0000000001315000
AUTHOR
Magdalena Kowalska
Evolution of nuclear structure in neutron-rich odd-Zn isotopes and isomers
Collinear laser spectroscopy was performed on Zn (Z=30) isotopes at ISOLDE, CERN. The study of hyperfine spectra of nuclei across the Zn isotopic chain, N=33–49, allowed the measurement of nuclear spins for the ground and isomeric states in odd-A neutron-rich nuclei up to N=50. Exactly one long-lived (&
Measurement of the Spin and Magnetic Moment ofMg31: Evidence for a Strongly Deformed Intruder Ground State
Unambiguous values of the spin and magnetic moment of $^{31}\mathrm{M}\mathrm{g}$ are obtained by combining the results of a hyperfine-structure measurement and a $\ensuremath{\beta}$-NMR measurement, both performed with an optically polarized ion beam. With a measured nuclear $g$ factor and spin $I=1/2$, the magnetic moment $\ensuremath{\mu}(^{31}\mathrm{M}\mathrm{g})=\ensuremath{-}0.88355(15){\ensuremath{\mu}}_{N}$ is deduced. A revised level scheme of $^{31}\mathrm{M}\mathrm{g}$ ($Z=12$, $N=19$) with ground state spin/parity ${I}^{\ensuremath{\pi}}=1/{2}^{+}$ is presented, revealing the coexistence of 1p-1h and 2p-2h intruder states below 500 keV. Advanced shell-model calculations and th…
2-Acylamino-6-pyridones: breaking of an intramolecular hydrogen bond by self-association and complexation with double and triple hydrogenbonding counterparts. Uncommon steric effect on intermolecular interactions
2-Acylamino-6-pyridones (acyl = RCO, where R = Me, Et, i-Pr, t-Bu, and 1-adamantyl) were previously characterized by X-ray diffractometry and solid-state NMR techniques by us. One of these compounds was used recently in organocatalysis. The series is now studied in solution and by computational methods recommended for noncovalent interactions (DFT/M05). These compounds showed interesting behavior during dilution and titration experiments monitored by (1)H NMR. 2-Acylamino-6-pyridones change their conformation at higher concentrations, forming double hydrogen-bonded dimers and trimers in which an uncommon steric effect is observed. To the best of our knowledge, this is the first example of s…
The influence of CH bond polarization on the self-association of 2-acylaminopyrimidines by NH/CH···O/N interactions: XRD, NMR, DFT, and AIM study
The single crystal structures of two 2-acylaminopyrimidines, where alkyl groups in acyl moiety are iso-propyl (1) and dichloromethyl (2), were solved by X-ray diffraction method. The strength of intermolecular hydrogen bonding interactions depends on the C–H bond polarization increased by exchanging two methyl groups by chlorine atoms in the adjacent substituent. The computational methods provide an additional insight into the intermolecular interactions and are utilized in explaining the differences in the observed crystal structures. The experimental and computational data together explain the differences in the formed aggregates and revealed that these simple substitutions cause crucial …
Billion-Fold Enhancement in Sensitivity of Nuclear Magnetic Resonance Spectroscopy for Magnesium Ions in Solution
Beta-nuclear magnetic resonance (NMR) spectroscopy is highly sensitive compared to conventional NMR spectroscopy, and may be applied for several elements across the periodic table. Beta-NMR has previously been successfully applied in the fields of nuclear and solid-state physics. In this work, beta-NMR is applied, for the first time, to record an NMR spectrum for a species in solution. 31Mg b-NMR spectra are measured for as few as 10^7 magnesium ions in ionic liquid (EMIM-Ac) within minutes, as a prototypical test case. Resonances are observed at 3882.9 and 3887.2 kHz in an external field of 0.3 T. The key achievement of the current work is to demonstrate that beta-NMR is applicable for the…
Precision Measurement ofLi11Moments: Influence of Halo Neutrons on theLi9Core
The electric quadrupole moment and the magnetic moment of the 11Li halo nucleus have been measured with more than an order of magnitude higher precision than before, |Q| = 33.3(5) mb and mu = +3.6712(3)muN, revealing a 8.8(1.5)% increase of the quadrupole moment relative to that of 9Li. This result is compared to various models that aim at describing the halo properties. In the shell model an increased quadrupole moment points to a significant occupation of the 1d orbits, whereas in a simple halo picture this can be explained by relating the quadrupole moments of the proton distribution to the charge radii. Advanced models so far fail to reproduce simultaneously the trends observed in the r…
Ground-state spins and moments of72,74,76,78Ga nuclei
Laser spectroscopy was performed on the ${}^{72,74,76,78}$Ga isotopes at On-Line Isotope Mass Separator (ISOLDE) facility, CERN. Ground-state nuclear spins and moments were extracted from the measured hyperfine spectra. The results are compared to shell-model calculations, which provide a detailed probe of the nuclear wave function. The spin is established from the shape of the hyperfine structure and the parity inferred from a comparison of shell-model calculations with the measured nuclear moments. The ground states of ${}^{76,78}$Ga are both assigned a spin and parity of ${I}^{\ensuremath{\pi}}={2}^{\ensuremath{-}}$, while ${}^{74}$Ga is tentatively assigned as ${I}^{\ensuremath{\pi}}={3…
Association of N-(Pyridin-2-yl),N′-substituted Ureas with 2-Amino-1,8-naphthyridines and Benzoates: NMR and Quantum Chemical Studies of the Substituent Effect on Complexation
Association of four N-(pyridin-2-yl),N'-R(1)-ureas (R(1) = ethyl, n-butyl, phenyl, and tert-butyl) with substituted 2-amino-1,8-naphthyridines and benzoates were studied by (1)H NMR spectroscopic titrations and quantum chemical calculations. The benzoates and 2-amino-1,8-naphthyridines were selected as representatives of double and triple hydrogen bonding counterparts, respectively. The classical substituent effect on the association was studied. A prerequisite and a crucial step for the complex formation was the breaking of the intramolecular hydrogen bond in urea derivatives. The QTAIM calculation method was employed to explain the hydrogen bonding within complexes. In the case of benzoat…
Nuclear ground-state spins and magnetic moments ofMg27,Mg29, andMg31
The ground-state spins and magnetic moments of neutron-rich {sup 27}Mg, {sup 29}Mg, and {sup 31}Mg were measured for the first time with laser and {beta}-NMR spectroscopy at ISOLDE/CERN. The hyperfine structure of {sup 27}Mg--observed in fluorescence--confirms previous assignments of the spin I=1/2 and reveals the magnetic moment {mu}{sub I}({sup 27}Mg)=-0.4107(15){mu}{sub N}. The hyperfine structure and nuclear magnetic resonance of optically polarized {sup 29}Mg--observed in the asymmetry of its {beta} decay after implantation in a cubic crystal--give I=3/2 and {mu}{sub I}({sup 29}Mg)=+0.9780(6){mu}{sub N}. For {sup 31}Mg they yield together I=1/2 and {mu}{sub I}({sup 31}Mg)=-0.88355(15){…
Charge radius changes of even-even neutron-rich Tellurium isotopes
Laser spectroscopy based on resonant ionization of laser-desorbed atoms has been used to study the neutron-rich tellurium isotopes with the COMPLIS facility at ISOLDE-CERN. The isotope shift and the hyperfine structure of several neutron-rich Te isotopes: $^{120–136}$Te and $^{123m–133m}$Te have been measured. From the hyperfine structure and the isotope shift we can extract the magnetic and quadrupole moments and the change in the mean square charge radius respectively. The mean square charge radii of the even-even isotopes have been deduced and their comparison with the known data for the other elements near Z=50 is presented. The experimental $\delta$ is compared with that obtained from …
Approaching theN=82shell closure with mass measurements of Ag and Cd isotopes
Mass measurements of neutron-rich Cd and Ag isotopes were performed with the Penning trap mass spectrometer ISOLTRAP. The masses of ${}^{112,114\ensuremath{-}124}$Ag and ${}^{114,120,122\ensuremath{-}124,126,128}$Cd, determined with relative uncertainties between $2\ifmmode\times\else\texttimes\fi{}{10}^{\ensuremath{-}8}$ and $2\ifmmode\times\else\texttimes\fi{}{10}^{\ensuremath{-}7}$, resulted in significant corrections and improvements of the mass surface. In particular, the mass of $^{124}\mathrm{Ag}$ was previously unknown. In addition, other masses that had to be inferred from $Q$ values of nuclear decays and reactions have now been measured directly. The analysis includes various mass…
Mg isotopes and the disappearance of magic N=20 Laser and β-NMR studies
Collinear laser spectroscopy and β-NMR spectroscopy with optical pumping were applied at ISOLDE/CERN to measure for the first time the magnetic moments of neutron-rich 27Mg, 29Mg, 31Mg and 33Mg, along with the spins of the two latter. The magnetic moment of 27Mg was derived from its hyperfine structure detected in UV fluorescent light, whereas the nuclear magnetic resonance observed in β-decay asymmetry from a polarised ensemble of nuclei gave the magnetic moment of 29Mg. For 31Mg and 33Mg, the hyperfine structure and nuclear magnetic resonance gave the spin and the magnetic moment. The preliminary results for 27Mg and 29Mg are consistent with a large neutron shell gap at N=20, whereas data…
Magnetic and quadrupole moments of neutron deficient 58-62Cu isotopes
Abstract This paper reports on the ground state nuclear moments measured in 58–62Cu using collinear laser spectroscopy at the ISOLDE facility. The quadrupole moments for 58–60Cu have been measured for the first time as Q ( Cu 58 ) = − 15 ( 3 ) efm 2 , Q ( Cu 59 ) = − 19.3 ( 19 ) efm 2 , Q ( Cu 60 ) = + 11.6 ( 12 ) efm 2 and with higher precision for 61,62Cu as Q ( Cu 61 ) = − 21.1 ( 10 ) efm 2 , Q ( Cu 62 ) = − 2.2 ( 4 ) efm 2 . The magnetic moments of 58,59Cu are measured with a higher precision as μ ( Cu 58 ) = + 0.570 ( 2 ) μ N and μ ( Cu 59 ) = + 1.8910 ( 9 ) μ N . The experimental nuclear moments are compared to large-scale shell-model calculations with the GXPF1 and GXPF1A effective i…
Nuclear charge radii of 62−80Zn and their dependence on cross-shell proton excitations
Nuclear charge radii of 62−80Zn have been determined using collinear laser spectroscopy of bunched ion beams at CERN-ISOLDE. The subtle variations of observed charge radii, both within one isotope and along the full range of neutron numbers, are found to be well described in terms of the proton excitations across the Z=28 shell gap, as predicted by large-scale shell model calculations. It comprehensively explains the changes in isomer-to-ground state mean square charge radii of 69−79Zn, the inversion of the odd-even staggering around N=40 and the odd-even staggering systematics of the Zn charge radii. With two protons above Z=28, the observed charge radii of the Zn isotopic chain show a cum…
Damping effects in Penning trap mass spectrometry
Abstract Collisions of ions with residual gas atoms in a Penning trap can have a strong influence on the trajectories of the ions, depending on the atom species and the gas pressure. We report on investigations of damping effects in time-of-flight ion-cyclotron resonance mass spectrometry with the Penning trap mass spectrometers ISOLTRAP at ISOLDE/CERN (Geneva, Switzerland) and SHIPTRAP at GSI (Darmstadt, Germany). The work focuses on the interconversion of the magnetron and cyclotron motional modes, in particular the modification of the resonance profiles for quadrupolar excitation due to the damping effect of the residual gas. Extensive experiments have been performed with standard and Ra…
Trap-assisted decay spectroscopy with ISOLTRAP
Penning traps are excellent high-precision mass spectrometers for radionuclides. The high-resolving power used for cleaning isobaric and even isomeric contaminants can be exploited to improve decay-spectroscopy studies by delivering purified samples. An apparatus allowing trap-assisted decay spectroscopy has been coupled to the ISOLTRAP mass spectrometer at ISOLDE/CERN. The results from studies with stable and radioactive ions show that the setup can be used to perform decay studies on purified short-lived nuclides and to assist mass measurements. (C) 2012 Elsevier B.V. All rights reserved.
Precision Test of Many-Body QED in theBe+2pFine Structure Doublet Using Short-Lived Isotopes
Absolute transition frequencies of the $2s\text{ }{^{2}S}_{1/2}\ensuremath{\rightarrow}2p\text{ }{^{2}P}_{1/2,3/2}$ transitions in ${\mathrm{Be}}^{+}$ were measured for the isotopes $^{7,9--12}\mathrm{Be}$. The fine structure splitting of the $2p$ state and its isotope dependence are extracted and compared to results of ab initio calculations using explicitly correlated basis functions, including relativistic and quantum electrodynamics effects at the order of $m{\ensuremath{\alpha}}^{6}$ and $m{\ensuremath{\alpha}}^{7} \mathrm{ln} \ensuremath{\alpha}$. Accuracy has been improved in both the theory and experiment by 2 orders of magnitude, and good agreement is observed. This represents on…
The MORA project
The MORA (Matter's Origin from the RadioActivity of trapped and oriented ions) project aims at measuring with unprecedented precision the D correlation in the nuclear beta decay of trapped and oriented ions. The D correlation offers the possibility to search for new CP-violating interactions, complementary to searches done at the LHC and with Electric Dipole Moments. Technically, MORA uses an innovative in-trap orientation method which combines the high trapping efficiency of a transparent Paul trap with laser orientation techniques. The trapping, detection, and laser setups are under development, for first tests at the Accelerator laboratory, JYFL, in the coming years.
First operational experience of HIE-ISOLDE
The High Intensity and Energy ISOLDE project (HIE-ISOLDE)* is a major upgrade of the ISOLDE facility at CERN. The energy range of the post-accelerator will be extended from 2.85 MeV/u to 9.3 MeV/u for beams with A/q = 4.5 (and to 14.3 MeV/u for A/q = 2.5) once all the cryomodules of the superconducting accelerator are in place. The project has been divided into different phases, the first of which (phase 1a) finished in October 2015 after the hardware and beam commissioning were completed**. The physics campaign followed with the delivery of both radioactive and stable beams to two different experimental stations. The characteristics of the beams (energies, intensities, time structure and b…
Charge radii of neon isotopes across the sd neutron shell
We report on the changes in mean square charge radii of unstable neon nuclei relative to the stable Ne-20, based on the measurement of optical isotope shifts. The studies were carried out using collinear laser spectroscopy on a fast beam of neutral neon atoms. High sensitivity on short-lived isotopes was achieved thanks to nonoptical detection based on optical pumping and state-selective collisional ionization, which was complemented by an accurate determination of the beam kinetic energy. The new results provide information on the structural changes in the sequence of neon isotopes all across the neutron sd shell, ranging from the proton drip line nucleus and halo candidate Ne-17 up to the…
Nuclear Charge Radii ofMg21−32
Charge radii of all magnesium isotopes in the sd shell have been measured, revealing evolution of the nuclear shape throughout two prominent regions of assumed deformation centered on (24)Mg and (32)Mg. A striking correspondence is found between the nuclear charge radius and the neutron shell structure. The importance of cluster configurations towards N=8 and collectivity near N=20 is discussed in the framework of the fermionic molecular dynamics model. These essential results have been made possible by the first application of laser-induced nuclear orientation for isotope shift measurements.
Nuclear spins, magnetic moments, and quadrupole moments of Cu isotopes fromN=28toN=46: Probes for core polarization effects
Measurements of the ground-state nuclear spins and magnetic and quadrupole moments of the copper isotopes from $^{61}\mathrm{Cu}$ up to $^{75}\mathrm{Cu}$ are reported. The experiments were performed at the CERN online isotope mass separator (ISOLDE) facility, using the technique of collinear laser spectroscopy. The trend in the magnetic moments between the $N=28$ and $N=50$ shell closures is reasonably reproduced by large-scale shell-model calculations starting from a $^{56}\mathrm{Ni}$ core. The quadrupole moments reveal a strong polarization of the underlying Ni core when the neutron shell is opened, which is, however, strongly reduced at $N=40$ due to the parity change between the $\mat…
Spin and magnetic moment of23Mg
A negative magnetic moment of 23Mg has been determined by collinear laser spectroscopy at CERN-ISOLDE. The absolute value is in agreement with previous measurements by nuclear magnetic resonance while the sign points at high-seniority configurations. The result is consistent with shell-model predictions for nuclei with valence nucleons in the sd shell. ispartof: Journal of Physics G, Nuclear and Particle Physics vol:44 issue:7 status: published
Tuning the hydrogen bonding strength in 2,6-bis(cycloalkylcarbonylamino)pyridine assemblies by variable flexibility. Association constants measured by hydrogen bonded vs. non-hydrogen bonded protons
International audience; The association of 2,6-bis(cycloalkylcarbonyloamino)pyridines with rigid and non-rigid counterparts was studied in chloroform solution by 1H NMR and computational methods. The angles within the cycloalkyl ring and rotation of these substituents determine the strength of the association via triple hydrogen-bonding. The dimerization and methyl-methyl repulsion have been addressed as mechanisms restricting heterocomplexation of diacetamide. The association constants obtained by the shift changes of hydrogen-bonded protons are in agreement with those of methine protons. This "dual shift" method was proposed as an additional verification of association constants obtained …
g factors of $^{31,32,33}$Al: Indication for intruder configurations in the $^{33}$Al ground state
Abstract The g factors of 31,32,33 Al have been measured using the β -nuclear magnetic resonance ( β -NMR) technique on spin-polarized beams produced in the fragmentation of a 36 S (77.5 MeV/u) beam on a 9 Be target. Nearly pure beams of Al ( Z = 13 ) isotopes were selected with the high-resolution fragment separator LISE at GANIL. An asymmetry as high as 6% has been observed in the β -NMR curve for 32 Al implanted in a Si single crystal. The magnetic moment of the N = 20 nucleus 33 Al is obtained for the first time: μ ( Al 33 , I π = 5 / 2 + ) = 4.088 ( 5 ) μ N , while those of 31,32 Al are obtained with improved accuracy: μ ( Al 31 , I π = 5 / 2 + ) = 3.830 ( 5 ) μ N and μ ( Al 32 , I π =…
CCDC 1422861: Experimental Crystal Structure Determination
Related Article: Borys Ośmiałowski, Karina Mroczyńska, Erkki Kolehmainen, Magdalena Kowalska, Arto Valkonen, Marek Pietrzak, and Kari Rissanen|2013|J.Org.Chem.|78|7582|doi:10.1021/jo4011393
CCDC 1422862: Experimental Crystal Structure Determination
Related Article: Borys Ośmiałowski, Karina Mroczyńska, Erkki Kolehmainen, Magdalena Kowalska, Arto Valkonen, Marek Pietrzak, and Kari Rissanen|2013|J.Org.Chem.|78|7582|doi:10.1021/jo4011393
CCDC 1422860: Experimental Crystal Structure Determination
Related Article: Borys Ośmiałowski, Karina Mroczyńska, Erkki Kolehmainen, Magdalena Kowalska, Arto Valkonen, Marek Pietrzak, and Kari Rissanen|2013|J.Org.Chem.|78|7582|doi:10.1021/jo4011393