0000000001316760

AUTHOR

K. Pihlaja

showing 5 related works from this author

New national and regional biological records for Finland 9:contributions to Bryophyta and Marchantiophyta 8

2018

Five species of mosses (Bryophyta: Oncophorus demetrii, Oncophorus integerrimus, Oxyrrhynchium speciosum, Sphagnum divinum and Sphagnum medium) and one of liverworts (Marchantiophyta: Kurzia trichoclados) are presented as new for Finland. Seligeria calcarea and Seligeria pusilla, previously thought to be regionally extinct from Finland, are reported to being found again. New records in biogeographical provinces for 74 species of mosses and 36 species of liverworts are listed. Finally, 17 occurrences in provinces are removed due to misidentifications or missing specimens. nonPeerReviewed

lajistokartoitussammaletSuomimaksasammaletArtikkelitlehtisammaletFinland
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NMR, X-Ray and MS Investigations of Ethyl 2-Aroyl-and Ethyl 2-Arylcarbamoyl-4,5- dimethyl-1,2,3,6-tetrahydropyridazine-1- carboxylates: Flexible Mult…

1999

The 1H and 13C NMR spectral assignments of ethyl 2-aroyl-4,5-dimethyl-1,2,3,6-tetrahydropyridazine-1-carboxylates (1a-1h) and ethyl 2-arylcarbamoyl-4,5-dimethyl-1,2,3,6-tetrahydropyridazine-1-carboxylates (2a-2k) are given based on DQF COSY, 1H,13C HMQC and 1H,13C HMBC-measurements; the dynamics of the tetrahydropyridazine ring has been studied by 1H, 1H EXSY-technique and the structure of one congener (4′-methylphenyl-derivative, 2a) has been confirmed by X-ray structure analysis.

DenticityStructure analysisStereochemistryChemistry010405 organic chemistryX-rayGeneral ChemistryCarbon-13 NMRRing (chemistry)010402 general chemistryMedicinal chemistry01 natural sciences0104 chemical sciencesJournal of Chemical Research
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Synthesis and structural characterization of cis- and trans-fused 4a,5,6,7,8,8a-hexahydro-2H,4H-1,3-benzodithiines and their 2-methyl and 2,2-dimethy…

2002

Both cis- and trans-fused 4a,5,6,7,8,8a-hexahydro-2H,4H-1,3-benzodithiine together with their 2-methyl and 2,2-dimethyl derivatives were prepared as racemates from the appropriate dithiols obtained via multistep syntheses. The products were characterized by 1 H and 13 C NMR, mass spectrometry, and for two of the cis-fused compounds by X-ray diffraction. 1 H, 1 H vicinal coupling constants indicated that all compounds attain chair-chair conformations as their predominant conformations. All three trans-fused isomers exist in totally biased chair-chair conformations and are essentially conformationally locked, whereas the cis-fused compounds are conformationally mobile and can potentially atta…

chemistry.chemical_compoundchemistryBicyclic moleculeStereochemistryOrganic ChemistryX-ray crystallographyDithiolMoleculeCarbon-13 NMRChemical synthesisConformational isomerismCis–trans isomerismThe Journal of organic chemistry
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CCDC 172657: Experimental Crystal Structure Determination

2002

Related Article: K.D.Klika, L.Janovec, J.Imrich, G.Suchar, P.Kristian, R.Sillanpaa, K.Pihlaja|2002|Eur.J.Org.Chem.|2002|1248|doi:10.1002/1099-0690(200204)2002:73.0.CO;2-H

Space GroupCrystallography3-(anthracen-9-yl)-2-ethylimino-13-thiazolidin-4-oneCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 247963: Experimental Crystal Structure Determination

2005

Related Article: H.Kivela, Z.Zalan, P.Tahtinen, R.Sillanpaa, F.Fulop, K.Pihlaja|2005|Eur.J.Org.Chem.|2005|1189|doi:10.1002/ejoc.200400611

Space GroupCrystallography(2R*4aS*8aS*)-1-methyl-2-phenoxyoctahydro-2H-312-benzoxazaphosphinine 2-oxideCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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