0000000001318717
AUTHOR
E. Lhotel
Long-range magnetic order in the porous metal–organic framework Ni(pyrazine)[Pt(CN)4]
A combined study involving DFT calculations, neutron scattering, heat capacity and magnetic measurements at very low temperatures demonstrates the long-range magnetic ordering of Ni(pyrazine)[Pt(CN)4] below 1.9 K, describing its antiferromagnetic spin arrangement. This compound belongs to the family of porous coordination polymers M(pyrazine)[Pt(CN)4] (M = divalent metal), renowned for showing interesting combinations of porosity and magnetic properties. The possibility of including long-range magnetic ordering, one of the most pursued functional properties, opens new perspectives for the multifunctionality of this class of compounds.
CCDC 825207: Experimental Crystal Structure Determination
Related Article: J.Ferrando-Soria, D.Cangussu, M.Eslava, Y.Journaux, R.Lescouezec, M.Julve, F.Lloret, J.Pasan, C.Ruiz-Perez, E.Lhotel, C.Paulsen, E.Pardo|2011|Chem.-Eur.J.|17|12482|doi:10.1002/chem.201101459
CCDC 825208: Experimental Crystal Structure Determination
Related Article: J.Ferrando-Soria, D.Cangussu, M.Eslava, Y.Journaux, R.Lescouezec, M.Julve, F.Lloret, J.Pasan, C.Ruiz-Perez, E.Lhotel, C.Paulsen, E.Pardo|2011|Chem.-Eur.J.|17|12482|doi:10.1002/chem.201101459
CCDC 825209: Experimental Crystal Structure Determination
Related Article: J.Ferrando-Soria, D.Cangussu, M.Eslava, Y.Journaux, R.Lescouezec, M.Julve, F.Lloret, J.Pasan, C.Ruiz-Perez, E.Lhotel, C.Paulsen, E.Pardo|2011|Chem.-Eur.J.|17|12482|doi:10.1002/chem.201101459
CCDC 825210: Experimental Crystal Structure Determination
Related Article: J.Ferrando-Soria, D.Cangussu, M.Eslava, Y.Journaux, R.Lescouezec, M.Julve, F.Lloret, J.Pasan, C.Ruiz-Perez, E.Lhotel, C.Paulsen, E.Pardo|2011|Chem.-Eur.J.|17|12482|doi:10.1002/chem.201101459