0000000001302914

AUTHOR

H. Kunz

showing 20 related works from this author

A compact apparatus for mass selective resonance ionization spectroscopy in a buffer gas cell

1997

Abstract An ultra-sensitive laser spectroscopic method for the investigation of transuranium nuclides has been developed based on resonance ionization in an argon buffer gas cell. This method has been combined with ion-guide extraction and mass selective direct detection of the resonantly ionized atoms. Using argon as a buffer gas, recoils of fusion reactions can be thermalized even at low pressure. The differential pumping system consists of only one roots pump and two turbo molecular pumps. The set-up has been tested with 243 Am evaporated from a filament located inside the optical gas cell. Resonance ionization is performed using a two-step excitation with an excimer-dye-laser combinatio…

Nuclear and High Energy PhysicsArgonBuffer gasAnalytical chemistrychemistry.chemical_elementMass spectrometryIon sourceAtmospheric-pressure laser ionizationchemistryIonizationAtomic physicsInstrumentationQuadrupole mass analyzerElectron ionizationNuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms
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Radiation detected resonance ionization spectroscopy on208Tl and242fAm

1993

An ultra-sensitive laser spectroscopic method has been developed for the hyperfine spectroscopy of short-lived isotopes far off stability produced by heavy ion induced nuclear reactions at very weak intensity (> 1/s). It is based on resonance ionization spectroscopy in a buffer gas cell with radiation detection of the ionization process (RADRIS). As a first on-line application of RADRIS optical spectroscopy at242fAm fission isomers is in progress at the low target production rate of 10/s. The resonance ionization has been performed in two steps utilizing an excimer dye laser combination with a repetition rate of 300 Hz. The first resonant step proceeds through terms which correspond to wave…

Nuclear and High Energy PhysicsDye laserExcimer laserChemistrymedicine.medical_treatmentAnalytical chemistryResonanceCondensed Matter PhysicsAtomic and Molecular Physics and OpticsIon sourceAtmospheric-pressure laser ionizationIonizationmedicinePhysical and Theoretical ChemistryAtomic physicsSpectroscopyAmbient ionizationHyperfine Interactions
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Isotope Shift Measurements for Superdeformed Fission Isomeric States

1998

Optical isotope shift measurements have been performed for the ${}^{240,242}{\mathrm{Am}}^{f}$ fission isomers with low target production rates of $10{\mathrm{s}}^{\ensuremath{-}1}$ employing resonance ionization spectroscopy in a buffer gas cell. Isotope shift ratios ${\mathrm{IS}}^{240f,241}/{\mathrm{IS}}^{243,241}\phantom{\rule{0ex}{0ex}}=\phantom{\rule{0ex}{0ex}}39.2(8)$ and ${\mathrm{IS}}^{242f,241}/{\mathrm{IS}}^{243,241}\phantom{\rule{0ex}{0ex}}=\phantom{\rule{0ex}{0ex}}41.4(8)$ have been measured at the 500.02 nm transition. A difference in the nuclear mean charge radii $\ensuremath{\delta}〈{r}^{2}{〉}_{\mathrm{opt}}^{242f,241}\phantom{\rule{0ex}{0ex}}=\phantom{\rule{0ex}{0ex}}5.34(2…

PhysicsIsotopeFissionResonance ionizationQuadrupoleGeneral Physics and AstronomyCharge (physics)Production (computer science)Atomic physicsPhysical Review Letters
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Isotope shift and hyperfine structure measurements at the242f Am fission isomer

1996

Istope shift and hyperfine structure measurements have been performed for the242fAm fission isomer with target production rates of only a few per second. The method is based on resonance ionization spectroscopy (RIS) in a buffer gas cell with radioactive decay detection of the ionization process (RADRIS). A relative isotope shift ratioX exp=IS242f,241/ IS243,241=41.7±0.9 has been measured for the 500.02 nm transition corresponding to a nuclear parameter Λ242f,241=5.4±0.3 fm2. The analysis of the quadrupole moment based on the deformed Fermi-model of the nuclear charge distribution including second order corrections results inQ 20=38.2 ±1.4( −0.8 +0.4 )model eb. The measurement of the hyperf…

Nuclear and High Energy PhysicsIsotopeFissionChemistryCondensed Matter PhysicsAtomic and Molecular Physics and OpticsEffective nuclear chargeIsomeric shiftIsotopic shiftIonizationPhysical and Theoretical ChemistryAtomic physicsHyperfine structureRadioactive decayHyperfine Interactions
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First observation of a resonance ionization signal on242mAm fission isomers

1992

The feasibility of a hyperfine spectroscopy on242mAm fission isomers has been demonstrated at the low target production rate of 10/s. The experimental method employed is based on resonance ionization spectroscopy in a buffer gas cell with detection of the ionization process by means of the fission decay of the isomers. The resonance ionization has been performed in two steps, utilizing an excimer dye laser combination with a repetition rate of 300 Hz. The first resonant step proceeds through theJ=7/2 term at 21440.35 cm−1, which has been excited with the tuncable dye laser beam of a wavelength of 466.28 nm, the second non-resonant step is achieved with the 351 nm radiation of the excimer la…

Nuclear and High Energy PhysicsDye laserExcimer laserChemistrymedicine.medical_treatmentAnalytical chemistryPhysics::OpticsResonancePhotoionizationCondensed Matter PhysicsAtomic and Molecular Physics and OpticsAtmospheric-pressure laser ionizationIonizationPhysics::Atomic and Molecular ClustersmedicinePhysics::Atomic PhysicsPhysical and Theoretical ChemistryAtomic physicsSpectroscopyHyperfine structureHyperfine Interactions
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CCDC 104808: Experimental Crystal Structure Determination

2000

Related Article: S.Deloisy, H.Kunz|1998|Tetrahedron Lett.|39|791|doi:10.1016/S0040-4039(97)10720-1

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersN-Cinnamylidene-5679-tetra-O-pivaloyl-123-trideoxy-4(R)-amino-galacto-non-1-enitolExperimental 3D Coordinates
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CCDC 678698: Experimental Crystal Structure Determination

2009

Related Article: S.Elzner, D.Schmidt, D.Schollmeyer, G.Erkel, T.Anke, H.Kleinert, U.Forstermann, H.Kunz|2008|ChemMedChem|3|924|doi:10.1002/cmdc.200800022

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(16S)-13-Dihydroxy-8-methyl-891011121314151617-decahydro-5H-7-oxabenzocyclohexadecene-618-dioneExperimental 3D Coordinates
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CCDC 250616: Experimental Crystal Structure Determination

2005

Related Article: C.Becker, C.Hoben, D.Schollmeyer, G.Scherr, H.Kunz|2005|Eur.J.Org.Chem.|2005|1497|doi:10.1002/ejoc.200500044

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters2-(6-Benzyl-25-dioxopiperazin-3-yl)-N-(diaminomethylene)ethanaminium nitrateExperimental 3D Coordinates
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CCDC 678696: Experimental Crystal Structure Determination

2009

Related Article: S.Elzner, D.Schmidt, D.Schollmeyer, G.Erkel, T.Anke, H.Kleinert, U.Forstermann, H.Kunz|2008|ChemMedChem|3|924|doi:10.1002/cmdc.200800022

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(S)-1113-Dihydroxy-4-methyl-456789-hexahydro-1H-benzo(d)oxacyclododecine-210-dioneExperimental 3D Coordinates
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CCDC 165221: Experimental Crystal Structure Determination

2002

Related Article: M.Follmann, A.Rosch, E.Klegraf, H.Kunz|2001|Synlett||1569|doi:10.1055/s-2001-17460

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(4R)-34-dihydro-4-propyl-1-(2346-tetra-O-pivaloyl-beta-D-galactopyranosyl)pyridine-2(1H)-oneExperimental 3D Coordinates
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CCDC 624381: Experimental Crystal Structure Determination

2007

Related Article: B.Kranke, H.Kunz|2007|Org.Biomol.Chem.|5|349|doi:10.1039/b615113b

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(2R5R6S)-N-(2'3'4'-Tri-O-pivaloyl-alpha-D-arabinopyranosyl)-56-diallyl-2-isopropylpiperidin-4-oneExperimental 3D Coordinates
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CCDC 678697: Experimental Crystal Structure Determination

2009

Related Article: S.Elzner, D.Schmidt, D.Schollmeyer, G.Erkel, T.Anke, H.Kleinert, U.Forstermann, H.Kunz|2008|ChemMedChem|3|924|doi:10.1002/cmdc.200800022

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters13-Dihydroxy-8-methyl-89101112131415-octahydro-5H-7-oxa-benzocyclotetradecene-616-dioneExperimental 3D Coordinates
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CCDC 237631: Experimental Crystal Structure Determination

2005

Related Article: E.Klegraf, M.Follmann, D.Schollmeyer, H.Kunz|2004|Eur.J.Org.Chem.|2004|3346|doi:10.1002/ejoc.200400169

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates(2R)-23-dihydro-2-phenyl-1-(2346-tetra-O-pivaloyl-beta-D-galactopyranosyl)pyridine-4(1H)-one
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CCDC 109406: Experimental Crystal Structure Determination

1999

Related Article: M.Weymann, M.Schultz-Kukula, H.Kunz|1998|Tetrahedron Lett.|39|7835|doi:10.1016/S0040-4039(98)01745-6

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates(2S4aR5R8aR)-N-(2'3'4'6'-Tetra-O-pivaloyl-beta-D-galactopyranosyl)-2-n-propyl-5-methyl-decahydrochinolin-4-one
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CCDC 619295: Experimental Crystal Structure Determination

2008

Related Article: M.Negru, D.Schollmeyer, H.Kunz|2007|Angew.Chem.,Int.Ed.|46|9339|doi:10.1002/anie.200703179

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersN-(4-Methoxycarbonyl(2.2)paracyclophan-15-ylmethylidene)-2346-tetra-O-pivaloyl-beta-D-galactopyranosylamineExperimental 3D Coordinates
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CCDC 229786: Experimental Crystal Structure Determination

2004

Related Article: B.Kranke, D.Hebrault, M.Schultz-Kukula, H.Kunz|2004|Synlett|2004|671|doi:10.1055/s-2004-817775

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D CoordinatesN-(2'3'4'-Tri-O-pivaloyl-alpha-D-arabinosyl)-2-(4''-chlorophenyl)-6-phenyl-piperidin-4-one
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CCDC 229785: Experimental Crystal Structure Determination

2004

Related Article: B.Kranke, D.Hebrault, M.Schultz-Kukula, H.Kunz|2004|Synlett|2004|671|doi:10.1055/s-2004-817775

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters22-Dimethylpropionic acid 45-bis(22-dimethylpropionyloxy)-2-(4-oxo-2-propyl-34-dihydro-2H-pyridin-1-yl)-tetrahydropyran-3-yl esterExperimental 3D Coordinates
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CCDC 237632: Experimental Crystal Structure Determination

2005

Related Article: E.Klegraf, M.Follmann, D.Schollmeyer, H.Kunz|2004|Eur.J.Org.Chem.|2004|3346|doi:10.1002/ejoc.200400169

Space GroupCrystallographyCrystal SystemCrystal Structure(2S3S)-23-dihydro-3-methyl-2-propyl-1-(2346-tetra-O-pivaloyl-beta-D-galactopyranosl)pyridine-4(1H)-oneCell ParametersExperimental 3D Coordinates
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CCDC 283243: Experimental Crystal Structure Determination

2006

Related Article: E.Klegraf, S.Knauer, H.Kunz|2006|Angew.Chem.,Int.Ed.|45|2623|doi:10.1002/anie.200504090

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters2-(2346-tetrakis-O-(22-Dimethylpropanoyl)hexopyranosyl)-1456-tetrahydro-15-15-methano-2-benzazocin-3(2H)-oneExperimental 3D Coordinates
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CCDC 136523: Experimental Crystal Structure Determination

2001

Related Article: P.Allef, H.Kunz|2000|Tetrahedron:Asymm.|11|375|doi:10.1016/S0957-4166(99)00541-8

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D CoordinatesN-Ethyl-N-(2346-tetra-O-pivaloyl-beta-D-galactopyranosyl)-22-diethyl-3-(p-nitrophenyl)-beta-alanine methyl ester
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