6533b7d0fe1ef96bd125a227

RESEARCH PRODUCT

Magnetic Transitions in the Double Perovskite Sr2FeRe1-xFexO6(0≤X≤0.5)

Haitao GaoWolfgang TremelVadim KsenofotovMartin PanthoeferFelser ClaudiaJoachim Barth

subject

CrystallographyMaterials scienceMagnetic momentFerromagnetismFerrimagnetismMössbauer spectroscopyCurie temperatureAntiferromagnetismPerovskite (structure)Solid solution

description

AbstractThe synthesis, structure, and magnetic and transport properties of solid solutions Sr2FeRe1-xFexO6 (0≤x≤0.5) are reported. A structural evolution in the solid solutions from a double perovskite to perovskite is observed with increasing Fe/Re disorder. Except for the metallic parent compound all members of the series are semiconducting. For the Fe-doped samples a change from ferrimagnetic interactions in the parent compound to a complex superposition of ferrimagnetic and antiferromagnetic interactions was observed. The magnetic moment decreases with x, whereas the Curie temperature TC remains unaffected. The magnetic and Mössbauer data suggest Fe to act as a redox-buffer.

https://doi.org/10.1557/proc-1119-l05-07