ChemInform Abstract: Giant Crown-Shaped Polytungstate Formed by Self-Assembly of CeIII-Stabilized Dilacunary Keggin Fragments.

6533b7d2fe1ef96bd125f38d

RESEARCH PRODUCT

ChemInform Abstract: Giant Crown-Shaped Polytungstate Formed by Self-Assembly of CeIII-Stabilized Dilacunary Keggin Fragments.

Juan M. Gutiérrez-zorrilla Santiago Reinoso Pablo Vitoria Mónica Giménez-marqués José Ramón Galán-mascarós

subject

chemistry.chemical_compound chemistry Yield (chemistry)Inorganic chemistry Crown (botany)Evaporation General Medicine Buffer solution Self-assembly

description

Single crystals of Na40K6[Ni(H2O)6]3 [K@K7Ce24Ge12W120O456 (OH)12(H2O)64]· 178H2O are synthesized by addition of KCl to a NaOAc/AcOH buffer solution containing Ce(NO3)3, GeO2, Na2WO4, and NiCl2 followed by slow evaporation at room temperature (24% yield).

year	journal	country	edition	language
2011-01-13	ChemInform

https://doi.org/10.1002/chin.201106016

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