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RESEARCH PRODUCT
ChemInform Abstract: Glycoside Synthesis via Electrophile-Induced Activation of N-Allyl Carbamates.
Jörg ZimmerHorst Kunzsubject
chemistry.chemical_classificationStereochemistryorganic chemicalsGlycosideGeneral MedicineGlycoside synthesischemistry.chemical_compoundchemistryElectrophileMonosaccharideOrganic chemistrylipids (amino acids peptides and proteins)GlycosylAllyl isocyanatedescription
Abstract O-Benzyl-, O-acyl-, N-acyl- and isopropylidene-protected glycosyl N-allylcarbamates, obtained from anomerically unprotected monosaccharides and allyl isocyanate, are activated by an electrophile-induced cyclisation and react with hydroxyl compounds to form the corresponding glycosides.
year | journal | country | edition | language |
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2010-08-20 | ChemInform |