0000000001306537
AUTHOR
P. Osadczuk
N,N,N',N'‐Tetramethylguanidinium tetrachloroantimonate(III) at 295 and 92K
The crystal structure of N,N,N',N'-tetramethylguanidinium tetrachloroantimonate(III), (C 5 H 14 N 3 )[SbCl 4 ], has been determined at 295 and 92 K. Each Sb atom is surrounded by six Cl atoms forming an irregular [SbCl 6 ] 3- octahedron. The octahedra are connected with each other in infinite zigzag chains. There is one crystallographically independent N,N,N',N'-tetramethylguanidinium cation in the crystal structure. It is linked to the [SbCl 6 ] 3- octahedra through N-H...Cl hydrogen bonds. The deformation of the octahedral coordination of the Sb III atom is related to the presence of N-H...Cl hydrogen bonds.
CCDC 135826: Experimental Crystal Structure Determination
Related Article: M.Bujak, P.Osadczuk, J.Zaleski|1999|Acta Crystallogr.,Sect.C:Cryst.Struct.Commun.|55|1443|doi:10.1107/S0108270199008264
CCDC 163897: Experimental Crystal Structure Determination
Related Article: M.Bujak, P.Osadczuk, J.Zaleski|2001|Acta Crystallogr.,Sect.C:Cryst.Struct.Commun.|57|388|doi:10.1107/S0108270101000774
CCDC 163896: Experimental Crystal Structure Determination
Related Article: M.Bujak, P.Osadczuk, J.Zaleski|2001|Acta Crystallogr.,Sect.C:Cryst.Struct.Commun.|57|388|doi:10.1107/S0108270101000774
CCDC 135825: Experimental Crystal Structure Determination
Related Article: M.Bujak, P.Osadczuk, J.Zaleski|1999|Acta Crystallogr.,Sect.C:Cryst.Struct.Commun.|55|1443|doi:10.1107/S0108270199008264