6533b7d5fe1ef96bd1263e19

RESEARCH PRODUCT

Single-Crystal-to-Single-Crystal Anion Exchange in a Gadolinium MOF: Incorporation of POMs and [AuCl4]−

Eugenio CoronadoJavier López-cabrellesGuillermo Mínguez Espallargas

subject

Polymers and PlasticsGadoliniumInorganic chemistryPorous Coordination Polymerschemistry.chemical_element010402 general chemistry01 natural sciencesArticleSingle Crystal DiffractionIonlcsh:QD241-441lcsh:Organic chemistryFunctional importanceanion exchangeMoleculepolyoxometalatesMaterialsIon exchange010405 organic chemistryGeneral ChemistryMOFs; anion exchange; polyoxometalatesMOFs0104 chemical sciencesCrystallographychemistryCristallsCompostos de coordinacióSingle crystal

description

The encapsulation of functional molecules inside porous coordination polymers (also known as metal-organic frameworks, MOFs) has become of great interest in recent years at the field of multifunctional materials. In this article, we present a study of the effects of size and charge in the anion exchange process of a Gd based MOF, involving molecular species like polyoxometalates (POMs), and [AuCl4]−. This post-synthetic modification has been characterized by IR, EDAX, and single crystal diffraction, which have provided unequivocal evidence of the location of the anion molecules in the framework.

yearjournalcountryeditionlanguage
2016-04-01Polymers
https://doi.org/10.3390/polym8050171