0000000001299094
AUTHOR
Kamran T. Mahmudov
showing 15 related works from this author
ChemInform Abstract: Metal-Free Regioselective C-C Bond Cleavage in 1,3,5-Triazine Derivatives of β-Diketones.
2014
The reaction of cyanuric chloride (I) with 3 equivalents of ketones (II) in the presence of 3 equivalents of KOH affords adducts (IV), which are converted into deacylated derivatives (III) by treatment with aqueous HCl solution in MeOH.
Aqua complex of iron(III) and 5-chloro-3-(2-(4,4-dimethyl-2,6- dioxocyclohexylidene) hydrazinyl)-2-hydroxybenzenesulfonate: Structure and catalytic a…
2013
Abstract A water-soluble iron(III) complex [Fe(H2O)3(L)]·5H2O (1) was prepared by reaction of iron(III) chloride with 5-chloro-3-(2-(4,4-dimethyl-2,6-dioxocyclohexylidene)hydrazinyl)-2-hydroxy-benzenesulfonic acid (H3L). The complex was characterized by IR, 1H NMR and ESI-MS spectroscopies, elemental and X-ray crystal structural analyses. The coordination environment of the central iron(III) is a distorted octahedron, three sites being occupied by L3− ligand, which chelates in O,N,O fashion, while three other sites are filled with the water molecules. The uncoordinated water molecules are held in the channels of the overall 3D supramolecular structure by the carbonyl and sulfonyl groups of …
Co(II)-mediated synthesis of 2-carbamimidoylbenzoates and isoindole-1,3-diaminates
2015
Abstract Phthalonitrile, acetoxime and cobalt(II) nitrate hexahydrate are combined in acetone with formation of stable and easy to handle Co(II) complex [Co{C6H4C(NH2)NC(ONCMe2)2}2](NO3)2 (1). Interaction of 1 with excess alcohols ROH (also used as solvents) and 2 equiv of (NH4)2S leads, in one-step, to alkyl 2-carbamimidoylbenzoate nitrates [C6H4COOR{2-C(NH2)2}]NO3 [R=CH3, C2H5, C3H7, CH(CH3)2]. Similarly, N1,N3-dialkyl-1H-isoindole-1,3-diaminate nitrates [C6H4C(NR′)NC(NR′)]NO3 [R=C3H7, C4H9, C(CH3)3, CH2CH2OH, CH2CH2SC2H5) can be directly produced from 1 by its reaction with 4 equiv of amines and 2 equiv of (NH4)2S in alcoholic media.
Metal-free regioselective C–C bond cleavage in 1,3,5-triazine derivatives of β-diketones
2014
Metal-free regioselective activation of a carbon–carbon bond in 1,3,5-triazine derivatives of β-diketones is easily achieved, in the absence of a catalyst, with the assistance of intramolecular hydrogen bonding.
CCDC 919328: Experimental Crystal Structure Determination
2013
Related Article: Kamran T. Mahmudov, Maximilian N. Kopylovich, Matti Haukka, Gunay S. Mahmudova, Espandi F. Esmaeila, Famil M. Chyragov, Armando J.L. Pombeiro|2013|J.Mol.Struct.|1048|108|doi:10.1016/j.molstruc.2013.05.041
CCDC 1030478: Experimental Crystal Structure Determination
2015
Related Article: Maximilian N. Kopylovich, Matti Haukka, Kamran T. Mahmudov|2015|Tetrahedron|71|8622|doi:10.1016/j.tet.2015.09.020
CCDC 1030479: Experimental Crystal Structure Determination
2015
Related Article: Maximilian N. Kopylovich, Matti Haukka, Kamran T. Mahmudov|2015|Tetrahedron|71|8622|doi:10.1016/j.tet.2015.09.020
CCDC 880877: Experimental Crystal Structure Determination
2013
Related Article: Maximilian N. Kopylovich, Kamran T. Mahmudov, Matti Haukka, Armando J. L. Pombeiro|2014|New J.Chem.|38|495|doi:10.1039/C3NJ01292A
CCDC 1030481: Experimental Crystal Structure Determination
2015
Related Article: Maximilian N. Kopylovich, Matti Haukka, Kamran T. Mahmudov|2015|Tetrahedron|71|8622|doi:10.1016/j.tet.2015.09.020
CCDC 880876: Experimental Crystal Structure Determination
2013
Related Article: Maximilian N. Kopylovich, Kamran T. Mahmudov, Matti Haukka, Armando J. L. Pombeiro|2014|New J.Chem.|38|495|doi:10.1039/C3NJ01292A
CCDC 1030485: Experimental Crystal Structure Determination
2015
Related Article: Maximilian N. Kopylovich, Matti Haukka, Kamran T. Mahmudov|2015|Tetrahedron|71|8622|doi:10.1016/j.tet.2015.09.020
CCDC 1030484: Experimental Crystal Structure Determination
2015
Related Article: Maximilian N. Kopylovich, Matti Haukka, Kamran T. Mahmudov|2015|Tetrahedron|71|8622|doi:10.1016/j.tet.2015.09.020
CCDC 1030483: Experimental Crystal Structure Determination
2015
Related Article: Maximilian N. Kopylovich, Matti Haukka, Kamran T. Mahmudov|2015|Tetrahedron|71|8622|doi:10.1016/j.tet.2015.09.020
CCDC 1030482: Experimental Crystal Structure Determination
2015
Related Article: Maximilian N. Kopylovich, Matti Haukka, Kamran T. Mahmudov|2015|Tetrahedron|71|8622|doi:10.1016/j.tet.2015.09.020
CCDC 1030480: Experimental Crystal Structure Determination
2015
Related Article: Maximilian N. Kopylovich, Matti Haukka, Kamran T. Mahmudov|2015|Tetrahedron|71|8622|doi:10.1016/j.tet.2015.09.020