Selective Formation of S4- and T-Symmetric Supramolecular Tetrahedral Cages and Helicates in Polar Media Assembled via Cooperative Action of Coordination and Hydrogen Bonds

We report on the synthesis and self-assembly study of novel supramolecular monomers encompassing quadruple hydrogen-bonding motifs and metal-coordinating 2,2'-bipyridine units. When mixed with metal ions such as Fe2+ or Zn2+, the tetrahedron cage complexes are formed in quantitative yields and full diastereoselectivity, even in highly polar acetonitrile or methanol solvents. The symmetry of the complexes obtained has been shown to depend critically on the flexibility of the ligand. Restriction of the rotation of the hydrogen-bonding unit with respect to the metal-coordinating site results in a T-symmetric cage, whereas introducing flexibility either through a methylene linker or rotating be…

Measurement report: PM<sub>2.5</sub>-bound nitrated aromatic compounds in Xi'an, Northwest China – seasonal variations and contributions to optical properties of brown carbon

Abstract. Nitrated aromatic compounds (NACs) are a group of key chromophores for brown carbon (light-absorbing organic carbon, i.e., BrC) aerosol, which affects radiative forcing. The chemical composition and sources of NACs and their contributions to BrC absorption, however, are still not well understood. In this study, PM 2.5 -bound NACs in Xi'an, Northwest China, were investigated for 112 daily PM 2.5 filter samples from 2015 to 2016. Both the total concentrations and contributions from individual species of NACs show distinct seasonal variations. The seasonally averaged concentrations of NACs are 2.1 (spring), 1.1 (summer), 12.9 (fall), and 56 ng m −3 (winter). Thereinto, 4-nitrophenol …

Supplementary material to "Measurement report: PM<sub>2.5</sub>-bound nitrated aromatic compounds in Xi'an, Northwest China: Seasonal variations and contributions to optical properties of brown carbon"

Concentrations, optical properties and sources of humic-like substances (HULIS) in fine particulate matter in Xi'an, Northwest China

Humic-like substances (HULIS) are ubiquitous in the atmospheric environment, which affects both human health and climate. We present here the mass concentration and optical characteristics of HULIS isolated from aerosol samples collected in Xi'an, China. Both mass concentration and absorption coefficient (Abs365) of HULIS show clear seasonal differences, with the highest average in winter (3.91 μgC m-3 and 4.78 M m-1, respectively) and the lowest in summer (0.65 μgC m-3 and 0.55 M m-1, respectively). The sources of HULIS_C and light absorption of HULIS were analyzed by positive matrix factorization (PMF) and four major sources were resolved, including secondary formation, biomass burning, c…

Characterization of the light absorbing properties, chromophores composition and sources of brown carbon aerosol in Xi'an, Northwest China

Abstract. The impact of brown carbon aerosol (BrC) on the Earth's radiative forcing balance has been widely recognized but remains uncertain, mainly because the relationships among BrC sources, chromophores, and optical properties of aerosol are poorly understood. In this work, the light absorption properties and chromophore composition of BrC were investigated for samples collected in Xi'an, Northwest China from 2015 to 2016. Both absorption Ångström exponent and mass absorption efficiency show distinct seasonal differences, which could be attributed to the differences in sources and chromophore composition of BrC. Three groups of light-absorbing organics were found to be important BrC ch…

Water-Insoluble Organics Dominate Brown Carbon in Wintertime Urban Aerosol of China: Chemical Characteristics and Optical Properties.

The chromophores responsible for light absorption in atmospheric brown carbon (BrC) are not well characterized, which hinders our understanding of BrC chemistry, the links with optical properties, and accurate model representations of BrC to global climate and atmospheric oxidative capacity. In this study, the light absorption properties and chromophore composition of three BrC fractions of different polarities were characterized for urban aerosol collected in Xi'an and Beijing in winter 2013-2014. These three BrC fractions show large differences in light absorption and chromophore composition, but the chromophores responsible for light absorption are similar in Xi'an and Beijing. Water-ins…

Selective Formation of S4- and T-Symmetric Supramolecular Tetrahedral Cages and Helicates in Polar Media Assembled via Cooperative Action of Coordination and Hydrogen-Bonds

We report on the synthesis and self-assembly study of novel supramolecular monomers encompassing quadruple hydrogen-bonding motifs and metal coordinating 2,2’-bipyridine units. When mixed with metal ions such as Fe2+ or Zn2+, the tetrahedron cage complexes are formed in quantitative yields and full diastereoselectivity, even in highly polar acetonitrile or methanol solvents. The symmetry of the complexes obtained has been shown to depend critically on the flexibility of the ligand. Restriction of the rotation of the hydrogen-bonding unit with respect to the metal coordinating site results in a T-symmetric cage, whereas by introducing flexibility either through a methylene linker or rotating…

Numerical and analytical analysis of a monopile-supported offshore wind turbine under ship impacts

Abstract Offshore wind turbines in the vicinity of ship traffic are exposed to increased risks of ship collisions. To better understand the impact mechanism, this paper evaluates the dynamic responses of a monopile-supported wind turbine under ship impacts, using both numerical and analytical methods. The nonlinear finite element method is applied during the numerical simulations, and the wind load effects, soil conditions, and rigid and deformable ship bows are considered. The analytical approach, originally developed based on the energy method, is extended here to address the damping effects of monopile-supported wind turbines. In the case study, the impacts are studied between a 4600-ton…

CCDC 1951280: Experimental Crystal Structure Determination

Related Article: Qixun Shi, Xiaohong Zhou, Wei Yuan, Xiaoshi Su, Algirdas Neniškis, Xin Wei, Lukas Taujenis, Gustautas Snarskis, Jas S. Ward, Kari Rissanen, Javier de Mendoza, Edvinas Orentas|2020|J.Am.Chem.Soc.|142|3658|doi:10.1021/jacs.0c00722