Regio-specific synthesis of new 1-(tert-butyl)-1H-pyrazolecarboxamide derivatives

6533b7cffe1ef96bd1258e2d

RESEARCH PRODUCT

Regio-specific synthesis of new 1-(tert-butyl)-1H-pyrazolecarboxamide derivatives

Santiago Matías Ruatta Carmen Ramírez De Arellano Marcelo Cesar Murguia Marcelo Cesar Murguia Santos Fustero

subject

Arylamine acylation Regio-specific condensation Pyrazole 010402 general chemistry 01 natural sciences Biochemistry Acylation chemistry.chemical_compound Nucleophile Drug Discovery Organic chemistry Tert butyl Reaction conditions 010405 organic chemistry Chemistry Aryl Otras Ciencias Químicas tert-Butyl hydrazine Organic Chemistry Ciencias Químicas Pyrazole carboxamide Condensation reaction 0104 chemical sciences Diacylation Yield (chemistry)CIENCIAS NATURALES Y EXACTAS

description

Regio-specific and non-regiospecific condensation reactions on 1,3-dicarbonyl compounds rendered 1,3,5-trisubstituted pyrazoles. Herein, the control of regio-specificity was a significant improvement in pyrazole research. A high yield acylation of poorly nucleophilic aryl amines, which resulted in mono- or diacylated products depending on the reaction conditions, is described. As a result, a library of potentially bioactive compounds was obtained. Fil: Ruatta Merke, Santiago Matías. Universidad Nacional del Litoral. Facultad de Bioquímica y Ciencias Biológicas; Argentina Fil: Murguia, Marcelo Cesar. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina. Universidad Nacional del Litoral. Facultad de Bioquímica y Ciencias Biológicas; Argentina Fil: Ramírez de Arellano, Carmen. Universidad de Valencia; España. Organometálicos para la Funcionalización de Entidades Orgánicas. Centro de Innovación en Química Avanzada; España Fil: Fustero, Santos. Universidad de Valencia; España. Centro de Investigaciones Príncipe Felipe; España

year	journal	country	edition	language
2017-06-01

https://fundanet.cipf.es/Publicaciones/ProdCientif/PublicacionFrw.aspx?id=1330

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