6533b7d2fe1ef96bd125ea04

RESEARCH PRODUCT

ChemInform Abstract: Synthesis and Self-Assembly of Novel Fluorous Cationic Amphiphiles with a 3,4-Dihydro-2(1H)-pyridone Spacer.

Marina PetrovaBaiba SkriveleIveta VesereRufus SmitsBrigita ViganteOksana PetrichenkoGunars DubursAiva PlotnieceYelena Goncharenko

subject

chemistry.chemical_compoundPyridinium bromideDynamic light scatteringAtomic force microscopyChemistryBromidePolymer chemistryAmphiphileCationic polymerizationGeneral MedicineSelf-assembly

description

Abstract The synthesis of fluorous (highly fluorinated) 3,4-dihydro-2(1 H )-pyridone-5-carboxylate cationic amphiphiles have been described, where the dihydropyridone serves as a spacer and either a pyridinium bromide or a triphenylphosphonium bromide form the polar cationic head group. The in water self-assembled aggregates have been observed by atomic force microscopy (AFM) and dynamic light scattering (DLS).

https://doi.org/10.1002/chin.201142144