<title>Level-crossing spectroscopy of the 7, 9, and 10D states of Cs in an external electric field</title>

We discuss experimental and theoretical studies of coherent excitation of magnetic sublevels in n D states of cesium that cross in an external electric field. Crossings of mF magnetic sublevels of hyperfine F levels with ΔmF = ±2 lead to resonances in the linearly polarized laser induced fluorescence, while crossings with ΔmF = ±1 lead to resonances in the circularly polarized laser induced fluorescence. These resonances can be exploited to observe alignment to orientation conversion. From the level crossing signals it is possible to measure atomic properties, such as the tensor polarizability α2 and the hyperfine constant A . Alignment to orientation conversion involves the deformation of …

Fourier transform spectroscopy and coupled-channel deperturbation treatment of the A1Sigma+ ~ b3Pi complex of KCs molecule

The laser induced fluorescence (LIF) spectra A1Sigma ~ b3Pi --> X1Sigma+ of KCs dimer were recorded in near infrared region by Fourier Transform Spectrometer with a resolution of 0.03 cm-1. Overall more than 200 LIF spectra were rotationally assigned to 39K133Cs and 41K133Cs isotopomers yielding with the uncertainty of 0.003-0.01 cm-1 more than 3400 rovibronic term values of the strongly mixed singlet A1Sigma+ and triplet b3Pi states. Experimental data massive starts from the lowest vibrational level v_A=0 of the singlet and nonuniformly cover the energy range from 10040 to 13250 cm-1 with rotational quantum numbers J from 7 to 225. Besides of the dominating regular A1Sigma+ ~ b3P Omega=…

Spectroscopic data, spin-orbit functions, and revised analysis of strong perturbative interactions for theA 1Σ+andb 3Πstates of RbCs

The current interest in producing ultracold RbCs molecules by optical excitation from weakly bound Feshbach resonances and stimulated decay to the absolute ground state requires detailed analyses of the intermediate excited states. In this study, we present two sets of experimental Fourier-transform spectroscopic data of the $A{ }^{1}{\ensuremath{\Sigma}}^{+}$-$b{ }^{3}\ensuremath{\Pi}$ complex. The $A$-$b$ mixed vibrational levels are the most likely candidates to be intermediates in the molecular formation. The more recent and more accurate data set is from mixed $A$-$b\ensuremath{\rightarrow}X$ transitions, while the second is derived in large part from $(4){ }^{1}{\ensuremath{\Sigma}}^{…

Magnetic predissociation in Te 2 B 1 u

We report a registration of magnetic predissociation (MPD) of electronically excited molecules via peculiarities in magnetic field B induced alignment-orientation conversion (AOC). Non-linear magnetic energy shift and heterogeneous MPD produce dispersion type fluorescence circularity signals C(B) of different sign. Measurements on B 1 u - , v(J) equals 2(96) state of 130 Te 2 yielded natural C v het equals plus or minus 6 s -1/2 and magnetic (alpha) v het equals minus or plus 9 multiplied by 10 3 s -1/2 T -1 rate constants of heterogeneous PD, supposing that the B1 u - state PD takes place through O u - state continuum.

The ground electronic state of KCs studied by Fourier transform spectroscopy

We present here the first analysis of laser induced fluorescence (LIF) of the KCs molecule obtaining highly accurate data and perform a direct potential construction for the X (1)Sigma(+) ground state in a wide range of internuclear distances. KCs molecules were produced by heating a mixture of K and Cs metals in a heat pipe at a temperature of about 270 degrees C. KCs fluorescence was induced by different laser sources: the 454.5, 457.9, 465.8, and 472.7 nm lines of an Ar(+) laser, a dye laser with Rhodamine 6G dye (excitation at around 16 870 cm(-1)), and 850 and 980 nm diode lasers (11 500-11 900 and 10 200-10 450 cm(-1) tuning ranges, respectively). The LIF to the ground state was recor…

Fourier-transform spectroscopy and deperturbation analysis of the spin-orbit coupled A(1)Σ(+) and b(3)Π states of KRb.

Fourier-transform A(1)Σ(+) - b(3)Π → X(1)Σ(+) laser-induced fluorescence spectra were recorded for the natural mixture of (39,41)K(85,87)Rb isotopologues produced in a heatpipe oven. Overall 4200 rovibronic term values of the spin-orbit coupled A(1)Σ(+) and b(3)Π states were determined with an uncertainty of about 0.01 cm(-1) in the energy range [10 850, 14 200] cm(-1) covering rotational quantum numbers J' ∈ [3, 280]. Direct deperturbation analysis of the A ∼ b complex performed within the framework of the A(1)Σ(+) ∼ b(3)ΠΩ=0,1,2 coupled-channel approach reproduced experimental data with a standard deviation of 0.004 cm(-1). Initial parameters of the internuclear potentials and spin-orbit …

Fourier-transform spectroscopy and coupled-channels deperturbation treatment of theA 1Σ+–b 3Πcomplex of KCs

The laser-induced fluorescence (LIF) A {sup 1{Sigma}+}-b {sup 3{Pi}{yields}}X {sup 1{Sigma}+} spectra of the KCs molecule were recorded in a near infrared region by a Fourier-transform spectrometer with a resolution of 0.03 cm{sup -1}. Overall more than 200 collisionally enhanced LIF spectra were rotationally assigned to {sup 39}K{sup 133}Cs and {sup 41}K{sup 133}Cs isotopomers yielding more than 3400 rovibronic term values of the strongly mixed singlet A {sup 1{Sigma}+} and triplet b {sup 3{Pi}} states with the uncertainty of 0.003-0.01 cm{sup -1}. Experimental data massive starts from the lowest vibrational level v{sub A}=0 of the singlet and nonuniformly covers the energy range E is an e…

Fourier-transform spectroscopy and potential construction of the (2)1Π state in KCs

The paper presents an empirical pointwise potential energy curve (PEC) of the (2)(1)Π state of the KCs molecule constructed by applying the Inverted Perturbation Approach routine. The experimental term values in the energy range E(v', J') ∈ [15 407; 16 579] cm(-1) involved in the fit were based on Fourier-Transform spectroscopy data obtained with 0.01 cm(-1) accuracy from the laser-induced (2)(1)Π → X(1)Σ(+) fluorescence spectra. Buffer gas Ar was used to facilitate the appearance of rotation relaxation lines in the spectra, thus enlarging the (2)(1)Π data set and allowing determination of the Λ-splitting constants. The data set included vibrational v' ∈ [0, 28] and rotational J' ∈ [7, 274]…

Potentials for modeling cold collisions between Na (3S) and Rb (5S) atoms

The experimental characterization of the electronic states correlated to the asymptote of ground state Na (3S) and Rb (5S) atoms was expanded by spectroscopic data on $a\phantom{\rule{0.2em}{0ex}}^{3}\ensuremath{\Sigma}^{+}$ state levels using a high resolution Fourier transform spectroscopy technique. The hyperfine splitting of the $a\phantom{\rule{0.2em}{0ex}}^{3}\ensuremath{\Sigma}^{+}$ state levels was partially resolved and analyzed for both $\mathrm{Na}\phantom{\rule{0.2em}{0ex}}^{85}\mathrm{Rb}$ and $\mathrm{Na}\phantom{\rule{0.2em}{0ex}}^{87}\mathrm{Rb}$ isotopomers. Transitions to high lying levels of the $a\phantom{\rule{0.2em}{0ex}}^{3}\ensuremath{\Sigma}^{+}$ and $X\phantom{\rul…

B1(1)Π state of KCs: high-resolution spectroscopy and description of low-lying energy levels.

The diode laser induced B(1)(1)Π → X(1)Σ(+) fluorescence spectra of the KCs molecule were recorded by Fourier-transform spectrometer with resolution of 0.03 cm(-1). Buffer gas Ar was used to facilitate appearance of rotation relaxation lines in the spectra, thus enlarging the B(1)(1)Π dataset, allowing one to determine the Λ-splitting constants and to reveal numerous local perturbations. A dataset was systematically obtained for B(1)(1)Π vibrational levels ν(') ∈ [0; 5] nonuniformly covering rotational levels with J(') ∈ [7; 233]. For ν(') ∈ [0; 3], the less-perturbed data of f-components were included in the fit. A pointwise potential energy curve (PEC) based on the inverted perturbation a…

High resolution spectroscopy and potential determination of the (3)1Pi state of NaCs.

The (3)(1)Pi state of the NaCs molecule was studied by high resolution Fourier-transform spectroscopy. The (3)(1)Pi--X (1)Sigma(+) laser induced fluorescence was excited by an Ar(+) ion laser or by a single-mode frequency-doubled cw Nd:YAG laser. The presence of argon buffer gas yielded rich rotational relaxation spectra allowing to enlarge the data set for the (3)(1)Pi state term values, as well as to observe Lambda splittings in a wide range of vibrational (v(')) and rotational (J(')) quantum numbers. The data field includes about 820 energy levels of (3)(1)Pi NaCs in the range from v(')=0 to 37 and from J(')=3 to 190, which corresponds to ca. 95% of the potential well depth. Direct fit o…

Energy and radiative properties of the (3)1{\Pi} and (5)1{\Sigma}+ states of RbCs: Experiment and theory

We combined high-resolution Fourier-transform spectroscopy and large-scale electronic structure calculation to study energy and radiative properties of the high-lying (3)1{\Pi} and (5)1{\Sigma}+ states of the RbCs molecule. The laser-induced (5)1{\Sigma}+(4)1{\Sigma}+(3)1{\Pi}-A(2)1{\Sigma}+ b(1)3{\Pi} fluorescence (LIF) spectra were recorded by the Bruker IFS-125(HR) spectrometer in the frequency range {\nu} 5500 to 10000cm-1 with the instrumental resolution of 0.03 cm-1. The rotational assignment of the observed LIF progressions, which exhibit irregular vibrational-rotational spacing due to strong spin-orbit interaction between A1{\Sigma}+ and b3(\Pi) states was based on the coincidences …

Solution of the fully-mixed-state problem: Direct deperturbation analysis of theAΣ+1–bΠ3complex in a NaCs dimer

Laser-induced fluorescence (LIF) spectra $(4)\phantom{\rule{0.2em}{0ex}}^{1}\ensuremath{\Sigma}^{+}\ensuremath{\rightarrow}A\phantom{\rule{0.2em}{0ex}}^{1}\ensuremath{\Sigma}^{+}--b\phantom{\rule{0.2em}{0ex}}^{3}\ensuremath{\Pi}$ and collisionally enhanced $A\phantom{\rule{0.2em}{0ex}}^{1}\ensuremath{\Sigma}^{+}--b\phantom{\rule{0.2em}{0ex}}^{3}\ensuremath{\Pi}\ensuremath{\rightarrow}X\phantom{\rule{0.2em}{0ex}}^{1}\ensuremath{\Sigma}^{+}$ LIF spectra measured by Fourier transform spectrometer with the resolution of $0.03--0.05\phantom{\rule{0.3em}{0ex}}{\mathrm{cm}}^{\ensuremath{-}1}$ provided about 1160 term values of the $e$-symmetry rovibronic levels of the fully mixed $A\phantom{\rule{…

Fourier-transform spectroscopy and description of low-lying energy levels in the B(1)(1)Π state of RbCs.

The Fourier transform spectrometer with resolution of 0.03 cm(-1) was applied to disperse the diode laser induced B(1)(1)Π → X(1)Σ(+) fluorescence spectra of the RbCs molecule in a heat pipe. The presence of buffer gas (Ar) produced in the spectra the dense pattern of collision-induced rotation relaxation lines, thus enlarging the B(1)(1)Π data set, allowing to determine the Λ-splitting constants and to reveal numerous local perturbations. In total, 2664 term values for (85)Rb(133)Cs and (87)Rb(133)Cs in the energy range from 13,770 to 15,200 cm(-1) were obtained with accuracy about 0.01 cm(-1). A pointwise potential energy curve (PEC) based on inverted perturbation approach was constructed…

Fourier-transform spectroscopy of (4)1Σ+→A 1Σ+−b 3Π,A 1Σ+−b 3Π →X1Σ+, and (1)3Δ1→bΠ0±3 transitions in KCs and deperturbation treatment ofA 1Σ+andb 3Π states

High resolution Fourier-transform spectroscopy data of term values in the spin-orbit (SO) coupled first excited A 1Σ+ and b 3Π states in KCs were obtained from (4)1Σ+ → A 1Σ+ − b 3Π, A 1Σ+ − b 3Π → X1Σ+, and (1)3Δ1→bΠ0±3 spectra of laser-induced fluorescence (LIF). About 3000 new rovibronic term values of the A 1Σ+ and b3ΠΩ states were obtained with an uncertainty about 0.01 cm−1 and added to the previously obtained 3439 term values in Kruzins et al. [Phys. Rev. A 81, 042509 (2010)] and 30 term values of the b3Π0+ state levels below the A 1Σ+ state in Tamanis et al. [Phys. Rev. A 82, 032506 (2010)]. The data field was extended considerably, going down to vibrational level vb = 0 and up in e…

Optical non-contact electric field mapping by LIF in Cs vapor

We present experimental and theoretical studies of the possibility of using cesium vapor as a tracer gas for optical non-contact electric field mapping. Optical images of electric field distributions have been obtained.

Spontaneous lifetimes and relaxation cross-sections of the D1Π state of NaRb

Abstract The time-resolved intensity of dispersed laser induced fluorescence following the Ar + -laser D 1 Π←X 1 Σ + excitation was measured for both 23 Na 85 Rb and 23 Na 87 Rb isotopomers in a thermal cell. Spontaneous radiative lifetime values determined for v ′ ( J ′ ) rovibronic levels of the D 1 Π state in the v ′ range from 0 to 17 and J ′ from 8 to 131 varied from 22.5 to 17.3 ns. Averaged collisional quenching cross-section values of (3–6)×10 −14 cm 2 were obtained for NaRb (D 1 Π, v ′ , J ′ ) + Rb collisions from the Stern–Volmer plots.

Hyperfine structure of the 3d34s4p6G multiplet of atomic vanadium

The spectrum of atomic vanadium was recorded using high-resolution Fourier transform spectroscopy with optical bandpass filters in the wavelength range from 360 to 500 nm. Vanadium atoms are produced and excited in a hollow-cathode discharge. The main focus lies on the determination of the magnetic dipole hyperfine constants A of the lowest multiplet of odd parity, the 6G of the configuration 3d34s4p, the hyperfine structure (HFS) of which was unknown to date. The HFS of the lines, connecting this multiplet with the multiplets 3d34s5s 6F, 3d34s4d 6H and 3d34s4d 6G, was observed and analysed. New results are presented for all six levels belonging to 3d34s4p 6G as well as for seven high-lying…

Laser synthesis of ultracold alkali metal dimers: optimization and control

Fourier transform spectroscopy, relativistic electronic structure calculation, and coupled-channel deperturbation analysis of the fully mixed $A^1\Sigma^+_u$ and $b^3\Pi_u$ states of Cs$_2$

The 4503 rovibronic term values belonging to the mutually perturbed $A^1\Sigma^+_u$ and $b^3\Pi_u$ states of Cs$_2$ were extracted from laser induced fluorescence (LIF) $A\sim b\rightarrow X^1\Sigma^+_g$ Fourier transform spectra with the 0.01 cm$^{-1}$ uncertainty. The experimental term values of the $A^1\Sigma^+_u\sim b^3\Pi_u$ complex covering the rotational levels $J\in [4,395]$ in the excitation energy range $[9655,13630]$ cm$^{-1}$ were involved into coupled-channel (CC) deperturbation analysis. The deperturbation model takes explicitly into account spin-orbit coupling of the $A^1\Sigma^+_u(A0^+_u)$ and $b^3\Pi^+_{0_u}(b0^+_u)$ states as well as spin-rotational interaction between the…

Level-crossing spectroscopy of the 7, 9, and10D5∕2states ofCs133and validation of relativistic many-body calculations of the polarizabilities and hyperfine constants

We present an experimental and theoretical investigation of the polarizabilities and hyperfine constants of D{sub J} states in {sup 133}Cs for J=3/2 and 5/2. Experimental values for the hyperfine constant A are obtained from level-crossing signals of the (7,9,10)D{sub 5} at {sub {approx}}{sub sol{approx}} at {sub 2} states of {sup 133}Cs and precise calculations of the tensor polarizabilities {alpha}{sub 2}. The results of relativistic many-body calculations for scalar and tensor polarizabilities of the (5-10)D{sub 3} at {sub {approx}}{sub sol{approx}} at {sub 2} and (5-10)D{sub 5} at {sub {approx}}{sub sol{approx}} at {sub 2} states are presented and compared with measured values from the …

Experimental studies of the NaRb ground-state potential up to thev″=76level

Laser induced fluorescence spectra of the C {sup 1}{sigma}{sup +}-X {sup 1}{sigma}{sup +} system of {sup 23}Na{sup 85}Rb and {sup 23}Na{sup 87}Rb have allowed vibrational levels of the electronic ground state up to v{sup ''}=76, spanning 99.85% of the potential well to be observed. The ground-state term values have been fitted to a Dunham polynomial expansion, and also to a direct modified Lennard-Jones (MLJ) potential. The analytical MLJ construction allowed us to match previous measured term values for v{sup ''}{<=}30 with long-range behavior of the potential through the intermediate internuclear distance region covered by the present investigation.

Level-crossing spectroscopy of the 7, 9, and 10D_5/2 states of 133Cs and validation of relativistic many-body calculations of the polarizabilities and hyperfine constants

We present an experimental and theoretical investigation of the polarizabilities and hyperfine constants of D_J states in 133Cs for J=3/2 and J=5/2. New experimental values for the hyperfine constant A are obtained from level-crossing signals of the (7,9,10)D_5/2 states of 133Cs and precise calculations of the tensor polarizabilities alpha_2. The results of relativistic many-body calculations for scalar and tensor polarizabilities of the (5-10)D_3/2 and (5-10)D_5/2 states are presented and compared with measured values from the literature. Calculated values of the hyperfine constants A for these states are also presented and checked for consistency with experimental values.

Extended Fourier-transform spectroscopy studies and deperturbation analysis of the spin-orbit coupled A1Σ+ and b3Π states in RbCs.

The article presents a study of the strongly spin-orbit coupled singlet A(1)Σ(+) and triplet b(3)Π states of the RbCs molecule, which provide an efficient optical path to transfer ultracold molecules to their rovibrational ground state. Fourier-transform A(1)Σ(+) - b(3)Π → X(1)Σ(+) and (4)(1)Σ(+) → A(1)Σ(+) - b(3)Π laser-induced fluorescence (LIF) spectra were recorded for the natural mixture of the (85)Rb(133)Cs and (87)Rb(133)Cs isotopologues produced in a heat pipe oven. Overall 8730 rovibronic term values of A(1)Σ(+) and b(3)Π states were determined with an uncertainty of 0.01 cm(-1) in the energy range [9012, 14087] cm(-1), covering rotational quantum numbers J ∈ [6, 324]. An energy-ba…

Fourier transform spectroscopy and direct potential fit of a shelflike state: application to E(4)1Σ(+) KCs.

The paper presents high-resolution experimental study and a direct potential construction of a shelflike state E(4)(1)Σ(+) of the KCs molecule converging to K(4(2)S) + Cs(5(2)D) atomic limit; such data are of interest for selecting optical paths for producing and monitoring cold polar diatomics. The collisionally enhanced laser induced fluorescence (LIF) spectra corresponding to both spin-allowed E(4)(1)Σ(+) → X(1)(1)Σ(+) and spin-forbidden E(4)(1)Σ(+) → a(1)(3)Σ(+) transitions of KCs were recorded in visible region by Fourier transform spectrometer with resolution of 0.03 cm(-1). Overall about 1650 rovibronic term values of the E(4)(1)Σ(+) state of (39)K(133)Cs and (41)K(133)Cs isotopologu…

Studies of rotational level Λ-doubling by rf-optical double resonance spectroscopy: application to NaK D1Π

Abstract We report here the application of optical-radio frequency double resonance spectroscopy for individual rotational levels of the NaK D 1 Π state. Lambda doubling constant q values for five ν′, J ′ levels are obtained. These data are combined with measurements of dc e - f Stark-mixing-induced changes in optical spectra, and the electric dipole moment d p in the D 1 Π state is determined.

The coupling of the X1Σ+and a3Σ+states of the atom pair Na + Cs and modelling cold collisions

The states X1?+ and a3?+ correlated to the ground-state asymptote of Na (3s) and Cs (6s) atoms have been experimentally investigated using high resolution Fourier-transform spectroscopy. The hyperfine splitting of the a3?+ state levels is partially resolved. Transitions to asymptotic vibrational levels of the a3?+ and X1?+ states were recorded simultaneously. The joint evaluation of the data of both the a3?+ and the X1?+ states allows us to determine accurate potential energy curves of both electronic states. Coupled-channels calculations are finally applied for deriving long range dispersion parameters and the exchange contribution of the molecular potentials, yielding a reliable descripti…

Line Identification of Atomic and Ionic Spectra of Holmium in the Near-UV. II. Spectra of Ho ii and Ho iii

Fourier Transform spectra of holmium (Ho) in the UV spectral range from 31,530 to 25,000 cm−1 (317 to 400 nm) have been investigated, particularly focusing on the ionic lines. The distinction between the different degrees of ionization (I, II, and III) is based on differences in signal-to-noise ratios from two Ho spectra, which have been measured with different buffer gases, i.e., neon and argon. Based on 106 known Ho ii and 126 known Ho iii energy levels, 97 lines could be classified as transitions of singly ionized Ho and 9 lines could be classified as transitions of doubly ionized Ho. Of the 97 Ho ii lines, 6 have not been listed in the extant literature. Another 215 lines have been assi…

Fourier-transform spectroscopy, direct potential fit, and electronic structure calculations on the entirely perturbed (4) 1Π state of RbCs

We perform a high-resolution Fourier-transform spectroscopic study of the $(4){\phantom{\rule{0.16em}{0ex}}}^{1}\mathrm{\ensuremath{\Pi}}$ state of the RbCs molecule by applying two-step $(4){\phantom{\rule{0.16em}{0ex}}}^{1}\mathrm{\ensuremath{\Pi}}\ensuremath{\leftarrow}A{\phantom{\rule{0.16em}{0ex}}}^{1}{\mathrm{\ensuremath{\Sigma}}}^{+}\ensuremath{\sim}b{\phantom{\rule{0.16em}{0ex}}}^{3}\mathrm{\ensuremath{\Pi}}\ensuremath{\leftarrow}X{\phantom{\rule{0.16em}{0ex}}}^{1}{\mathrm{\ensuremath{\Sigma}}}^{+}$ optical excitation followed by observation of the $(4){\phantom{\rule{0.16em}{0ex}}}^{1}\mathrm{\ensuremath{\Pi}}\ensuremath{\rightarrow}X{\phantom{\rule{0.16em}{0ex}}}^{1}{\mathrm{\ensu…

Electric-Field-Induced Symmetry Breaking of Angular Momentum Distribution in Atoms

We report the experimental observation of alignment to orientation conversion in the 7D_3/2 and 9D_3/2 states of Cs in the presence of an external dc electric field, and without the influence of magnetic fields or atomic collisions. Initial alignment of angular momentum states was created by two-step excitation with linearly polarized laser radiation. The appearance of transverse orientation of angular momentum was confirmed by the observation of circularly polarized light. We present experimentally measured signals and compare them with the results of a detailed theoretical model based on the optical Bloch equations.

Experimental study of the long range interactions between a Na (3S) and a Rb (5S) atom

Transitions to near asymptotic levels of the a3Σ+ and the X1Σ+ electronic states in NaRb were recorded by high resolution Fourier transform spectroscopy technique. The hyperfine splitting of the a3Σ+ state levels was analysed. The application of coupled channels calculations is discussed for determination of accurate potential energy curves of the a3Σ+ and the X1Σ+ states capable for reliable description of cold collisions between a Na and a Rb atoms in their ground states.

Electric field induced alignment-orientation conversion in diatomic molecules: analysis and observation for NaK

This article reports the observation of the molecular fluorescence circularity under irradiation with linearly polarised light. This alignment-orientation conversion phenomenon arises as a result of partial transformation from alignment of the ensemble of 1 P state molecular angular momenta into their orientation under the effect of non-linear dc Stark effect. Circularity rate up to 0.12 was observed in D 1 P! X 1 S fluorescence of 23 Na 39 K molecules in agreement with the theoretically predicted value.

Spectroscopic studies of the(4)1Σ+state of RbCs and modeling of the optical cycle for ultracoldX 1Σ+(v=0,J=0)molecule production

We performed high-resolution Fourier-transform spectroscopy measurements and direct-potential-fit of the shelflike RbCs $(4){\phantom{\rule{0.16em}{0ex}}}^{1}{\ensuremath{\Sigma}}^{+}$ state. Overall, 2317 rovibronic ${v}^{\ensuremath{'}},{J}^{\ensuremath{'}}$ term values with ${v}^{\ensuremath{'}}\ensuremath{\in}[3,88]$, ${J}^{\ensuremath{'}}\ensuremath{\in}[7,276]$ were obtained with accuracy 0.01 cm${}^{\ensuremath{-}1}$ from the $(4){\phantom{\rule{0.16em}{0ex}}}^{1}{\ensuremath{\Sigma}}^{+}\ensuremath{\rightarrow}X{\phantom{\rule{0.16em}{0ex}}}^{1}{\ensuremath{\Sigma}}^{+},a{\phantom{\rule{0.16em}{0ex}}}^{3}{\ensuremath{\Sigma}}^{+}$ laser-induced fluorescence (LIF) spectra. The mass-i…

NaK Λ doubling and permanent electric dipoles in low-lying1Πstates: Experiment and theory

The paper presents \ensuremath{\Lambda} splittings and q factors in the NaK $D{}^{1}\ensuremath{\Pi}$ state, directly measured from the electric radio-frequency-optical double resonance (RF-ODR) in laser-induced fluorescence (LIF) for a number of vibrational states $v=1--22$ with definite rotational levels J between 7 and 46. Permanent electric dipole moment values (d) have been obtained by measuring in LIF spectra the relative intensities of ``forbidden'' lines caused by dc Stark effect induced $e/f$ mixing in the ${}^{1}\ensuremath{\Pi}$ state, with their subsequent processing, which allowed us to obtain the $q/d$ ratio. A possible influence of the hyperfine structure on the RF-ODR signal…

Coupling of theXΣ+1andaΣ+3states ofKRb

A comprehensive study of the electronic states at the $4s+5s$ asymptote in $\mathrm{KRb}$ is presented. Abundant spectroscopic data on the $a\phantom{\rule{0.2em}{0ex}}^{3}\ensuremath{\Sigma}^{+}$ state were collected by Fourier-transform spectroscopy, which allows one to determine an accurate experimental potential energy curve up to $14.8\phantom{\rule{0.3em}{0ex}}\mathrm{\AA{}}$. The existing data set [C. Amiot et al., J. Chem. Phys. 112, 7068 (2000)] on the ground state $X\phantom{\rule{0.2em}{0ex}}^{1}\ensuremath{\Sigma}^{+}$ was extended by several additional levels lying close to the atomic asymptote. In a coupled channels fitting routine complete molecular potentials for both electr…

On Oscillation Theorem for Two-Component Schrodinger Equation

Conventional one-dimensional oscillation theorem is found to be violated for multi-component Schr\"{o}dinger equations in a general case while for two-component eigenstates coupled by the sign-constant potential operator the following statements are valid: (1) the ground state ($v = 0$) is not degenerate; and (2) the arithmetic mean of nodes $n_1$, $n_2$ for the two-component wavefunction never exceeds the ordering number $v$ of eigenstate: $(n_1 + n_2)/2\leq v$.

Line Identification of Atomic and Ionic Spectra of Holmium in the Visible Spectral Range. I. Spectrum of Ho i

Permanent electric dipoles andΛ-doubling constants in the lowestΠ1states of RbCs

The article presents first experimental data on the Stark induced $e\text{\ensuremath{-}}f$ mixing in the $(4)\phantom{\rule{0.2em}{0ex}}^{1}\ensuremath{\Pi}$ state of the $^{85}\mathrm{Rb}^{133}\mathrm{Cs}$ molecule, as well as the ab initio calculations of permanent electric dipole moments $(d)$ in the $(1,2,3,4)\phantom{\rule{0.2em}{0ex}}^{1}\ensuremath{\Pi}$ states and $q$ factors in the $(2,4)\phantom{\rule{0.2em}{0ex}}^{1}\ensuremath{\Pi}$ states. The appearance of the ``forbidden'' lines in the laser-induced $(4)\phantom{\rule{0.2em}{0ex}}^{1}\ensuremath{\Pi}\ensuremath{\rightarrow}X\phantom{\rule{0.2em}{0ex}}^{1}\ensuremath{\Pi}^{+}$ fluorescence spectrum in the presence of an elect…

Radiative lifetimes of the(1–3)Π1states in NaCs: Experiment and theory

The radiative lifetimes of the $(3)\phantom{\rule{0.2em}{0ex}}^{1}\ensuremath{\Pi}$ and $D(2)\phantom{\rule{0.2em}{0ex}}^{1}\ensuremath{\Pi}$ states of the NaCs molecule have been directly measured in a thermal cell from fluorescence kinetics after modulated laser excitation. The experimental ${\ensuremath{\tau}}_{(3)\phantom{\rule{0.2em}{0ex}}^{1}\ensuremath{\Pi}}^{\mathrm{rad}}$ values of the $(3)\phantom{\rule{0.2em}{0ex}}^{1}\ensuremath{\Pi}({v}^{\ensuremath{'}}∊[3,25];{J}^{\ensuremath{'}}∊[25,106])$ levels decrease from $29\phantom{\rule{0.3em}{0ex}}\text{to}\phantom{\rule{0.3em}{0ex}}21\phantom{\rule{0.3em}{0ex}}\mathrm{ns}$ as the ${v}^{\ensuremath{'}}$ values increase. The measured …

Deperturbation treatment of theAΣ+1–bΠ3complex of NaRb and prospects for ultracold molecule formation inXΣ+1(v=0;J=0)

High resolution Fourier transform spectra (FTS) of laser induced fluorescence (LIF) of $C\phantom{\rule{0.2em}{0ex}}^{1}\ensuremath{\Sigma}^{+};D\phantom{\rule{0.2em}{0ex}}^{1}\ensuremath{\Pi}\ensuremath{\rightarrow}A\phantom{\rule{0.2em}{0ex}}^{1}\ensuremath{\Sigma}^{+}--b\phantom{\rule{0.2em}{0ex}}^{3}\ensuremath{\Pi}$ and $A\phantom{\rule{0.2em}{0ex}}^{1}\ensuremath{\Sigma}^{+}--b\phantom{\rule{0.2em}{0ex}}^{3}\ensuremath{\Pi}\ensuremath{\rightarrow}X\phantom{\rule{0.2em}{0ex}}^{1}\ensuremath{\Sigma}^{+}$ transitions in ${\mathrm{Na}}^{85}\mathrm{Rb}$ and ${\mathrm{Na}}^{87}\mathrm{Rb}$ were obtained. An analysis of the direct LIF spectra together with the rotational relaxation satellite…

Analogue of oscillation theorem for nonadiabatic diatomic states: application to the A 1Σ+ and b 3Π states of KCs

Relative intensity measurements in the high resolution A (1)Sigma(+) approximately b (3)Pi--X (1)Sigma(+) laser induced fluorescence spectra of the KCs molecule highlighted a breakdown of the conventional one-dimensional oscillation theorem (L. D. Landau and E. M. Lifshitz, Quantum Mechanics, Pergamon, New York, 1965). For strongly spin-orbit coupled A (1)Sigma(+) and b (3)Pi states the number of nodes n(A) and n(b) of the non-adiabatic vibrational eigenfunctions phi and phi corresponding to the v-th eigenstate differs essentially from their adiabatic counterparts. It is found, however, that in the general case of two-component states with wavefunctions phi and phi coupled by the sign-const…

Investigation of the hyperfine structure of weak atomic Vanadium lines by means of Fourier transform spectroscopy

In continuation of our work on the investigation of the hyperfine structure (HFS) of atomic vanadium, we analyzed weak spectral lines in a Fourier transform spectrum that have not been investigated up to now. The main objective of this work was the determination of the magnetic dipole HFS constant A of the energy level at 15 103.784 cm−1, which was the only energy level with unknown A value up to the energy of 28 000 cm−1. Additionally, other gaps in the data of magnetic dipole HFS could be filled in. The spectrum of vanadium–argon plasma in a hollow cathode lamp is recorded in the spectral range from 12 500 to 26 000 cm−1 or 800 to 380 nm, respectively. The HFS of 42 weak atomic vanadium l…

Energy and radiative properties of the (3)1�� and (5)1��+ states of RbCs: Experiment and theory

We combined high-resolution Fourier-transform spectroscopy and large-scale electronic structure calculation to study energy and radiative properties of the high-lying (3)1�� and (5)1��+ states of the RbCs molecule. The laser-induced (5)1��+(4)1��+(3)1��-A(2)1��+ b(1)3�� fluorescence (LIF) spectra were recorded by the Bruker IFS-125(HR) spectrometer in the frequency range �� 5500 to 10000cm-1 with the instrumental resolution of 0.03 cm-1. The rotational assignment of the observed LIF progressions, which exhibit irregular vibrational-rotational spacing due to strong spin-orbit interaction between A1��+ and b3(��) states was based on the coincidences between observed and calculated energy diff…

Nonlinear magneto-optical resonances for systems withJ∼100observed in K2molecules

We present the results of an experimental as well as a theoretical study of nonlinear magneto-optical resonances in diatomic potassium molecules in the electronic ground state with large values of the angular momentum quantum number $J\ensuremath{\sim}100$. At zero magnetic field, the absorption transitions are suppressed because of population trapping in the ground state due to Zeeman coherences between magnetic sublevels of this state along with depopulation pumping. The destruction of such coherences in an external magnetic field was used to study the resonances in this work. K${}_{2}$ molecules were formed in a glass cell filled with potassium metal at a temperature above 150 ${}^{\ensu…

High resolution spectroscopy and channel-coupling treatment of the A 1Σ+–b 3Π complex of NaRb

The paper presents the study of the fully mixed A 1Σ+–b 3Π complex of the NaRb molecule based on high-resolution sub-Doppler spectroscopy and intensity measurements, ab initio relativistic calculations of energies, transition moments and spin–orbit interactions, as well as an inverted channel-coupling approach (ICCA) deperturbation analysis. A two-laser V-type pump–probe excitation scheme was employed to obtain A←X transition frequencies to 16 A-state vibrational levels from v=6 to v=21 with J from 8 to 23. Additionally, relative intensities in laser-induced A→X fluorescence spectra have been recorded, including progressions with all observable transitions to the ground state vibronic level…

The branching ratio of intercombination A1Σ+∼b3Π→a3Σ+/X1Σ+transitions in the RbCs molecule: Measurements and calculations

Abstract We observed the A 1 Σ + ∼ b 3 Π → a 3 Σ + / X 1 Σ + laser-induced fluorescence (LIF) of the RbCs molecule excited from the ground X 1 Σ + state by the Ti:Sapphire laser. The LIF spectra from the common perturbed levels of the singlet-triplet A ∼ b complex was recorded by the Fourier-transform (FT) spectrometer with the instrumental resolution of 0.03 cm − 1 . The relative intensity distribution in the rotationally resolved A ∼ b → a 3 Σ + ( v a ) / X 1 Σ + ( v X ) progressions was measured, and their branching ratio was found to be about of 1 ÷ 5 × 10 − 4 in the bound region of the a 3 Σ + and X 1 Σ + states. The experiment was complemented with the scalar- and full-relativistic ca…

Energy and radiative properties of the low-lying NaRb states

D 1 P ‐B 1 P transition dipole moments, as well as nonadiabatic L-uncoupling matrix elements between the examined 1 P and four lowest 1 S 1 states for both 23 Na 85 Rb and 23 Na 87 Rb isotopomers. The relevant MPPT ab initio matrix elements and energy curves were converted by means of the approximate sum rule to radiative lifetimes and L-doubling constants ( q factors! for the particular rovibronic levels of the B 1 P and D 1 P states. The theoretical lifetimes agree well with their experimental counterparts for both B 1 P and D 1 P states. The q factor estimates obtained in the singlet-singlet approximation are in good agreement with the experimental ones for the D 1 P(1<v8<12;7<J8<50) lev…

Near-dissociation photoassociative production of deeply bound NaCs molecules

We demonstrate that a photoassociation resonance detuned less than a wave number below the Cs 6 {sup 2}P{sub 3/2} atomic line can be used to create a deeply bound molecular sample of ultracold polar NaCs. We assign 1 {sup 1}{Sigma}{sup +} (v=4,5,6,11,19) vibrational levels utilizing a pulsed depletion spectroscopic method (scanning {approx}700 cm{sup -1} at a time) in which we observe the 1 {sup 1}{Sigma}{sup +}{yields}2 {sup 1}{Sigma}{sup +}-1 {sup 3{Pi}} vibrational progression. These data are compared with results from a hot-molecule collision-enhanced laser-induced fluorescence experiment and shown to be in good agreement. This technique is a powerful tool to experimentally determine th…

Global analysis of data on the spin-orbit coupled $A^{1}\Sigma_{u}^{+}$ and $b^{3}\Pi_{u}$ states of Cs2

We present experimentally derived potential curves and spin-orbit interaction functions for the strongly perturbed $A^{1}\Sigma_{u}^{+}$ and $b^{3}\Pi_{u}$ states of the cesium dimer. The results are based on data from several sources. Laser-induced fluorescence Fourier transform spectroscopy (LIF FTS) was used some time ago in the Laboratoire Aim\'{e} Cotton primarily to study the $X ^{1}\Sigma_{g}^{+}$ state. More recent work at Tsinghua University provides information from moderate resolution spectroscopy on the lowest levels of the $b^{3}\Pi_{0u}^{\pm}$ states as well as additional high resolution data. From Innsbruck University, we have precision data obtained with cold Cs$_{2}$ molecu…

Energy and radiative properties of the (3)Π1 and (5)Σ+1 states of RbCs: Experiment and theory

We combined high-resolution Fourier-transform spectroscopy and large-scale electronic structure calculation to study energy and radiative properties of the high-lying $(3)^{1}\mathrm{\ensuremath{\Pi}}$ and $(5)^{1}\mathrm{\ensuremath{\Sigma}}^{+}$ states of the RbCs molecule. The laser-induced $(5)^{1}\mathrm{\ensuremath{\Sigma}}^{+},(4)^{1}\mathrm{\ensuremath{\Sigma}}^{+},(3)^{1}\mathrm{\ensuremath{\Pi}}\ensuremath{\rightarrow}A(2)^{1}\mathrm{\ensuremath{\Sigma}}^{+}\ensuremath{\sim} b(1)^{3}\mathrm{\ensuremath{\Pi}}$ fluorescence (LIF) spectra were recorded by the Bruker IFS-125(HR) spectrometer in the frequency range $\ensuremath{\nu}\ensuremath{\in}[5500,10\phantom{\rule{0.16em}{0ex}}00…

Identification of Deeply Bound Heteronuclear Molecules Using Pulsed Laser Depletion Spectroscopy

We demonstrate that a near-dissociation photoassociation resonance can be used to create a deeply bound molecular sample of ultracold NaCs. To probe the resulting vibrational distribution of the sample, we use a new technique that can be applied to any ultracold molecular system. We utilize a tunable pulsed dye laser to produce efficient spectroscopic scans ($\sim700$ cm$^{-1}$ at a time) in which we observe the $1^{1} \Sigma^{+}\rightarrow 2^{1}\Sigma^{+}-2^{3}\Pi$ vibrational progression, as well as the dissociation limit to the Cs 6$^{2}$P$_{3/2}$ asymptote. We assign $1^{1} \Sigma^{+}$$(\emph{v}$ = 4, 5, 6, 11, 19) vibrational levels in our sample.

Singlet and triplet potentials of the ground-state atom pair Rb+Cs studied by Fourier-transform spectroscopy

A comprehensive study of the $X {}^{1}\ensuremath{\Sigma}{}^{+}$ and $a {}^{3}\ensuremath{\Sigma}{}^{+}$ electronic states of the Rb and Cs atom pair in RbCs is presented. Abundant spectroscopic data for the $^{85}\mathrm{Rb}$$^{133}\mathrm{Cs}$ and $^{87}\mathrm{Rb}$$^{133}\mathrm{Cs}$ isotopologues were obtained from Fourier-transform spectra of laser-induced fluorescence (LIF) from the $B {}^{1}\ensuremath{\Pi}$ and $(4){}^{1}\ensuremath{\Sigma}{}^{+}$ states to the $a {}^{3}\ensuremath{\Sigma}{}^{+}$ (4549 transitions) and $X {}^{1}\ensuremath{\Sigma}{}^{+}$ (15 709 transitions) states. The $X {}^{1}\ensuremath{\Sigma}{}^{+}$ state data were complemented by about 15 500 transitions obta…

HIGH-RESOLUTION FOURIER TRANSFORM SPECTROSCOPY OF LANTHANUM IN Ar DISCHARGE IN THE NEAR-INFRARED

A high-resolution spectrum of lanthanum has been recorded by a Fourier Transform spectrometer in the wavelength range from 833 nm to 1666 nm (6000 cm{sup –1} to 12,000 cm{sup –1}) using as light source a hollow cathode lamp operated with argon as the discharge carrier gas. In total, 2386 spectral lines were detected in this region, of which 555 lines could be classified as La I transitions and 10 lines as La II transitions. All La II transitions and 534 of these La I transitions were classified for the first time, and 6 of the La II transitions and 433 of the classified La I transitions appear to be new lines, which could not be found in the literature. The corresponding energy level data o…

The coupling of the X$^{1}\Sigma ^{+}$ and a$^{3}\Sigma ^{+}$ states of KRb

A comprehensive study of the electronic states at the 4s+5s asymptote in KRb is presented. Abundant spectroscopic data on the \astate state were collected by Fourier-transform spectroscopy which allow to determine an accurate experimental potential energy curve up to 14.8 \AA . The existing data set (C. Amiot et al. J. Chem. Phys. 112, 7068 (2000)) on the ground state \Xstate was extended by several additional levels lying close to the atomic asymptote. In a coupled channels fitting routine complete molecular potentials for both electronic states were fitted. Along with the line frequencies of the molecular transitions, recently published positions of Feshbach resonances in $^{40}$K and $^{…

Fourier-transform spectroscopy and relativistic electronic structure calculation on the c3Σ+ state of KCs

Abstract The Ti:Saphire laser operated within 13800 - 11800 cm − 1 range was used to excite the c 3 Σ + state of KCs molecule directly from the ground X 1 Σ + state. The laser-induced fluorescence (LIF) spectra of the c 3 Σ + → a 3 Σ + transition were recorded with Fourier-transform spectrometer within 8000 to 10000 cm − 1 range. Overall 673 rovibronic term values belonging to both e / f -components of the c 3 Σ + ( Ω = 1 ± ) state of 39 KCs, covering vibrational levels from v = 0 to about 45, and rotational levels J ∈ [ 11 , 149 ] were determined with the accuracy of about 0.01 cm − 1 ; among them 7 values for 41 KCs. The experimental term values with v ∈ [ 0 , 22 ] were involved in a dire…

Direct excitation of the “dark”b3Πstate predicted by deperturbation analysis of theA1Σ+−b3Πcomplex in KCs

The diode-laser-induced fluorescence spectra $b {}^{3}{\ensuremath{\Pi}}_{\ensuremath{\Omega}=0}^{+}\ensuremath{\rightarrow}{X}^{ 1}{\ensuremath{\Sigma}}^{+}$ originated from the rovibronic levels of the ``dark'' triplet $b {}^{3}{\ensuremath{\Pi}}_{\ensuremath{\Omega}=0}^{+}$ state of KCs dimers were recorded with a Fourier transform spectrometer with a resolution of 0.03 cm${}^{\ensuremath{-}1}$. Term values of 30 rovibronic levels $({v}_{b0}^{*}\ensuremath{\in}[14,18];{J}^{\ensuremath{'}}\ensuremath{\in}[47,134])$ below the minimum of perturbing $A {}^{1}{\ensuremath{\Sigma}}^{+}$ state were determined with 0.003--0.01 cm${}^{\ensuremath{-}1}$ uncertainty. The optimal excitation and dete…

Hyperfine structure study of atomic niobium with enhanced sensitivity of Fourier transform spectroscopy

In an experimental setup with a high-resolution Fourier transform (FT) spectrometer and a hollow-cathode discharge, bandpass interference filters are used to enhance the sensitivity. This extension leads to an improvement of the signal-to-noise ratio in the spectrum of atomic niobium by a factor of up to 10 compared to FT spectra measured previously without filters (see Kroger et al 2010 Astron. Astrophys. 516 A70). Several additional spectral lines with low intensity have been observed. Additionally, in some intense lines, blends become visible due to the better signal-to-noise ratio. The hyperfine structure of 51 lines recorded in the wavelength range from 415 to 670 nm is analysed or re-…

Fourier-transform spectroscopy, relativistic electronic structure calculation, and coupled-channel deperturbation analysis of the fully mixed A1Σu+ and b3Πu states of Cs2

The 4503 rovibronic term values belonging to the mutually perturbed $A^1\Sigma^+_u$ and $b^3\Pi_u$ states of Cs$_2$ were extracted from laser induced fluorescence (LIF) $A\sim b\rightarrow X^1\Sigma^+_g$ Fourier transform spectra with the 0.01 cm$^{-1}$ uncertainty. The experimental term values of the $A^1\Sigma^+_u\sim b^3\Pi_u$ complex covering the rotational levels $J\in [4,395]$ in the excitation energy range $[9655,13630]$ cm$^{-1}$ were involved into coupled-channel (CC) deperturbation analysis. The deperturbation model takes explicitly into account spin-orbit coupling of the $A^1\Sigma^+_u(A0^+_u)$ and $b^3\Pi^+_{0_u}(b0^+_u)$ states as well as spin-rotational interaction between the…

Electric field induced hyperfine level-crossings in (nD)Cs at two-step laser excitation: experiment and theory

The pure electric field level-crossing of m_F Zeeman sublevels of hyperfine F levels at two-step laser excitation was described theoretically and studied experimentally for the nD_3/2 states in Cs with n = 7,9, and 10, by applying a diode laser in the first 6S_1/2 to 6P_3/2 step and a diode or dye laser for the second 6P_3/2 to nD_3/2 step. Level-crossing resonance signals were observed in the nD_3/2 to 6P_1/2 fluorescence. A theoretical model was developed to describe quantitatively the resonance signals by correlation analysis of the optical Bloch equations in the case when an atom simultaneously interacts with two laser fields in the presence of an external dc electric field. The simulat…

LIF intensity distribution as a deperturbation tool: application to the fully-mixed A1Σ+–b3Π complex of NaRb

Abstract The intensity distribution in the NaRb A 1 Σ + ( v A ′ = 16 , J ′ = 30 ; v A ′ = 18 , J ′ = 66 ) ∼ b 3 Π → X 1 Σ + ( v X ′ ′ = 2 ÷ 44 , J ′ ′ = J ′ ± 1 ) fluorescence series induced by diode laser excitation from the ground state have been measured and directly applied to restore adiabatic potential energy curve for the A-state of the fully-mixed A 1 Σ + – b 3 Π complex. Relative intensities in the long non-diagonal A → X progressions have been proved to be much less influenced by strong spin–orbit interaction than the corresponding term values of the fully coupled A 1 Σ + – b 3 Π complex.

The B 1Pi state of NaCs: high resolution laser induced fluorescence spectroscopy and potential construction.

The lowest (1)Pi state of the NaCs molecule, the B(1)(1)Pi state, was studied using a dye laser for inducing fluorescence that was resolved by a high resolution Fourier-transform spectrometer. The presence of argon buffer gas yielded rich rotational relaxation spectra allowing to enlarge the data set for the B(1)(1)Pi state, to obtain Lambda-splittings and to reveal numerous local perturbations. 543 weakly perturbed energy levels for rotational quantum numbers from J(')=5 to 168 and vibrational quantum numbers from v(')=0 to 25, which cover about 87% of the potential well depth, were used for a direct pointwise fit of the potential energy curve applying the inverted perturbation approach me…

Stark level crossing and optical-rf double resonance in NaK D 1 Π

We report here (Lambda) -doubling splitting and permanent electric dipole moment d p measurements for a number of vibrotational levels of NaK D 1 II state. Two different methods, which are not Doppler limited, were used. Stark effect induced level crossing was registered as fluorescence polarization changes with external electric field, which allowed us to obtain, from one fit, the values of electric dipole moment and (Lambda) -doubling splitting (Delta) ef between e, f substates of an individual rotational state. Another method consisted in obtaining the ratio (Delta) ef /d p from electric field dependence of the intensity of forbidden line appeared in fluorescence as a result of e- f Star…

HYPERFINE STRUCTURE CONSTANTS OF ENERGETICALLY HIGH-LYING LEVELS OF ODD PARITY OF ATOMIC VANADIUM

High-resolution Fourier transform spectra of a vanadium-argon plasma have been recorded in the wavelength range of 365-670 nm (15,000-27,400 cm–1). Optical bandpass filters were used in the experimental setup to enhance the sensitivity of the Fourier transform spectrometer. In total, 138 atomic vanadium spectral lines showing resolved or partially resolved hyperfine structure have been analyzed to determine the magnetic dipole hyperfine structure constants A of the involved energy levels. One of the investigated lines has not been previously classified. As a result, the magnetic dipole hyperfine structure constants A for 90 energy levels are presented: 35 of them belong to the configuration…

HIGH-RESOLUTION FOURIER TRANSFORM SPECTROSCOPY OF Nb i IN THE NEAR-INFRARED

In this study, a Fourier Transform spectrum of Niobium (Nb) is investigated in the near-infrared spectral range from 6000 to 12,000 cm−1 (830–1660 nm). The Nb spectrum is produced using a hollow cathode discharge lamp in an argon atmosphere. Both Nb and Ar spectral lines are visible in the spectrum. A total of 110 spectral lines are assigned to the element Nb. Of these lines, 90 could be classified as transitions between known levels of atomic Nb. From these classified Nb i transitions, 27 have not been listed in literature previously. Additionally, 8 lines are classified for the first time.

Hyperfine structure measurements of neutral niobium with Fourier transform spectroscopy

Aims. We report on experimental studies of hyperfine structure splitting of neutral niobium.Methods. We used high-resolution Fourier transform spectroscopy to record a spectrum of niobium produced with a hollow cathode discharge lamp in the range of wavenumbers from 10 000 cm-1 to 30 000 cm-1 .Results. The magnetic dipole hyperfine structure constants A were determined for the 109 levels of odd parity by analyzing the profiles of 224 spectral lines. The A  values of 57 of these level are reported for the first time.

Experimental and theoretical studies of Λ doublings and permanent electric dipoles in the low-lying Π1 states of NaCs

We present experimental data on the electric permanent dipole moments d(v',J') and lambda splittings (q factors) in the quasidegenerate (3) 1pi(e/f) state of the NaCs molecule over a wide range of the vibrational (v') and rotational (J') quantum numbers by using the combination of dc Stark mixing and electric radio frequency-optical double resonance methods. Within the experimental (3) 1pi state v' ranged from v' = 0 to 34, q values exhibited a pronounced decrease from 7.91x10(-6) to 0.47x10(-6) cm(-1), while absolute value(d) values varied between 8.0 and 5.0 D. Experimental evaluation yielded small d values about 1 D for D2 1pi state v'3 levels. The experiment is supported by ab initio el…

Potential construction of the B (1) 1 Π state in KCs based on Fourier-Transform spectroscopy data

Abstract The paper presents an empirical pointwise potential energy curve (PEC) of the extensively perturbed B ( 1 ) 1 Π state of the KCs molecule constructed by applying an Inverted Perturbation Approach routine. The experimental term values in the energy range E ( v ′ , J ′ ) ∈ [ 14071 ; 15502 ] cm − 1 involved in the fit were based on Fourier-Transform spectroscopy data obtained with 0.01 cm−1 accuracy from laser-induced B ( 1 ) 1 Π → X 1 Σ + fluorescence spectra in the present work (654 term values) combined with 520 term values from Birzniece et al. (2012) . The data set included vibrational v ′ ∈ [ 0 , 35 ] and rotational J ′ ∈ [ 7 , 233 ] quantum numbers covering about 85% of the pot…

Ab initio multi-reference perturbation theory calculations of the ground and low-lying electronic states of the KRb molecule

The potential energy curves of the low-lying electronic states correlating up to the limit K(4p) + Rb(5s) of KRb molecule have been calculated using the multi-reference perturbation theory method at the CASSCF/ XMCQDPT2 level of theory without and with spin–orbit coupling. The calculated parameters of the ground X 1 R + state are in the best agreement among all previously performed ab initio calculations for the KRb molecule. The calculated vibrational intervals of the ground electronic term of the 39 K 85 Rb molecule describe the experiment with the accuracy within ±1 cm ?1 . The calculated intensities of the 2 1 R + (v 0 = 3, J 0 = 26) ? X 1 R + (v 00 = 0...24, J 00 = 25, 27) transitions …

Spin-orbit, radial, and angular coupling effects in the NaRb excited states

Spin-orbit, radial, and angular nonadiabatic matrix elements between the lowest excited states of NaRb are evaluated by quasi-relativistic ab initio methods, and the results accompanied by potential curves, permanent and transition moments are compared with experimental data and preceding calculations.

Long-range coupling ofX1Σ+anda3Σ+states of the atom pairK+Cs

The potential of the ground state of NaRb

The X$^{1}\Sigma ^{+}$ state of NaRb was studied by Fourier transform spectroscopy. An accurate potential energy curve was derived from more than 8800 transitions in isotopomers $^{23}$Na$^{85}$Rb and $^{23}$Na$^{87}$Rb. This potential reproduces the experimental observations within their uncertainties of 0.003 \rcm to 0.007 \rcm. The outer classical turning point of the last observed energy level ($v''=76$, $J''=27$) lies at $\approx 12.4$ \AA, leading to a energy of 4.5 \rcm below the ground state asymptote.

Line Identification of Atomic and Ionic Spectra of Holmium in the Near-UV. Part I. Spectrum of Ho i

The Fourier Transform spectra of a Holmium hollow cathode discharge lamp have been investigated in the UV spectral range from 25,000 up to 31,530 cm−1 (317 to 400 nm). Two Ho spectra have been measured with neon and argon as buffer gases. Based on the intensity ratios from these two spectra, a distinction was made between atomic and ionic lines (ionic lines are discussed in an accompanying paper). Using the known Ho i energy levels, 71 lines could be classified as transitions of atomic Ho, 34 of which have not been published previously. Another 32 lines, which could not be classified, are listed in the literature and assigned as atomic Ho. An additional 370 spectral lines have been assigned…

Spectra of a Holmium in the near-UV. I. Ho I.

The Fourier Transform spectra of a Holmium hollow cathode discharge lamp have been investigated in the UV spectral range from 25000 up to 31530cm^-1^ (317 to 400nm). Two Ho spectra have been measured with neon and argon as buffer gases. Based on the intensity ratios from these two spectra, a distinction was made between atomic and ionic lines (ionic lines are discussed in an accompanying paper). Using the known Ho I energy levels, 71 lines could be classified as transitions of atomic Ho, 34 of which have not been published previously. Another 32 lines, which could not be classified, are listed in the literature and assigned as atomic Ho. An additional 370 spectral lines have been assigned t…

Spectra of a Holmium in the near-UV. II.

Fourier Transform spectra of Holmium (Ho) in the UV spectral range from 31530 to 25000cm^-1^ (317 to 400nm) have been investigated, particularly focusing on the ionic lines. The distinction between the different degrees of ionization (I, II, and III) is based on differences in signal-to-noise ratios from two Ho spectra, which have been measured with different buffer gases, i.e., neon and argon. Based on 106 known Ho II and 126 known Ho III energy levels, 97 lines could be classified as transitions of singly ionized Ho and 9 lines could be classified as transitions of doubly ionized Ho. Of the 97 Ho II lines, 6 have not been listed in the extant literature. Another 215 lines have been assign…