6533b825fe1ef96bd1281cac

RESEARCH PRODUCT

The coupling of the X1Σ+and a3Σ+states of the atom pair Na + Cs and modelling cold collisions

O. DocenkoJ. ZaharovaRuvin FerberA. PashovM. TamanisHorst KnöckelEberhard Tiemann

subject

PhysicsScatteringUltracold atomQuantum stateAtomic physicsCondensed Matter PhysicsSpectroscopyDispersion (geology)Feshbach resonancePotential energyHyperfine structureAtomic and Molecular Physics and Optics

description

The states X1?+ and a3?+ correlated to the ground-state asymptote of Na (3s) and Cs (6s) atoms have been experimentally investigated using high resolution Fourier-transform spectroscopy. The hyperfine splitting of the a3?+ state levels is partially resolved. Transitions to asymptotic vibrational levels of the a3?+ and X1?+ states were recorded simultaneously. The joint evaluation of the data of both the a3?+ and the X1?+ states allows us to determine accurate potential energy curves of both electronic states. Coupled-channels calculations are finally applied for deriving long range dispersion parameters and the exchange contribution of the molecular potentials, yielding a reliable description of cold collisions between Na and Cs atoms in their two different hyperfine ground states. Scattering lengths and Feshbach resonances are predicted for selected quantum states.

https://doi.org/10.1088/0953-4075/39/19/s08