0000000001303196

AUTHOR

Daniel Fortin

showing 61 related works from this author

Reactivity of CuI and CuBr toward Et2S: a reinvestigation on the self-assembly of luminescent copper(I) coordination polymers.

2010

CuI reacts with SEt(2) in hexane to afford the known strongly luminescent 1D coordination polymer [(Et(2)S)(3){Cu(4)(mu(3)-I)(4)}](n) (1). Its X-ray structure has been redetermined at 115, 235, and 275 K in order to address the behavior of the cluster-centered emission and is built upon Cu(4)(mu(3)-I)(4) cubane-like clusters as secondary building units (SBUs), which are interconnected via bridging SEt(2) ligands. However, we could not reproduce the preparation of a coordination polymer with composition [(Et(2)S)(3){Cu(4)(mu(3)-Br)(4)}](n) as reported in Inorg. Chem. 1975, 14, 1667. In contrast, the autoassembly reaction of SEt(2) with CuBr results in the formation of a novel 1D coordination…

chemistry.chemical_classificationCoordination polymerInorganic chemistrychemistry.chemical_elementBridging ligandPolymerCrystal structureCopperInorganic Chemistrychemistry.chemical_compoundCrystallographychemistryDensity functional theorySBusPhysical and Theoretical ChemistryLuminescenceInorganic chemistry
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The first unpaired electron placed inside a C3-symmetry P-chirogenic cluster

2010

The Pd(3)(dppm*)(3)(CO)(n+) enantiomers (n = 2 (2), 1 (3)) were prepared either from (R,R)- or (S,S)-P-chirogenic bis(phenyl-m-xylylphosphino)methane (dppm*; 1) and Pd(OAc)(2) in the presence of CF(3)CO(2)H, CO and water (n = 2), and then by reductive electrolysis (n = 1). The stable enantiomeric [Pd(3)((S,S)-dppm*)(3)(CO)](+)˙ (3), is the first C(3)-symmetry radical-cation M-M bonded cluster, therefore the odd electron is delocalized onto the Pd(3) frame within this symmetry. The novel chiral species have been characterized by circular dichroism (CD) of both enantiomers of the Pd(3)(dppm*)(3)(CO)(2+) clusters (2) and by EPR spectroscopy for the Pd(3)((S,S)-dppm*)(3)(CO)(+)˙ paramagnetic co…

Models MolecularSteric effectsStereochemistryChemistryElectron Spin Resonance SpectroscopyMolecular ConformationElectronsStereoisomerismlaw.inventionInorganic ChemistryMagneticsCrystallographyDelocalized electronParamagnetismUnpaired electronlawIntramolecular forceElectrochemistryOrganometallic CompoundsMolecular orbitalElectron paramagnetic resonanceHyperfine structurePalladiumDalton Transactions
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Decoupling the artificial special pair to slow down the rate of singlet energy transfer

2012

Trimer 2, composed of a cofacial heterobismacrocycle, octamethyl-porphyrin zinc(II) and bisarylporphyrin zinc(II) held by an anthracenyl spacer, and a flanking acceptor, bisarylporphyrin free-base ( Ar = -3,5-(t Bu )2 C 6 H 3), has been studied by means of absorption spectroscopy, "steady state and time-resolved fluorescence" and fs transient absorption spectroscopy, and density functional theory (DFT) in order to assess the effect of decoupling the chromophores' low energy MOs on the rate of the singlet, S1, energy transfer, k ET , compared to a recently reported work on a heavily coupled trimeric system, Trimer 1, [biphenylenebis(n-nonyl)porphyrin zinc(II)]-bisarylporphyrin free-base ( A…

CrystallographyAbsorption spectroscopyChemistryUltrafast laser spectroscopyTrimerDensity functional theoryGeneral ChemistrySinglet stateChromophoreAbsorption (electromagnetic radiation)PhotochemistryAcceptorJournal of Porphyrins and Phthalocyanines
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Copper(I) Halides (X = Br, I) Coordinated to Bis(arylthio)methane Ligands: Aryl Substitution and Halide Effects on the Dimensionality, Cluster Size a…

2014

Bis(phenylthio)methane (L1) reacts with CuI to yield the 1D-coordination polymer [{Cu4(μ3-I)4}(μ-L1)2]n (1) bearing cubane Cu4I4 clusters as connecting nodes. The crystal structures at 115, 155, 195, and 235 K provided evidence for a phase transition changing from the monoclinic space group C2/c to P21/c. The self-assembly process of CuI with bis(p-tolylthio)methane (L2), bis(4-methoxyphenylthio)methane (L3), and bis(4-bromo-phenylthio)methane (L4) affords the 1D-coordination polymers [{Cu4(μ3-I)4}(μ-Lx)2]n (x = 2, 3, or 4). Compounds 2 and 4 are isostructural with C2/c low temperature polymorph of 1, whereas the inversion centers and 2-fold axes are lost in 3 (space group Cc). The use of b…

Steric effectsArylGeneral ChemistryCrystal structureCondensed Matter PhysicsPhotochemistryMethanechemistry.chemical_compoundCrystallographychemistryCubaneRibbon[CHIM]Chemical SciencesGeneral Materials ScienceIsostructuralComputingMilieux_MISCELLANEOUSMonoclinic crystal system
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Luminescent P-Chirogenic Copper Clusters

2013

P-chirogenic clusters of the cubanes [Cu4I4L4] (L = chiral phosphine) were prepared from (+)- and (-)-ephedrine with L = (S)- or (R)-(R)(Ph)(i-Pr)P (with R = CH3 (seven steps) or C17H35 (10 steps)) with e.e. up to 96%. The X-ray structure of [Cu4I4((R)-(CH3)(Ph)(i-Pr)P)4] confirmed the cubane structure with average Cu···Cu and Cu···I distances of 2.954 and 2.696 Å, respectively. The cubane structure of the corresponding [Cu4I4((S)-(CH3)(Ph)(i-Pr)P)4] was established by the comparison of the X-ray powder diffraction patterns, and the opposite optical activity of the (S)- and (R)-ligand-containing clusters was confirmed by circular dichroism spectroscopy. Small-angle X-ray scattering patterns…

Circular dichroismchemistry.chemical_elementCopperInorganic Chemistrychemistry.chemical_compoundCrystallographychemistryCubaneExcited stateEmission spectrumPhysical and Theoretical ChemistryLuminescencePhosphinePowder diffractionInorganic Chemistry
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The Pd3(dppm)3(CO)n clusters (n = 1-,2-); rare cases of anionic palladium species.

2010

Two novel anionic palladium clusters, Pd(3)(dppm)(3)(CO)(n-) (Pd(3)(n); n = 1-,2-) were electrochemically generated from the dicationic cluster Pd(3)(2+) in 0.2 M THF/Bu(4)NPF(6)via two first consecutive reversible 1-electron reductions (Pd(3)(2+) + 1 e(-) ⇌ Pd(3)(+), -0.210, and Pd(3)(+) + 1 e(-) ⇌ Pd(3)(0), -0.470 V vs. SCE) followed by two others at -2.350 (Pd(3)(0) + 1 e(-) ⇌ Pd(3)(1-), reversible) and at -2.690 V vs. SCE (Pd(3)(1-) + 1 e(-) ⇌ Pd(3)(2-), irreversible). The chemical stability and instability, respectively, of the Pd(3)(dppm)(3)(CO)(n-) clusters (Pd(3)(n); n = 1-,2-) at the time scale of the electrochemical experiments were addressed by DFT computations. Indeed, geometry …

Inorganic ChemistryBond lengthStereochemistryOxidation stateChemistryCluster (physics)Substrate (chemistry)chemistry.chemical_elementChemical stabilityElectrochemistryMedicinal chemistryRelative stabilityPalladiumDalton transactions (Cambridge, England : 2003)
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P-Chirogenic Phosphines Supported by Calix[4]arene: New Insight into Palladium-Catalyzed Asymmetric Allylic Substitution

2013

The first P-chirogenic mono- and diphosphine ligands supported on the upper rim of a calix[4]arene moiety were synthesized using the ephedrine methodology. The lithiated calix[4]arene mono- and dianions both react with the oxazaphospholidine–borane, prepared from ephedrine, to afford regio- and stereoselectively the corresponding calix[4]arenyl aminophosphine–boranes, by cleavage of the heterocyclic ring at the P–O bond position. Subsequent reactions with HCl and then organolithium reagent and finally decomplexation with DABCO lead to the corresponding calix[4]arenyl mono- or diphosphines. Both enantiomers of the calix[4]arenyl phosphines were obtained either by using (+)- or (−)-ephedrine …

Allylic rearrangementStereochemistryOrganic Chemistrychemistry.chemical_elementDABCOBoraneOrganolithium reagentMedicinal chemistryInorganic Chemistrychemistry.chemical_compoundchemistryDiphosphinesMoietyPhysical and Theoretical ChemistryEnantiomerPalladiumOrganometallics
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Design of Triads for Probing the Direct Through Space Energy Transfers in Closely Spaced Assemblies

2013

Using a selective stepwise Suzuki cross-coupling reaction, two trimers built on three different chromophores were prepared. These trimers exhibit a D(^)A1-A2 structure where the donor D (octa-β-alkyl zinc(II)porphyrin either as diethylhexamethyl, 10a, or tetraethyltetramethyl, 10b, derivatives) through space transfers the S1 energy to two different acceptors, di(4-ethylbenzene) zinc(II)porphyrin (A1; acceptor 1) placed cofacial with D, and the corresponding free base (A2; acceptor 2), which is meso-meso-linked with A1. This structure design allows for the possibility of comparing two series of assemblies, 9a,b (D(^)A1) with 10a,b (D(^)Â1-A2), for the evaluation of the S1 energy transfer for…

Models MolecularMetalloporphyrinsChemistryEnergy transferMolecular Conformationchemistry.chemical_elementFree baseZincChromophoreSpace (mathematics)AcceptorPorphyrinFluorescenceInorganic ChemistryCrystallographychemistry.chemical_compoundEnergy TransferDrug DesignPhysical and Theoretical ChemistryAtomic physicsInorganic Chemistry
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Through-bond versus through-space T1 energy transfers in organometallic compound-metalloporphyrin pigments

2009

The preparation and characterization of two d9−d9 M2-bonded Pt2(dppm)2(C≡CC6H4-M(P))2 complexes (where M = Zn or Pd, and P = diethylhexamethylporphyrin) were achieved. The central [Pt2(dppm)2(C≡CC6H4)2] organometallic unit appears to be an independent chromophore and is suspected to be luminescent at 77 K (in 2MeTHF) in the porphyrin-containing complexes, as this is the case for the unfunctionalized Pt2(dppm)2(C≡CPh)2 parent compound. However, when this spacer is connected (by a single C−C bond) to either M(P) (M = Zn, Pd), even in the absence of conjugation (as the computed dihedral angle between the C6H4 and porphyrin planes is ∼84.5°), total quenching of the luminescence of the [Pt2(dppm…

chemistry.chemical_elementDihedral angle010402 general chemistry01 natural sciencesInorganic Chemistrychemistry.chemical_compoundplatinumPhysical and Theoretical ChemistryComputingMilieux_MISCELLANEOUSQuenching (fluorescence)010405 organic chemistryChemistryOrganic ChemistryChromophoremetalloporphyrin pigmentpalladiumPorphyrin0104 chemical sciences[CHIM.THEO]Chemical Sciences/Theoretical and/or physical chemistryCrystallographytriplet energy transfer[ CHIM.THEO ] Chemical Sciences/Theoretical and/or physical chemistryAbsorption (chemistry)organometallic compoundPlatinumLuminescencePalladium
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The First P ‐Stereogenic 1D Coordination Polymers with the Metal Centers in the Backbone

2011

The enantiomeric ligands (R,R)- and (S,S)-bis(o-anisylphenylphosphanyl)methane (R,R-22 and S,S-22) and (R,R)- and (S,S)-bis(phenyl-m-xylylphosphanyl)methane (R,R-23 and S,S-23; dppm*), were treated with [Cu(NCCH3)4](BF4) and AgBF4 to produce the binuclear complexes [Cu2(dppm*)2(NCCH3)4](BF4)2 or [Ag2(dppm*)2](BF4)2, respectively. Then, these complexes were used as building blocks to prepare the first P-chirogenic 1D coordination polymers {[M2(dppm*)2(dmb)2](BF4)2}n [dppm* = (R,R)-22, (S,S)-22, (R,R)-23, (S,S)-23, M = Cu, Ag, dmb = 1,8-diisocyano-p-menthane] where M is part of the backbone of the polymer chain. The isostructural nature of these new polymers with the achiral parent polymers, …

Inorganic ChemistryMetalCircular dichroismCrystallographyChemistryvisual_artProton NMRvisual_art.visual_art_mediumEnantiomerIsostructuralChirality (chemistry)Bimetallic stripStereocenterEuropean Journal of Inorganic Chemistry
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A Very Low Band Gap Diketopyrrolopyrrole-Porphyrin Conjugated Polymer

2017

International audience; A porphyrin-diketopyrrolopyrrole-containing polymer (poly(porphyrin-diketopyrrolopyrrole) (PPDPP)) shows impressive molar absorption coefficients from lambda=300 to 1000 nm. The photophysical and structural properties of PPDPP have been studied. With PPDPP as the electron donor and [ 6,6]phenyl C-71 butyric acid methyl ester (PC71BM) as the electron acceptor, the bulk heterojunction polymer solar cell showed overall power conversion efficiencies of 4.18 and 6.44% for as-cast and two-step annealing processed PPDPP: PC71BM (1: 2) active layers, respectively. These results are quite impressive for porphyrin-containing polymers, especially when directly included in the p…

Materials scienceBand gapbuilding-blockporphyrinoidsElectron donorthin-film transistors02 engineering and technologyConjugated system010402 general chemistryPhotochemistry[ CHIM ] Chemical Sciences01 natural sciencesPolymer solar cellheterojunction solar-cellschemistry.chemical_compound[CHIM]Chemical Sciencessmall-moleculepolymerschemistry.chemical_classificationsemiconducting polymerscharge transferGeneral ChemistryPolymerChromophoreElectron acceptorside-chains021001 nanoscience & nanotechnologyPorphyrinphotovoltaic properties0104 chemical sciencesphotodynamic therapychemistryorganic photovoltaics0210 nano-technologyabsorptionperformanceconjugationChemPlusChem
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Formation of an unprecedented (CuBr)5 cluster and a zeolite-type 2D-coordination polymer: a surprising halide effect

2013

A unique pentanuclear cluster within a zeolite-type polymer ([Cu5(μ4-Br)(μ3-Br)2(μ2-Br)2](μ2-MeSPr)3)n (1; void space >81%) and a luminescent 1D ([Cu(μ3-I)]4(MeSPr)3)n polymer, 2, are formed when MeSPr reacts with CuBr and CuI.

BromidesModels MolecularPolymersCoordination polymerInorganic chemistryHalide010402 general chemistry01 natural sciencesCatalysischemistry.chemical_compoundHalogensPolymer chemistryMaterials ChemistryCluster (physics)ZeoliteComputingMilieux_MISCELLANEOUSchemistry.chemical_classificationLuminescent Agents010405 organic chemistryMetals and AlloysGeneral ChemistryPolymer3. Good health0104 chemical sciencesSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialschemistryVoid spaceZeolitesCeramics and CompositesLuminescenceCopperChemical Communications
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1,4-Bis(arylthio)but-2-enes as Assembling Ligands for (Cu2X2)n (X = I, Br; n = 1, 2) Coordination Polymers: Aryl Substitution, Olefin Configuration, …

2016

CuI reacts with E-PhS(CH2CH═CHCH2)SPh, L1, to afford the coordination polymer (CP) [Cu2I2{μ-E-PhS(CH2CH═CHCH2)SPh}2]n (1a). The unprecedented square-grid network of 1 is built upon alternating two-dimensional (2D) layers with an ABAB sequence and contains rhomboid Cu2(μ2-I)2 clusters as secondary building units (SBUs). Notably, layer A, interconnected by bridging L1 ligands, contains exclusively dinuclear units with short Cu···Cu separations [2.6485(7) A; 115 K]. In contrast, layer B exhibits Cu···Cu distances of 2.8133(8) A. The same network is observed when CuBr reacts with L1. In the 2D network of [Cu2Br2{μ-E-PhS(CH2CH═CHCH2)SPh}2]n (1b), isotype to 1a, one square-grid-type layer contain…

chemistry.chemical_classificationOlefin fiber010405 organic chemistryCoordination polymerStereochemistryArylHalideGeneral ChemistryPolymer010402 general chemistryCondensed Matter Physics01 natural sciences0104 chemical scienceschemistry.chemical_compoundCrystallographychemistryGeneral Materials ScienceSBusLuminescenceCurse of dimensionalityCrystal Growth & Design
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Strong donor–acceptor couplings in a special pair-antenna model

2010

A special pair model composed of two cofacial zinc porphyrins (acceptor) linked to a free base (donor) acts as an energy transfer dyad. Despite the absence of conjugation, ππ*/charge transfer excited states and ultrafast energy transfer (∼5 ps) are noted.

ChemistryEnergy transferMetals and Alloyschemistry.chemical_elementFree baseCharge (physics)General ChemistryZincPhotochemistryMolecular physicsAcceptorCatalysisSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsExcited stateMaterials ChemistryCeramics and CompositesAntenna (radio)Donor acceptorChemical Communications
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Organometallic Oligomers Based on Bis(arylacetylide)bis(P-chirogenic phosphine)platinum(II) Complexes: Synthesis and Photonic Properties

2013

A series of P-chirogenic oligomers of the type (-C≡C-aryl-C≡C-PtL2-)n [L = (R)- and (S)-P(Ph)(iPr)(C17H35); aryl = 1,4-benzene, 2,1,3-benzothiadiazole] along the corresponding achiral analogues (L = PBu3) and model complexes PhC≡CPtL2C≡CPh were prepared from the ephedrine strategy and were fully characterized [(1)H, (31)P NMR; IR; small-angle X-ray scattering (SAXS); gel permeation chromatography (GPC); thermal gravimetric analysis (TGA); circular dichroism, UV-vis, and luminescence spectroscopy; photophysics, and degree of anisotropy measurements]. From the CD measurements, the chiral environment of the phosphine ligands is modestly felt by the aryl moieties. Concurrently, the TGA shows th…

Models MolecularPhotonsCircular dichroismThermogravimetric analysisMolecular StructureOrganoplatinum CompoundsAcetylenePhosphinesSmall-angle X-ray scatteringChemistryLigandArylMolecular Dynamics SimulationPhotochemistryInorganic ChemistryGel permeation chromatographychemistry.chemical_compoundPolymer chemistryPhysical and Theoretical ChemistryLuminescencePhosphineInorganic Chemistry
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Singlet and triplet energy transfers in tetra-(meso-truxene)zinc(II)- and tetra-(meso-tritruxene)zinc(II) porphyrin and porphyrin-free base dendrimer…

2011

The synthesis, optical properties, and energy transfer features of four dendrimers composed of meso-tetrasubstituted zinc(II) porphyrin (ZnP) or a free base (P) central core, where the substituents are four truxene (Tru) or four tritruxene dendrons (TriTru), TruP, TriTruP, TruZnP, and TriTruZnP, are reported. Selective excitation of the truxene donors results in a photoinduced singlet energy transfer from the truxenes to the porphyrin acceptor. The rates for singlet energy transfer (k(ET)), evaluated from the change in the fluorescence lifetime of the donors (Tru and TriTru) in the presence and absence of the acceptor (P or ZnP) for TruP, TruZnP, TriTruP, and TriTruZnP, are 5.9, 1.2, 0.87, …

biologyChemistryFree basechemistry.chemical_elementZincbiology.organism_classificationPhotochemistryFluorescencePorphyrinAcceptorInorganic Chemistrychemistry.chemical_compoundDendrimerTetraSinglet statePhysical and Theoretical ChemistryInorganic chemistry
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CCDC 1418779: Experimental Crystal Structure Determination

2016

Related Article: Antoine Bonnot, Michael Knorr, Fabrice Guyon, Marek M. Kubicki, Yoann Rousselin, Carsten Strohmann, Daniel Fortin, Pierre D. Harvey|2016|Cryst.Growth Des.|16|774|doi:10.1021/acs.cgd.5b01360

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-[(mu-11'-(butane-14-diyldisulfanediyl)bis(4-methylbenzene))-bis(mu-iodo)-di-copper]Experimental 3D Coordinates
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CCDC 952665: Experimental Crystal Structure Determination

2013

Related Article: Naima Khiri-Meribout, Etienne Bertrand, Jérôme Bayardon, Marie-Joëlle Eymin, Yoann Rousselin, Hélène Cattey, Daniel Fortin, Pierre D. Harvey, and Sylvain Jugé|2013|Organometallics|32|2827|doi:10.1021/om400229p

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates(S)-(-)-(o-Anisyl(phenyl)(17-chloro-25262728-tetrapropoxycalix[4]arene-5-yl)phosphino)borane
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CCDC 974338: Experimental Crystal Structure Determination

2014

Related Article: Michael Knorr,Abderrahim Khatyr,Ahmed Dini Aleo,Anass El Yaagoubi,Carsten Strohmann,Marek M. Kubicki,Yoann Rousselin,Shawkat M. Aly,Antony Lapprand,Daniel Fortin, Pierre D. Harvey|2014|Cryst.Growth Des.|14|5373|doi:10.1021/cg500905z

Space GroupCrystallographybis(mu2-Bromo)-tetrakis(bis(p-tolylthio)methane-S)-di-copperCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 974340: Experimental Crystal Structure Determination

2014

Related Article: Michael Knorr,Abderrahim Khatyr,Ahmed Dini Aleo,Anass El Yaagoubi,Carsten Strohmann,Marek M. Kubicki,Yoann Rousselin,Shawkat M. Aly,Antony Lapprand,Daniel Fortin, Pierre D. Harvey|2014|Cryst.Growth Des.|14|5373|doi:10.1021/cg500905z

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-[bis(mu2-11'-(methylenedisulfanediyl)bis(3-methylbenzene))-bis(mu2-bromo)-di-copper]Experimental 3D Coordinates
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CCDC 1418785: Experimental Crystal Structure Determination

2016

Related Article: Antoine Bonnot, Michael Knorr, Fabrice Guyon, Marek M. Kubicki, Yoann Rousselin, Carsten Strohmann, Daniel Fortin, Pierre D. Harvey|2016|Cryst.Growth Des.|16|774|doi:10.1021/acs.cgd.5b01360

Space GroupCrystallographycatena-[(mu-bromo)-(mu-11'-(but-2-ene-14-diyldisulfanediyl)bis(4-methylbenzene))-copper]Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1418780: Experimental Crystal Structure Determination

2016

Related Article: Antoine Bonnot, Michael Knorr, Fabrice Guyon, Marek M. Kubicki, Yoann Rousselin, Carsten Strohmann, Daniel Fortin, Pierre D. Harvey|2016|Cryst.Growth Des.|16|774|doi:10.1021/acs.cgd.5b01360

Space GroupCrystallographyCrystal Systemcatena-[(mu-cis-1-methyl-4-((4-((4-methylphenyl)sulfanyl)but-2-en-1-yl)sulfanyl)benzene)-(mu-iodo)-copper(i)]Crystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 974327: Experimental Crystal Structure Determination

2014

Related Article: Michael Knorr,Abderrahim Khatyr,Ahmed Dini Aleo,Anass El Yaagoubi,Carsten Strohmann,Marek M. Kubicki,Yoann Rousselin,Shawkat M. Aly,Antony Lapprand,Daniel Fortin, Pierre D. Harvey|2014|Cryst.Growth Des.|14|5373|doi:10.1021/cg500905z

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-(tetrakis(mu3-Iodo)-bis(mu2-bis(phenylthio)methane-SS')-tetra-copper)Experimental 3D Coordinates
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CCDC 1418767: Experimental Crystal Structure Determination

2016

Related Article: Antoine Bonnot, Michael Knorr, Fabrice Guyon, Marek M. Kubicki, Yoann Rousselin, Carsten Strohmann, Daniel Fortin, Pierre D. Harvey|2016|Cryst.Growth Des.|16|774|doi:10.1021/acs.cgd.5b01360

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinatescatena-[(mu-11'-(but-2-ene-14-diyldisulfanediyl)dibenzene)-bis(mu-iodo)-di-copper]
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CCDC 1418763: Experimental Crystal Structure Determination

2016

Related Article: Antoine Bonnot, Michael Knorr, Fabrice Guyon, Marek M. Kubicki, Yoann Rousselin, Carsten Strohmann, Daniel Fortin, Pierre D. Harvey|2016|Cryst.Growth Des.|16|774|doi:10.1021/acs.cgd.5b01360

Space GroupCrystallographyCrystal Systemcatena-[bis(mu-trans-11'-(but-2-ene-14-diyldisulfanediyl)dibenzene)-di(iodo)-di-copper]Crystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1418781: Experimental Crystal Structure Determination

2016

Related Article: Antoine Bonnot, Michael Knorr, Fabrice Guyon, Marek M. Kubicki, Yoann Rousselin, Carsten Strohmann, Daniel Fortin, Pierre D. Harvey|2016|Cryst.Growth Des.|16|774|doi:10.1021/acs.cgd.5b01360

Space GroupCrystallographycatena-[(mu-bromo)-(mu-11'-(but-2-ene-14-diyldisulfanediyl)bis(4-methylbenzene))-copper]Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1418772: Experimental Crystal Structure Determination

2016

Related Article: Antoine Bonnot, Michael Knorr, Fabrice Guyon, Marek M. Kubicki, Yoann Rousselin, Carsten Strohmann, Daniel Fortin, Pierre D. Harvey|2016|Cryst.Growth Des.|16|774|doi:10.1021/acs.cgd.5b01360

Space GroupCrystallographycatena-[bis(mu-11'-(but-2-ene-14-diyldisulfanediyl)dibenzene)-bis(mu-bromo)-di-copper]Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 974334: Experimental Crystal Structure Determination

2014

Related Article: Michael Knorr,Abderrahim Khatyr,Ahmed Dini Aleo,Anass El Yaagoubi,Carsten Strohmann,Marek M. Kubicki,Yoann Rousselin,Shawkat M. Aly,Antony Lapprand,Daniel Fortin, Pierre D. Harvey|2014|Cryst.Growth Des.|14|5373|doi:10.1021/cg500905z

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-(bis(mu3-Iodo)-(mu2-bis(4-methoxyphenylthio)methane-SS')-di-copper)Experimental 3D Coordinates
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CCDC 1418782: Experimental Crystal Structure Determination

2016

Related Article: Antoine Bonnot, Michael Knorr, Fabrice Guyon, Marek M. Kubicki, Yoann Rousselin, Carsten Strohmann, Daniel Fortin, Pierre D. Harvey|2016|Cryst.Growth Des.|16|774|doi:10.1021/acs.cgd.5b01360

Space GroupCrystallographycatena-[(mu-bromo)-(mu-11'-(but-2-ene-14-diyldisulfanediyl)bis(4-methylbenzene))-copper]Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1418770: Experimental Crystal Structure Determination

2016

Related Article: Antoine Bonnot, Michael Knorr, Fabrice Guyon, Marek M. Kubicki, Yoann Rousselin, Carsten Strohmann, Daniel Fortin, Pierre D. Harvey|2016|Cryst.Growth Des.|16|774|doi:10.1021/acs.cgd.5b01360

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinatescatena-[(mu-11'-(but-2-ene-14-diyldisulfanediyl)dibenzene)-bis(mu-iodo)-di-copper]
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CCDC 1418765: Experimental Crystal Structure Determination

2016

Related Article: Antoine Bonnot, Michael Knorr, Fabrice Guyon, Marek M. Kubicki, Yoann Rousselin, Carsten Strohmann, Daniel Fortin, Pierre D. Harvey|2016|Cryst.Growth Des.|16|774|doi:10.1021/acs.cgd.5b01360

Space GroupCrystallographyCrystal Systemcatena-[bis(mu-11'-(but-2-ene-14-diyldisulfanediyl)dibenzene)-bis(mu-iodo)-di-copper]Crystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 974333: Experimental Crystal Structure Determination

2014

Related Article: Michael Knorr,Abderrahim Khatyr,Ahmed Dini Aleo,Anass El Yaagoubi,Carsten Strohmann,Marek M. Kubicki,Yoann Rousselin,Shawkat M. Aly,Antony Lapprand,Daniel Fortin, Pierre D. Harvey|2014|Cryst.Growth Des.|14|5373|doi:10.1021/cg500905z

Space GroupCrystallographyCrystal Systemcatena-(bis(mu3-Iodo)-(mu2-bis(p-tolylthio)methane-SS')-di-copper)Crystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 947670: Experimental Crystal Structure Determination

2013

Related Article: Antony Lapprand, Antoine Bonnot, Michael Knorr, Youann Rousselin, Marek M. Kubicki, Daniel Fortin, Pierre D. Harvey|2013|Chem.Commun.|49|8848|doi:10.1039/C3CC45284K

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinatescatena-[bis(mu~4~-Bromo)-tetrakis(mu~3~-bromo)-tetrakis(mu~2~-bromo)-hexakis(mu~2~-methyl(propyl)thio)-deca-copper]
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CCDC 1418776: Experimental Crystal Structure Determination

2016

Related Article: Antoine Bonnot, Michael Knorr, Fabrice Guyon, Marek M. Kubicki, Yoann Rousselin, Carsten Strohmann, Daniel Fortin, Pierre D. Harvey|2016|Cryst.Growth Des.|16|774|doi:10.1021/acs.cgd.5b01360

Space GroupCrystallographybis(mu-bromo)-bis(mu-(11'-(but-2-ene-14-diylbis(sulfanediyl))dibenzene))-di-copperCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1424523: Experimental Crystal Structure Determination

2015

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterstetrakis(mu-iodo)-tetrakis(isopropyl(methyl)phenylphosphine)-tetra-copperExperimental 3D Coordinates
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CCDC 1418784: Experimental Crystal Structure Determination

2016

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Space GroupCrystallographycatena-[(mu-bromo)-(mu-11'-(but-2-ene-14-diyldisulfanediyl)bis(4-methylbenzene))-copper]Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 974326: Experimental Crystal Structure Determination

2014

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Space GroupCrystallographyCrystal Systemcatena-(bis(mu3-Iodo)-(mu2-bis(phenylthio)methane-SS')-di-copper)Crystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 974341: Experimental Crystal Structure Determination

2014

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis(mu2-bromo)-bis(acetonitrile)-bis(11'-(methylenedisulfanediyl)bis(2-methylbenzene))-di-copper(i)Experimental 3D Coordinates
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CCDC 974324: Experimental Crystal Structure Determination

2014

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Space GroupCrystallographyCrystal Systemcatena-(bis(mu3-Iodo)-(mu2-bis(phenylthio)methane-SS')-di-copper)Crystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1418769: Experimental Crystal Structure Determination

2016

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CCDC 974325: Experimental Crystal Structure Determination

2014

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CCDC 1418774: Experimental Crystal Structure Determination

2016

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CCDC 1418783: Experimental Crystal Structure Determination

2016

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Space GroupCrystallographycatena-[(mu-bromo)-(mu-11'-(but-2-ene-14-diyldisulfanediyl)bis(4-methylbenzene))-copper]Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1418771: Experimental Crystal Structure Determination

2016

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Space GroupCrystallographycatena-[bis(mu-11'-(but-2-ene-14-diyldisulfanediyl)dibenzene)-bis(mu-bromo)-di-copper]Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 974328: Experimental Crystal Structure Determination

2014

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-(bis(mu3-Iodo)-(mu2-bis(4-bromophenylthio)methane-SS')-di-copper)Experimental 3D Coordinates
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CCDC 1418766: Experimental Crystal Structure Determination

2016

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Space GroupCrystallographyCrystal Systemcatena-[bis(mu-11'-(but-2-ene-14-diyldisulfanediyl)dibenzene)-bis(mu-iodo)-di-copper]Crystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 974336: Experimental Crystal Structure Determination

2014

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CCDC 974335: Experimental Crystal Structure Determination

2014

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CCDC 1418764: Experimental Crystal Structure Determination

2016

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CCDC 1418775: Experimental Crystal Structure Determination

2016

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2014

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CCDC 1418762: Experimental Crystal Structure Determination

2016

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CCDC 952664: Experimental Crystal Structure Determination

2013

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CCDC 974329: Experimental Crystal Structure Determination

2014

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CCDC 1431598: Experimental Crystal Structure Determination

2016

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CCDC 1418773: Experimental Crystal Structure Determination

2016

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CCDC 1418768: Experimental Crystal Structure Determination

2016

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CCDC 952663: Experimental Crystal Structure Determination

2013

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CCDC 974339: Experimental Crystal Structure Determination

2014

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CCDC 952662: Experimental Crystal Structure Determination

2013

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CCDC 947669: Experimental Crystal Structure Determination

2013

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