hypersaline, anoxic Thetis, Kryos, Medee and Tyro deep-sea basins from the Eastern Mediterranean were determined in light of their mineralogical composition, and biomass contents. Mineralogical investigations demonstrate that all the studied sediments show a similar mineralogy. Detritic assemblages mainly consist of quartz, gypsum and calcite with Mg contents ranging from 0 to about 7%, often of a bioclastic nature. On the contrary, authigenic parageneses are formed by halite, bischofite, dolomite and calcite, with Mg contents up to 22%. Textural evidences of biological activity were also identified. In sediment…

CALYPSO: LA RETE RADAR HF PER IL MONITORAGGIO DELLE CORRENTI MARINE SUPERFICIALI NEL CANALE TRA LA SICILIA E MALTA (MAR MEDITERRANEO)

Il canale tra le isole di Sicilia e Malta si trova in una delle principali rotte marittime del Mediterraneo e in una regione strategica per le piattaforme di estrazione petrolifera, quindi seriamente esposta al rischio di eventi di sversamento di idrocarburi in mare. Ciò può costituire una grave minaccia agli ecosistemi locali e alle attività economiche, tra le quali il turismo e la pesca. I danni derivanti da un eventuale sversamento sarebbero incalcolabili per l'arcipelago maltese, dove le risorse marine ed il turismo rappresentano i principali proventi economici e, in maniera analoga, per la Sicilia. Le misure di prevenzione e di mitigazione, insieme a un rapido intervento e a un process…

Authigenic phase formation and microbial activity control Zr, Hf, and rare earth element distributions in deep-sea brine sediments

Abstract. Sediments collected from hypersaline and anoxic deep-sea basins in the eastern Mediterranean (Thetis, Kryos, Medee, and Tyro) were characterised in terms of their mineralogical composition, the distributions of rare earth elements (REE), Zr, and Hf and their content of microbial DNA. We identified two major mineralogical fractions: one fraction of detritic origin was composed of quartz, gypsum, and low-Mg calcite bioclasts (with 0 < Mg < 0.07%) and another fraction of authigenic origin constituted of halite, dolomite, high-Mg calcite (with a Mg content of up to 22%) and rare bischofite and showed a textural evidence of microbial assemblages. We found that in the Medee and Ty…

Influence of dissolved organic matter on rare earth elements and yttrium distributions in coastal waters

International audience; Data collected during this study indicate that dissolved Y and REE (rare earth element) behaviour can be monitored through shale-normalised ratios. Relationships occurring between these ratios suggest that leaching from lithogenic materials is the main source of REE in the studied area. This process involves riverine detrital matter in the inner area of the Gulf of Palermo. Features of shale-normalised patterns and the relationship recognised between dissolved Fe and Y/Ho suggest that REE are released from Fe-rich coatings of atmospheric dust. Observed similarities between dissolved Fe and chlorophyll- content suggest that leaching of Fe-rich atmospheric particulates…

Eastern Mediterranean Transient-type events over the last five centuries

Studio delle tanatocenosi a foraminiferi bentonici nel Golfo di Gela

THE EFFECT OF HEAVY METALS ON BENTHIC FORAMINIFERA IN THE GULF OF GELA (SICILIAN CHANNEL)

Benthic foraminifera are very sensitive to oceanographic parameter variations, to which they rapidly response through changes in the abundance and/or richness of their associations and in morphological variations of their shell. Many studies have used benthic foraminifera as bioindicators. We investigated recent benthic foraminiferal assemblages in the Gulf of Gela (Sicilian Channel, Mediterranean Sea), examining their relative abundance, specific richness and morphological abnormalities, to highlight a possible correlation with oceanographic features and the concentration of heavy metals in sediments. Sediment was sampled in summer 2006 using box corers in four stations at increasing dista…

Identification of proteolytic enzymes from Eriphia verrucosa and Palinurus elephas capable to degrade gliadin

In small intestinal disease, coeliac sprue, proline-rich gluten peptides from wheat, rye and barley are relatively resistant to gastrointestinal digestion, and therefore remain in the intestinal lumen to elicit immunopathology in genetically susceptible individuals. Since most serine endopeptidases are unable to hydrolyse proline residues, proline specific proteases may be therapeutic keys in digestive diseases. Partial hydrolysis reduces the risk of allergenic sensitization while total hydrolysis ensures the elimination of the allergenicity of whey protein (Villad´oniga and others 2007). Kimoto and others (1998) reported that 18-, 31-, 37- and 58-kDa wheat allergens were recognized by the …

Stima dei flussi energetici all’interfaccia aria-mare con l’impiego di SST da Satellite e dati rilevati in situ.

La conoscenza dei flussi energetici scambiati fra oceano e bassa atmosfera è un requisito utile per modellare e comprendere il sistema climatico e la dinamica degli oceani. L’elevata difficoltà di effettuare misure in situ ed in continuo in ambiente marino induce spesso all’utilizzo ausiliario di strumentazione satellitare. Nel presente lavoro è stato effettuato un confronto tra la stima dei flussi energetici superficiali valutati con dati provenienti da satellite e quelli ottenuti da misure in situ. In particolare, per il confronto, sono stati utilizzati i dati SST acquisiti dal satellite NOAA e i dati raccolti in situ dai sensori istallati a bordo della Nave Oceanografica Urania nel corso…

PICOPHYTOPLANKTON DYNAMICS IN NOISY MARINE ENVIRONMENT

We present a stochastic reaction-diffusion-taxis model to describe the picophytoplankton dynamics along a water column. The model, which is valid for poorly mixed waters, typical of the Mediterranean Sea, considers intraspecific competition of picophytoplankton for light and nutrients. Random fluctuations of environmental variables are taken into account by adding a source of multiplicative noise to the diffusion equation for the picophytoplankton biomass concentration, whose distribution along the water column shows a maximum at a certain depth. After converting our results into chlorophyll a concentrations, we compare theoretical distributions, obtained for different noise intensities, wi…

CALYPSO: a new HF RADAR network to monitor sea surface currents in the Malta-Sicily channel (Mediterranean sea)

Located in one of the main shipping lanes in the Mediterranean Sea, and in a strategic region for oil extraction platforms, the Malta-Sicily channel is exposed to significant oil spill risks. Shipping and extraction activities constitute a major threat for marine areas of relevant ecological value in the area, and impacts of oil spills on the local ecosystems and the economic activities, including tourism and fisheries, can be dramatic. Damages would be even more devastating for the Maltese archipelago, where marine resources represent important economic assets. Additionally, North Africa coastal areas are also under threat, due to their proximity to the Malta-Sicily Channel. Prevention and…

Linking air–sea energy fluxes and European anchovy potential spawning ground.

The physical and chemical processes of the sea greatly affect the reproductive biology of fishes, mainly influencing both the numbers of spawned eggs and the survivorship of early stages up to the recruitment period. In the central Mediterranean, the European anchovy constitutes one of the most important fishery resource. Because of its short living nature and of its recruitment variability, associated to high environmental variability, this small pelagic species undergo high interannual fluctuation in the biomass levels. Despite several efforts were addressed to characterize fishes spawning habitat from the oceanographic point of view, very few studies analyze the air-sea exchanges effects…

Two-species model for spatial distributions of sardine and anchovy: A comparison with real data

We present a study of pattern formation in a set of two coupled equations modeling two competing species. We consider generalized Lotka-Volterra equations in the presence of a multiplicative noise which models the interaction between the species and the environment. The interaction parameter between the species is a random process which obeys a stochastic differential equation with a generalized bistable potential in the presence of a periodic driving term, which accounts for the environment temperature variation.We find noise-induced spatial patterns with strong anti-correlation between the two species. We compare our theoretical results with the experimental data of the spatial distributi…

A new method to valued efficiency of enzyme blends for pancreas tissue digestion

One of the best successful examples of cell therapy is represented by islet transplantation since 1990. However islet isolation methods are not completely standardized yet. More than half of isolation procedures failed to isolate adequate islets for transplantation, due to variable pancreas conditions and to unpredictable enzymatic blend efficiency. Enzymes used for pancreas digestion include collagenases and neutral proteases: their composition and activity are largely variable between different batches. We set up a new in vitro method to better in vitro characterize enzymatic blend before its use in human pancreas. In our experimental approach human immortalized cells (ECV-304) or human is…

Trace elements release from volcanic ashes to seawater. Natural concentrations in Central Mediterranean sea.

Distributions and concentrations of many minor and trace elements in epicontinental basins, as Mediterranean Sea, are mainly driven to atmospheric fallout from surroundings. This mechanism supplies an estimated yearly flux of about 1000 kg km-2 of terrigenous matter of different nature on the whole Mediterranean basin. Dissolution of these materials and processes occurring at solid-liquid interface along the water column drive the distributions of many trace elements as V, Cr, Mn, Co, Cu, and Pb with contents ranging from pmol l-1 (Co, Cd, Pb) to nmol l-1 scale in Mediterranean seawater, with some local differences in the basin. The unwinding of an oceanographic cruise in the coastal waters…

Il Registro incontra i Sindaci: l’iniziativa di comunicazione del Registro Tumori di Palermo e Provincia

Registri Tumori; epidemiologia tumori; comunicazione rischio oncologico