6533b7d7fe1ef96bd1268ec5
RESEARCH PRODUCT
A Singular Noninterpenetrating Coordination Polymer with the Pt3O4 Structure Containing Naked [Na+]4 Units
José Antonio RealAna GaletAna B. GasparM. Carmen MuñozXavier Solanssubject
LigandCoordination polymerInorganic chemistryCationic polymerizationIonic bondingIonInorganic Chemistrychemistry.chemical_compoundCrystallographyPerchloratechemistryMoleculePhysical and Theoretical ChemistryHomolepticdescription
The homoleptic low-spin complex [Fe(L)3]2+ where L is the bisbidentate ligand 1,10-phenanthroline-5,6-dione, coordinates Na+ ions via exo-oriented dione groups defining a three-dimensional cationic network {[Fe(L)3]4Na3}11+}n with Pt3O4 topology. The large volume generated by the network is filled with 11 perchlorate ions, 7 "NaClO4" ionic pairs, and 9 H2O molecules. Singular [Na+]4 units, in which the Na+ ions are practically uncoordinated, are formed.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2006-12-19 | Inorganic Chemistry |