6533b7d3fe1ef96bd1260846

RESEARCH PRODUCT

Magnetic predissociation in Te 2 B 1 u

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description

We report a registration of magnetic predissociation (MPD) of electronically excited molecules via peculiarities in magnetic field B induced alignment-orientation conversion (AOC). Non-linear magnetic energy shift and heterogeneous MPD produce dispersion type fluorescence circularity signals C(B) of different sign. Measurements on B 1 u - , v(J) equals 2(96) state of 130 Te 2 yielded natural C v het equals plus or minus 6 s -1/2 and magnetic (alpha) v het equals minus or plus 9 multiplied by 10 3 s -1/2 T -1 rate constants of heterogeneous PD, supposing that the B1 u - state PD takes place through O u - state continuum.