Zur Umlagerung von Nitrosoalkyl‐sulfonamiden durch Alkalien

6533b7d4fe1ef96bd126274d

RESEARCH PRODUCT

Zur Umlagerung von Nitrosoalkyl‐sulfonamiden durch Alkalien

subject

Inorganic Chemistry Chemistry Medicinal chemistry

description

Substituierte Nitrosoalkyl-sulfonamide, die in α-Stellung zum Amidstickstoff eine aktivierte Methylengruppe besitzen, reagieren mit Alkalien unter Verschiebung der Nitrosogruppe vom Amidstickstoff an den α-Kohlenstoff, unter Bildung von Sulfonyl-amidoximen. Ausdehnung und Grenzen der Reaktion werden untersucht und ihr inner-molekularer Verlauf nachgewiesen.

year	journal	country	edition	language
1956-07-01	Chemische Berichte

https://doi.org/10.1002/cber.19560890714

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