0000000001306777

AUTHOR

Juliusz A. Wolny

showing 10 related works from this author

Fe II Complexes with Triple N 1, N 2‐Triazole Bridge Schiff Base Ligand: Antiferromagnetic Dimer vs. Spin Conversion Trimer

2018

Schiff base010405 organic chemistryLigandDimerTriazole124-TriazoleTrimer010402 general chemistry01 natural sciences0104 chemical sciencesInorganic Chemistrychemistry.chemical_compoundCrystallographychemistrySpin crossoverAntiferromagnetismEuropean Journal of Inorganic Chemistry
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Tin-DNA complexes investigated by nuclear inelastic scattering of synchrotron radiation

2005

Nuclear inelastic scattering (NIS) of synchrotron radiation has been used to investigate the dynamics of tin ions chelated by DNA. Theoretical NIS spectra have been simulated with the help of density functional theory (DFT) calculations using 12 models for different binding sites of the tin ion in (CH3)Sn(DNAPhosphate)2. The simulated spectra are compared with the measured spectrum of the tin-DNA complex.

Chemical Physics (physics.chem-ph)Nuclear and High Energy PhysicsMaterials sciencenuclear inelastic scattering tin–DNASynchrotron radiationchemistry.chemical_elementFOS: Physical sciencesInelastic scatteringCondensed Matter PhysicsMolecular physicsAtomic and Molecular Physics and OpticsSpectral lineIonchemistry.chemical_compoundCondensed Matter::Materials SciencechemistrySettore CHIM/03 - Chimica Generale E InorganicaPhysics - Chemical PhysicsPhysics::Accelerator PhysicsDensity functional theoryPhysical and Theoretical ChemistryTinNuclear ExperimentDNASettore CHIM/02 - Chimica Fisica
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Vibrational spectrum of the spin crossover complex [Fe(phen)(2)(NCS)(2)] studied by IR and Raman spectroscopy, nuclear inelastic scattering and DFT c…

2006

The vibrational modes of the low-spin and high-spin isomers of the spin crossover complex [Fe(phen)(2)(NCS)(2)] (phen = 1,10-phenanthroline) have been measured by IR and Raman spectroscopy and by nuclear inelastic scattering. The vibrational frequencies and normal modes and the IR and Raman intensities have been calculated by density functional methods. The vibrational entropy difference between the two isomers, DeltaS(vib), which is--together with the electronic entropy difference DeltaS(el)--the driving force for the spin-transition, has been determined from the measured and from the calculated frequencies. The calculated difference (DeltaS(vib) = 57-70 J mol(-1) K(-1), depending on the m…

Models MolecularSpectrophotometry InfraredNitrogenAnalytical chemistryGeneral Physics and AstronomyInfrared spectroscopyInelastic scatteringIron Chelating AgentsSpectrum Analysis RamanMolecular physicsHot bandsymbols.namesakeIsomerismNormal modeSpin crossoverFerrous CompoundsPhysics::Chemical PhysicsPhysical and Theoretical ChemistryElectronic entropyChemistryMolecular vibrationsymbolsThermodynamicsSpin LabelsRaman spectroscopyMathematicsPhenanthrolinesPhysical chemistry chemical physics : PCCP
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Dynamics of Metal Centers Monitored by Nuclear Inelastic Scattering

2005

Nuclear inelastic scattering of synchrotron radiation has been used now since 10 years as a tool for vibrational spectroscopy. This method has turned out especially useful in case of large molecules that contain a M\"ossbauer active metal center. Recent applications to iron-sulfur proteins, to iron(II) spin crossover complexes and to tin-DNA complexes are discussed. Special emphasis is given to the combination of nuclear inelastic scattering and density functional calculations.

iron-sulfur proteinspin crossover complexeChemical Physics (physics.chem-ph)Nuclear and High Energy PhysicsMaterials scienceFOS: Physical sciencesSynchrotron radiationInfrared spectroscopyInelastic scatteringCondensed Matter Physicsvibrational spectroscopyAtomic and Molecular Physics and Opticsnuclear inelastic scatteringMetalSettore CHIM/03 - Chimica Generale E InorganicaSpin crossovervisual_artPhysics - Chemical PhysicsMössbauer spectroscopyvisual_art.visual_art_mediumMoleculedensity functional theory calculationsPhysical and Theoretical ChemistryAtomic physicsSettore CHIM/02 - Chimica Fisica
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Spin- and phase transition in the spin crossover complex [Fe(ptz)6](BF4)2 studied by nuclear inelastic scattering of synchrotron radiation and by DFT…

2006

Abstract Nuclear inelastic scattering (NIS) spectra of [Fe(ptz) 6 ](BF 4 ) 2 (ptz = 1- n -propyl-tetrazole) have been measured for five phases differing in spin state and crystallographic structure. Different spectral patterns have been found for the low-spin and high-spin phases and are described in terms of normal coordinate analysis of the complex molecule. For both low-spin and high-spin phases the conversion from ordered to disordered phase results in splitting of the observed NIS bands. Packing becomes visible in the NIS spectra via coupling of the Fe–N stretching vibrations with those of the terminal n -propyl groups. The DFT-based normal coordinate analysis also reveals the characte…

Phase transitionSpin statesChemistryGeneral Physics and AstronomyCrystal structureInelastic scatteringSpectral lineCrystallographysymbols.namesakeSpin crossoversymbolsPhysics::Chemical PhysicsPhysical and Theoretical ChemistrySpin (physics)Raman spectroscopyChemical Physics Letters
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Vibrational properties of 1D- and 3D polynuclear spin crossover Fe(II) urea-triazoles polymer chains and quantification of intrachain cooperativity

2020

Abstract The vibrational dynamics of the iron centres in 1D and 3D spin crossover Fe(II) 4-alkyl-urea triazole chains have been investigated by synchrotron based nuclear inelastic scattering. For the 1D system, the partial density of phonon states has been modelled with density functional theory methods. Furthermore, spin dependent iron ligand distances and vibrational modes were obtained. The previously introduced intramolecular cooperativity parameter H coop (Rackwitz et al, Phys. Chem. Chem. Phys. 2013, 15, 15450) has been determined to −31 kJ mol−1 for [Fe(n-Prtrzu)3(tosylate)2] and to +27 kJ mol−1 for [Fe(n-Prtrzu)3(BF4)2]. The change of sign in H coop is in line with the incomplete an…

Coordination sphereMaterials scienceSpin statesSpin transitionCooperativity02 engineering and technologyInelastic scattering021001 nanoscience & nanotechnologyCondensed Matter Physics01 natural sciencesCrystallographySpin crossoverIntramolecular force0103 physical sciencesGeneral Materials ScienceDensity functional theory010306 general physics0210 nano-technologyJournal of Physics: Condensed Matter
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CCDC 1587515: Experimental Crystal Structure Determination

2018

Related Article: Ai-Min Li, Tim Hochdoerffer, Juliusz A. Wolny, Volker Schuenemann, Eva Rentschler|2018|Eur.J.Inorg.Chem.|2018|4190|doi:10.1002/ejic.201800784

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinatestris(mu-4-(p-tolylidene-amino)-4H-124-triazole)-bis(4-(p-tolylidene-amino)-4H-124-triazole)-tetrakis(isoselenocyanato)-di-iron(ii) trihydrate
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CCDC 1587514: Experimental Crystal Structure Determination

2018

Related Article: Ai-Min Li, Tim Hochdoerffer, Juliusz A. Wolny, Volker Schuenemann, Eva Rentschler|2018|Eur.J.Inorg.Chem.|2018|4190|doi:10.1002/ejic.201800784

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterstris(mu-4-(p-tolylidene-amino)-4H-124-triazole)-bis(4-(p-tolylidene-amino)-4H-124-triazole)-tetrakis(thiocyanato)-di-iron(ii) trihydrateExperimental 3D Coordinates
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CCDC 1587516: Experimental Crystal Structure Determination

2018

Related Article: Ai-Min Li, Tim Hochdörffer, Juliusz A. Wolny, Volker Schünemann, Eva Rentschler|2018|Eur.J.Inorg.Chem.||4190|doi:10.1002/ejic.201800784

Space GroupCrystallographyhexakis(mu-1-(4-methylphenyl)-N-(4H-124-triazol-4-yl)methanimine)-hexa-aqua-tri-iron hexakis(tetrafluoroborate) ethyl acetate solvate tetrahydrateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1587517: Experimental Crystal Structure Determination

2018

Related Article: Ai-Min Li, Tim Hochdoerffer, Juliusz A. Wolny, Volker Schuenemann, Eva Rentschler|2018|Eur.J.Inorg.Chem.|2018|4190|doi:10.1002/ejic.201800784

Space GroupCrystallographyhexakis(mu-1-(4-methylphenyl)-N-(4H-124-triazol-4-yl)methanimine)-hexa-aqua-tri-iron hexakis(tetrafluoroborate) ethyl acetate solvate tetrahydrateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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