0000000001312908
AUTHOR
Bram Verbelen
Efficient two-step synthesis of water soluble BODIPY–TREN chemosensors for copper(II) ions
Two simple fluorescent sensors for Cu(II) ions were synthesized in two reaction steps, using recently developed C–H functionalization reactions for boron dipyrrins, starting from a standard 8-aryl-BODIPY dye and a tris(2-aminoethyl)amine (TREN) ligand. At pH 5, the resulting BODIPY–TREN conjugates are demonstrated to be promising, highly selective, water soluble, Cu(II) sensors that can permeate the cell membrane. crosscheck: This document is CrossCheck deposited related_data: Supplementary Information identifier: Bram Verbelen (ORCID) identifier: Wim Dehaen (ORCID) copyright_licence: The Royal Society of Chemistry has an exclusive publication licence for this journal copyright_licence: Thi…
From One-Pot NH-Sulfoximidations of Thiophene Derivatives to Dithienylethene-Type Photoswitches
Thiophene NH-sulfoximines have been synthesized using a one-pot NH-sulfoximidation reaction of thiophenes. The reactivity of the products was investigated, and the developed protocols were used for the synthesis of a new class of dithienylethene-type photoswitches containing a sulfoximidoyl group.
CCDC 1894289: Experimental Crystal Structure Determination
Related Article: Bram Verbelen, Eric Siemes, Andreas Ehnbom, Christoph Räuber, Kari Rissanen, Dominik Wöll, Carsten Bolm|2019|Org.Lett.|21|4293|doi:10.1021/acs.orglett.9b01475