6533b870fe1ef96bd12d074d
RESEARCH PRODUCT
N,N,N',N'‐Tetramethylguanidinium tetrachloroantimonate(III) at 295 and 92K
Maciej BujakP. OsadczukJacek Zaleskisubject
CrystallographyZigzagOctahedronStereochemistryChemistryHydrogen bondAtomMoleculeGeneral MedicineCrystal structureGeneral Biochemistry Genetics and Molecular Biologydescription
The crystal structure of N,N,N',N'-tetramethylguanidinium tetrachloroantimonate(III), (C 5 H 14 N 3 )[SbCl 4 ], has been determined at 295 and 92 K. Each Sb atom is surrounded by six Cl atoms forming an irregular [SbCl 6 ] 3- octahedron. The octahedra are connected with each other in infinite zigzag chains. There is one crystallographically independent N,N,N',N'-tetramethylguanidinium cation in the crystal structure. It is linked to the [SbCl 6 ] 3- octahedra through N-H...Cl hydrogen bonds. The deformation of the octahedral coordination of the Sb III atom is related to the presence of N-H...Cl hydrogen bonds.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 1999-09-15 | Acta Crystallographica Section C-Crystal Structure Communications |