6533b7d0fe1ef96bd125b641

RESEARCH PRODUCT

ChemInform Abstract: Glycoside Synthesis via Electrophile-Induced Activation of N-Allyl Carbamates.

Jörg ZimmerHorst Kunz

subject

chemistry.chemical_classificationStereochemistryorganic chemicalsGlycosideGeneral MedicineGlycoside synthesischemistry.chemical_compoundchemistryElectrophileMonosaccharideOrganic chemistrylipids (amino acids peptides and proteins)GlycosylAllyl isocyanate

description

Abstract O-Benzyl-, O-acyl-, N-acyl- and isopropylidene-protected glycosyl N-allylcarbamates, obtained from anomerically unprotected monosaccharides and allyl isocyanate, are activated by an electrophile-induced cyclisation and react with hydroxyl compounds to form the corresponding glycosides.

https://doi.org/10.1002/chin.199332238