6533b7d0fe1ef96bd125a42e

RESEARCH PRODUCT

Sterically controlled self-assembly of tetrahedral M(6)L(4) cages via cationic N-donor ligands.

Anssi PeuronenSamu ForsblomManu Lahtinen

subject

chemistry.chemical_classificationSteric effectsChemistryMetals and AlloysSolid-stateCationic polymerizationGeneral ChemistryPolymerCombinatorial chemistryCatalysisSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsMaterials ChemistryCeramics and CompositesTetrahedronSelf-assemblyta116

description

Tripodal cationic N-donor ligands exhibit sterically controlled self-assembly of tetrahedral M6L4 coordination cages that promote selective anion encapsulation (PF6(-)OTf(-)) in the solid state. The described method is a potential template for stepwise assembly of hetero-ligand coordination cages and polymers.

10.1039/c3cc49663ehttps://pubmed.ncbi.nlm.nih.gov/24718313