6533b7d4fe1ef96bd12630a7

RESEARCH PRODUCT

Oxygen on Fe(110): magnetic properties of the adsorbate system

Gerd SchönhenseMathias GetzlaffJoachim Bansmann

subject

Materials scienceMagnetic momentIron oxidechemistry.chemical_elementCondensed Matter PhysicsEpitaxyMolecular physicsOxygenElectronic Optical and Magnetic MaterialsOverlayerCondensed Matter::Materials Sciencechemistry.chemical_compoundNuclear magnetic resonancechemistryFerromagnetismChemisorptionAntiferromagnetism

description

Abstract Investigations concerning the electronic and magnetic properties of oxygen adsorbed on magnetized iron films were carried out by means of angle and spin resolving photoelectron spectroscopy. Iron(1 1 0), epitaxially grown on a W(1 1 0) crystal, served as the ferromagnetic substrate. Exchange splittings of the O 2p x derived level were detected demonstrating a magnetic coupling between the chemisorbate and the iron layer. This observation indicates the presence of an induced magnetic moment within the adsorbate overlayer. Variations of the exchange splitting occurred as a function of the oxygen coverage, energy of the exciting radiation, and detection angle of the emitted photoelectrons pointing to a k ‖ -dependent exchange splitting. High oxygen exposures lead to a FeO overlayer at the surface, showing vanishing peak separations due to the antiferromagnetic behavior of iron oxide.

https://doi.org/10.1016/s0304-8853(98)00686-6