6533b7cffe1ef96bd125993a
RESEARCH PRODUCT
Effect of Guest Molecules on Spin Transition Temperature in Loaded Hofmann‐Like Clathrates with Improved Porosity
Lucía Piñeiro-lópezM. Carmen MuñozMaksym SeredukJosé Antonio Realsubject
010405 organic chemistryChemistrySpin transition010402 general chemistry01 natural sciences0104 chemical sciences3. Good healthInorganic ChemistryCrystallographySpin crossoverMoleculeMetal-organic frameworkHost–guest chemistryPorositydescription
The synthesis, crystal structure, magnetic and calorimetric studies of a new clathrate compound of the Hofmann-type spin crossover (SCO) metal-organic framework (MOF) {Fe(bpb)[MII(CN)4]}·xGuest (bpb = bis(4-pyridyl)butadiyne, and MII = Ni, Pt) with characteristic fsc topology is reported. The framework {Fe(bpb)[MII(CN)4]} can host up to 1.5 guest molecules of (trifluoromethyl)benzene and display complete one-step cooperative SCO behavior. Our systematic study on {Fe(bpb)[Pt(CN)4]}·xGuest shows a general reciprocal correlation between the SCO temperature with the volume of the guest molecules.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2020-01-30 | European Journal of Inorganic Chemistry |