6533b7cefe1ef96bd12578d1
RESEARCH PRODUCT
Electric hyperfine interaction in199Hg fluorides
S. LaubachE. KankeleitP. SchwalbachK. Hasselbachsubject
Nuclear and High Energy PhysicsMössbauer effectChemistryHalideElectronQuadrupole splittingCondensed Matter PhysicsAtomic and Molecular Physics and OpticsTetragonal crystal systemQuadrupoleAtomPhysical and Theoretical ChemistryAtomic physicsHyperfine structuredescription
With the current integration technique, the Mossbauer effect on the 158 keV, 5/2−→1/2− transition in199Hg was studied using the cubic HgF2 and the tetragonal Hg2F2 as absorbers; in the latter, a quadrupole splittingeQVzz=}- 9.0(2) mm/s was observed. Electron densities were calculated with the self-consistent-charge-extended-Hueckel-molecular-orbital method and δ〈r2〉=(3.26±0.11) fm2 derived. From the quadrupole splitting and the calculation, an effective antishielding factor almost twice that of the neutral Hg atom is derived.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 1985-12-01 | Hyperfine Interactions |