6533b7cffe1ef96bd125909b

RESEARCH PRODUCT

Evidence of the Facile Hydride and Enolate Addition to the Imine Bond of an Aluminum−Salophen Complex

Kari RissanenMassimo CamettiLuca RussoAntonella Dalla CortMarcello ColapietroGustavo Portalone

subject

Inorganic Chemistrychemistry.chemical_compoundchemistryNucleophileAluminiumHydridePolymer chemistryIminechemistry.chemical_elementPhysical and Theoretical ChemistryPhotochemistry

description

The isolation of complexes 2 and 3, unambiguously characterized by single-crystal X-ray diffraction, demonstrates that nucleophilic additions to the aluminum-coordinated imino bond of salophen complex 1 can be achieved under very mild conditions.

10.1021/ic701521shttp://hdl.handle.net/11311/655602