Author: Tianyu Wu

0000000001318192

AUTHOR

Tianyu Wu

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Asymmetric synthesis of cyclopentanes bearing four contiguous stereocenters via an NHC-catalyzed Michael/Michael/esterification domino reaction.

2016

An NHC-catalyzed Michael/Michael/esterification domino reaction via homoenolate/enolate intermediates for the asymmetric synthesis of tetrasubstituted cyclopentanes is described.

CyclopentanesStereochemistry010402 general chemistry01 natural sciencesCatalysisDominoCatalysisStereocenterCascade reactiondomino reactionMaterials Chemistryta116cyclopentane motifs010405 organic chemistryChemistryMetals and AlloysEnantioselective synthesisGeneral Chemistry5400104 chemical sciences3. Good healthSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsChemistryddc:540Ceramics and CompositesChemical communications (Cambridge, England)

researchProduct

ChemInform Abstract: Asymmetric Synthesis of Cyclopentanes Bearing Four Contiguous Stereocenters via an NHC-Catalyzed Michael/Michael/Esterification …

2016

An NHC-catalyzed Michael/Michael/esterification domino reaction via homoenolate/enolate intermediates for the asymmetric synthesis of tetrasubstituted cyclopentanes bearing four contiguous stereocenters is described. A variety of α,β-unsaturated aldehydes and 2-nitroallylic acetates react well with good domino yields and high stereoselectivities.

CyclopentanesBearing (mechanical)Cascade reactionlawChemistryStereochemistryEnantioselective synthesisGeneral MedicineDominolaw.inventionCatalysisStereocenterChemInform

researchProduct

CCDC 1437686: Experimental Crystal Structure Determination

2016

Related Article: Tao Shu, Qijian Ni, Xiaoxiao Song, Kun Zhao, Tianyu Wu, Rakesh Puttreddy, Kari Rissanen, Dieter Enders|2016|Chem.Commun.|52|2609|doi:10.1039/C5CC09581F

Space GroupCrystallographyCrystal SystemCrystal Structureethyl 3-(13-benzodioxol-5-yl)-2-(4-chlorophenyl)-4-nitrocyclopentanecarboxylateCell ParametersExperimental 3D Coordinates

researchProduct

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